A5002277497- Molecular Sensors and Ion Detection
- Luminescence and Fluorescent Materials
- Energetic Materials and Combustion
- Advanced biosensing and bioanalysis techniques
- Thermal and Kinetic Analysis
- Graphene research and applications
- Catalytic C–H Functionalization Methods
- Catalytic Cross-Coupling Reactions
- Nanoplatforms for cancer theranostics
- Rocket and propulsion systems research
- Advanced ceramic materials synthesis
- Organoboron and organosilicon chemistry
- Synthesis and Catalytic Reactions
- Catalytic Processes in Materials Science
- Multicomponent Synthesis of Heterocycles
- Oxidative Organic Chemistry Reactions
- Intermetallics and Advanced Alloy Properties
- Radical Photochemical Reactions
- Sulfur-Based Synthesis Techniques
- Crystallization and Solubility Studies
- Crystallography and molecular interactions
- X-ray Diffraction in Crystallography
- Analytical Chemistry and Sensors
- Advancements in Battery Materials
- Carbon Nanotubes in Composites
Nanjing University of Science and Technology
2013-2024
Ministry of Industry and Information Technology
2022-2024
Nanjing University
1999-2012
Osaka University
2005
Nankai University
2003
A three-dimensionally ordered macroporous Fe2O3/Al nanothermite membrane has been prepared with a polystyrene spheres template. The nanothermite, an enhanced interfacial contact between fuel and oxidizer, outputs 2.83 kJ g–1 of energy. This is significantly more than reported before. approach, fully compatible MEMS technology, provides efficient way to produce micrometer thick nanostructured thermite films overall spatial uniformity. These exciting achievements will greatly facilitate...
It is highly desired but still remains challenging to design a primary explosive-based nanoparticle-encapsulated conductive skeleton for the development of powerful yet safe energetic films employed in miniaturized explosive systems. Herein, proof-of-concept electrochemical preparation metal-organic frameworks (MOFs) derived porous carbon embedding copper-based azide (Cu(N3 )2 or CuN3 , CA) nanoparticles on copper substrate described. A Cu-based MOF, i.e., Cu-BTC fabricated based anodized...
A porous CuN3 film has been facilely synthesized by a sustainable electroassisted azidation methodology using the template of Cu as precursor. Such films show excellent performances both superior energy release and tremendous brisance, which can be tuned changes current density time. Energy reaches maximum 1200 J·g–1 at 3.0 mA·cm–2 with reaction time 450 s. Meanwhile, conversion ratio reach ca. 31% 43 wt % in prepared film. In addition, growth mechanism is justified not only experimental...
Abstract Mn 2 O 3 has been selected to realize nanothermite membrane for the first time in literature. /Al synthesized by magnetron sputtering a layer of Al film onto three-dimensionally ordered macroporous (3DOM) skeleton. The energy release is significantly enhanced owing unusual 3DOM structure, which ensures and integrate compactly nanoscale greatly increase effective contact area. morphology DSC curve have investigated at various aluminizing times. At optimized 30 min, reaches maximum...
A novel highly efficient FRET system from aggregation-induced emission to BODIPY based on the host–guest interaction for mimicking a light harvesting was disclosed with efficiency up 93%
Microigniters play an important role for the reliable initiation of micro explosive devices. However, microigniter is still limited by low out-put energy to realize high reliability and safety. Integration energetic materials with microigniters effective method enhance ignition ability. In this work, a Al/Co3O4 nanothermite film three-dimensionally ordered macroporous structure was prepared deposition nanoscale Al layers using magnetron sputtering on Co3O4 skeletons that are synthesized...
A new practical and efficient synthesis of 1,3,5-trisubstituted pyrazoles has been developed by reacting hydrazonoyl halides with β-oxophosphonates under mild conditions in good yields excellent regioselectivity. This process employs an addition–elimination sequence. Wide scope, functional group compatibility established.
A tetraphenylenlene (TPE)-based fluorescent probe could selectively monitor pH in THF–H<sub>2</sub>O media wide-range pH. From acidic to basic conditions, it displayed monomer emission, ratiometric fluorescence and aggregation-induced emission successively.
Copper(I)-catalyzed cross-coupling reactions of aryl diazonium salts with bis(pinacolato)diboron can proceed smoothly in the water phase at room temperature to give corresponding arylboronate esters good high yields. The Sandmeyer-type borylation not only provides direct access arylboronates bearing halo and acidic substituents, but also achieves a green process.
3DOM Al/NiFe<sub>2</sub>O<sub>4</sub> nanothermite with significantly improved heat output and lower onset temperature.
A BODIPY-based turn-on fluorescent probe 1 has been designed and synthesized for fluorescence detection of Cu2+ in aqueous media imaging living cells. The CN bonds are selectively hydrolyzed by the reaction with to generate formyl-BODIPY. favorable features towards include significant enhancement (over 290-fold), high selectivity low limit (0.1 μM).
The Pt-catalyzed reactions of terminal alkynes HCCR (2) with ArI (6) (Ar = aryl and thienyl) Ar'SM (M Li, Na, K, Sn(n-Bu3)) (7) have been examined. Among them, the combined use 2- 3-iodothiophene PhSK resulted in formation (Z)-Ar(H)CC(SAr')(R) (5) moderate to good yields. When iodide was employed as a coupling partner, thioether ArSAr' (4), direct cross-coupling product between 6 7, competitively produced together 5. ratios 5/4 were significantly dependent on substituent Ar Ar' 7 well...
A novel chemo-photodynamic combined therapeutic self-assembly polymeric platform (MPEG-Hyd-Br<sub>2</sub>-BODIPY) was constructed which can encapsulate DOX and exhibited an accelerated release rate with decreasing pH value results in considerable time/dose-dependent cytotoxicity.