Junkai He

ORCID: 0000-0002-1955-5554
Publications
Citations
Views
---
Saved
---
About
Contact & Profiles
Research Areas
  • Catalytic Processes in Materials Science
  • Electrocatalysts for Energy Conversion
  • Catalysis and Oxidation Reactions
  • Advanced battery technologies research
  • Advanced Photocatalysis Techniques
  • Advancements in Battery Materials
  • Nanomaterials for catalytic reactions
  • Mesoporous Materials and Catalysis
  • Supercapacitor Materials and Fabrication
  • Catalysis and Hydrodesulfurization Studies
  • Clay minerals and soil interactions
  • Oxidative Organic Chemistry Reactions
  • Chemical Synthesis and Reactions
  • Catalysts for Methane Reforming
  • Copper-based nanomaterials and applications
  • Asymmetric Hydrogenation and Catalysis
  • Electrochemical Analysis and Applications
  • Graphene research and applications
  • Iron oxide chemistry and applications
  • Advanced Battery Materials and Technologies
  • Fuel Cells and Related Materials
  • Soil and Unsaturated Flow
  • CO2 Reduction Techniques and Catalysts
  • Advanced oxidation water treatment
  • Therapeutic Uses of Natural Elements

University of Connecticut
2015-2022

Wuhan University
2021

Eagle Mount
2020

London Rebuilding Society
2016-2020

University of Science and Technology Beijing
2018

China University of Mining and Technology
2010-2011

Inner Mongolia University of Science and Technology
2011

A unique approach for the synthesis of nonstoichiometric, mesoporous molybdenum oxide (MoO 3– x ) with nanosized crystalline walls by using a soft template (PEO‐ b ‐PS) method is introduced. The as‐synthesized MoO very active and stable (durability > 12 h) electrochemical hydrogen evolution reaction (HER) under both acidic alkaline conditions. intrinsic 3 serves as an HER electrocatalyst without assistance carbon materials, noble metals, or MoS 2 materials. results from transmission...

10.1002/aenm.201600528 article EN Advanced Energy Materials 2016-06-15

We report a facile synthetic protocol to prepare mesoporous FeS2 without the aid of hard template as an electrocatalyst for hydrogen evolution reaction (HER). The materials with high surface area were successfully prepared by sol–gel method following sulfurization treatment in H2S atmosphere. A remarkable HER catalytic performance was achieved low overpotential 96 mV at current density 10 mA·cm–2 and Tafel slope 78 per decade under alkaline conditions (pH 13). theoretical calculations...

10.1021/jacs.7b07044 article EN Journal of the American Chemical Society 2017-09-05

A direct and effective approach is proposed to fabricate bimetallic phosphide Ni2P–Cu3P with controllable phase composition distribution for catalytic hydrogen evolution reaction (HER). Unlike previously reported precursors, a porous Ni–Cu alloy incorporated graphitic carbon (NiCuC) prepared via powder metallurgy employed herein, the generated Ni2P–Cu3P@NiCuC possesses hierarchical structure due high porosity tunable Ni/Cu ratio of precursor. With an optimal Cu content 30.0 wt %, catalyst...

10.1021/acscatal.9b00494 article EN ACS Catalysis 2019-06-25

The electrolysis of water provides a powerful pathway for the storage and conversion clean renewable energy. Therefore, development earth-abundant, inexpensive, highly efficient electrocatalysts contributes great deal to overall efficiency electrolytic system. Here, inspired by low charge transfer resistance mixed-valence cations, favorable H atom binding energy cobalt, high electrical conductivity graphene, we report facile synthesis strategy synthesize spinel ternary oxide material...

10.1021/acscatal.6b02650 article EN ACS Catalysis 2016-12-13

We report on the new facile synthesis of mesoporous NiO/MnO2 in one step by modifying inverse micelle templated UCT (University Connecticut) methods. The catalyst shows excellent electrocatalytic activity and stability for both oxygen evolution reaction (OER) reduction (ORR) alkaline media after further coating with polyaniline (PANI). For electrochemical performance, optimized exhibits a potential gap, ΔE, 0.75 V to achieve current 10 mA cm–2 OER −3 ORR 0.1 M KOH solution. Extensive...

10.1021/acsami.7b07383 article EN ACS Applied Materials & Interfaces 2017-11-21

10.1016/j.saa.2010.08.039 article EN Spectrochimica Acta Part A Molecular and Biomolecular Spectroscopy 2010-09-01

Electrocatalysis of water is a scalable and easily available source the production hydrogen (H2), future energy carrier. This drive for clean inspired us to develop an inexpensive, readily producible, highly active, stable catalyst replace current state art platinum catalysts. Building on promising evolution reaction (HER) activity many pyrites, their structural tuning by different metals nonmetals has been found be effective in several instances. We present here one such effort partial...

10.1021/acscatal.8b02904 article EN ACS Catalysis 2018-12-03

Significance Electrochemical reduction of CO 2 to useful chemicals or fuels is critical closing the carbon cycle and preventing further deterioration environment/climate. This work addresses low-energy-efficiency problem limited by sluggish oxygen evolution reaction (OER) on anode side. The only active OER catalysts for coupling in neutral conditions are based noble metals such as Ir, Ru, gold. Herein, we developed a nonprecious-metal-based with higher activity stability than those...

10.1073/pnas.1915319116 article EN Proceedings of the National Academy of Sciences 2019-11-13

Pursuing cost-effective water-splitting catalysts is still a significant scientific challenge to produce renewable fuels and chemicals from various feedstocks. The construction of controllable binder-free nanostructures with self-standing holey ultrathin nanosheets one the promising approaches. Herein, by employing combination potentiodynamic mode electrodeposition low-temperature phosphidation, three-dimensional (3D) CoP are fabricated on carbon cloth (PD-CoP UNSs/CC) as bifunctional...

10.1021/acsami.9b08238 article EN ACS Applied Materials & Interfaces 2019-07-25

Abstract The increasing demand of emerging technologies for high energy density electrochemical storage has led many researchers to look alternative anode materials graphite. most promising conversion and alloying do not yet possess acceptable cycle life or rate capability. In this work, we use tin oxide, SnO 2 , as a representative material explore the influence graphene incorporation In-doping increase electronic conductivity concomitantly improve capacity retention life. It was found that...

10.1038/srep25860 article EN cc-by Scientific Reports 2016-05-11
Coming Soon ...