A5084609042- Chemical Synthesis and Reactions
- Inorganic and Organometallic Chemistry
- Catalytic C–H Functionalization Methods
- Nanomaterials for catalytic reactions
- Chemical Synthesis and Analysis
- Chemical Reactions and Isotopes
- Asymmetric Hydrogenation and Catalysis
University of Minnesota
2024-2025
Twin Cities Orthopedics
2025
Shell (Netherlands)
1985-1986
Ti-catalyzed alkyne diamination and hydrohydrazination proceed through a common N-aminoazatitanacyclobutene intermediate. These reactions have historically existed as processes catalyzed by distinct molecular Ti compounds, with several reports for only single example diamination. Here, we demonstrate that diamidoamine catalyst, (NNN)Ti(═NNR2) (1, (NNN)H2 = N-methyl-N',N″-bis(trimethylsilyl)diethylenetriamine; R alkyl, aryl), is capable of catalyzing both hydrohydrazination, where the...
Abstract An extremely mild method for the conversion of RCH2X (X = Br, I) into RCH2OH is described. The particularly useful when R contains a base-sensitive group.