A5077368447- Crystallization and Solubility Studies
- X-ray Diffraction in Crystallography
- Photoreceptor and optogenetics research
- Molecular Sensors and Ion Detection
- Supramolecular Chemistry and Complexes
- Micro and Nano Robotics
- Polymer Science and PVC
- Photochromic and Fluorescence Chemistry
- Coordination Chemistry and Organometallics
- Luminescence and Fluorescent Materials
- Protein Structure and Dynamics
- Lipid Membrane Structure and Behavior
- Organoboron and organosilicon chemistry
- Porphyrin and Phthalocyanine Chemistry
- Organometallic Compounds Synthesis and Characterization
- Crystallography and molecular interactions
- Advanced NMR Techniques and Applications
- Synthesis and characterization of novel inorganic/organometallic compounds
- Microwave-Assisted Synthesis and Applications
- Fuel Cells and Related Materials
- Chemical Synthesis and Analysis
- Thermal and Kinetic Analysis
Western New England University
2022
Institut Charles Sadron
2014-2017
Centre National de la Recherche Scientifique
2014-2017
Université de Strasbourg
2014-2017
Dartmouth College
2012-2014
The University of Texas at Austin
1967
Molecular switches and machines that are powered by acid-base reactions susceptible to low switching cycles because of the concomitant formation waste products during their operation. Here, we demonstrate fast, efficient, reversible modulation a hydrazone switch in methanol using visible-light activated photoacid, with no generation side products, high conversion rates (>95%), loss activity over 100 cycles. TEG functionalization allows for process be carried (>90%) water as well.
Regulating signal amplification using a switchable catalytic cycle.
Crystal structures of η5-coordinated polymers cyclopentadienyl lithium (CpLi) derivatives are rare. Herein we describe the solid-state characterization base-free supersandwich benzyl ([BnCp–Li]∞). The self-assembled polymer has shortest mean Li–Cp (2.286 Å) and Li–Cpcentroid (1.948 bond distances known mono-substituted CpLi compounds.
Abstract Heteroaryl azobenzene molecular switches often have superior performance compared to their parent derivatives. Herein, we report the efficient photoswitching of phenylazopyridine 5‐methoxy‐2‐(2‐phenyldiazenyl)pyridine using 1 H NMR and UV/vis spectroscopy demonstrating >92 % Z at photostationary state a thermal half‐life 6.3 days room temperature. Kinetic studies are in good agreement with DFT predicted isomerization barrier.