A coordination polymer with the composition C12H20O16Zn2 (ZnBTC) (BTC = benzene-1,3,5-tricarboxylate) was synthesized under hydrothermal conditions at 120 °C, and its crystal structure determined using single-crystal X-ray crystallography. First-principles electronic investigation of compound carried out density functional theory computational approach. The highest occupied molecular orbital, lowest unoccupied energy gap, global reactivity descriptors ZnBTC were investigated in both gas...

Cancer remains a major global health concern, necessitating the development of novel and more effective treatment strategies. This research focused on exploring potential silicene as nano-drug delivery platform. Silicene, two-dimensional honeycomb structure, has garnered attention an alternative to graphene, germanenes, stanenes due its comparative advantages in interfacing with micro or nano electronic devices. In this study, we investigated co-doping Ag-doped B, N, P, S evaluate their...

Abstract Gas sensors exhibit significant potential due to their widespread use in various applications, such as food packaging, indoor air quality assessment, and real-time monitoring of man-made gas emissions mitigate global warming. The utilization nanostructured materials for sensor adsorbent surfaces has seen remarkable growth over time, though substantial efforts are still needed develop more efficient adsorbents. Consequently, this study investigates the viability metal-doped quantum...

BACKGROUND:Methicillin-resistant Staphylococcus aureus (MRSA) bacteremia and sepsis are commonly treated with intravenous vancomycin. However, vancomycin treatment is associated adverse reactions, including skin rashes nephrotoxicity. We present a case of acute renal failure due to tubulointerstitial nephritis diffuse leukocytoclastic vasculitic eruption following treatment. CASE REPORT:A 79-year-old Caucasian male patient was for MRSA bacteremia. Prior treatment, his creatinine normal at...

Lomustine is an alkylating chemotherapy drug that used to treat diverse types of cancer, including brain tumors, Hodgkin's lymphoma, and non-Hodgkin's which works by interfering with the DNA in cancer cells, preventing them from dividing growing. As such lipid bilayer cell body fluids provides environments lomustine (lmt) performs its biological function. Chemical reactions involving systems occur liquid phase, where accurate modeling reaction pathways considers influence solvent used....

Abstract In this research paper we report the detailed synthesis, spectral ( 1 H‐NMR, FT‐IR, and UV‐Vis), crystal structure determination, DFT studies, molecular modeling of 4‐amino‐3‐mercapto‐5‐methyl‐1,2,4‐triazole (L 2 ) Schiff base ligand its complexes cadmium as suitable bioactive agents for treatment malaria. From spectroscopic results, synthesized has potentialtridentate coordination with themetal ion via hydroxy naphthalinic‐O, azomethine‐N sulphur atom thione group. First principle...

Poverty is a social problem. Its alleviation has been one of the major issues that occupy significant place in scale preference developmental policies several nations, international organizations, church and other interested stakeholders. Thus, thrust this work centers on poverty strategies selected Churches Anambra State: namely how institution participates some economic activities, skill acquisition programmes, empowerment among others view controlling scourge poverty. The research methods...

BACKGROUND:Intravesical bacillus Calmette-Guerin (BCG) is used in the treatment and prophylaxis of carcinoma situ urinary bladder for primary or recurrent stage Ta T1 papillary tumors following transurethral resection. Significant systemic complications are rare but have been reported. CASE REPORT:We describe this case Mycobacterium bovis psoas abscess worsening abdominal aortic aneurysm BCG therapy cancer. A 76-year-old male presented with a fever few days. He had computed tomography (CT)...

Abstract This work focuses on comparative investigation of three different doped surfaces a nano‐cage C 59 As, Ga and Ge to understand their sensitivity ability adsorbed uric acid (UA). is done using the density functional theory (DFT) computation, employing ωB97XD/def2SVP level theory. After interaction with UA, FMO results reveal that UA@C As more reactive Eg=5.1911 eV stable Eg=5.3304 eV, while relatively Eg=5.2145 eV. Geometric optimization analysis reveals shows best least adsorption...

Spirituality connotes praxis informed by religious or faith convictions. This can transform the individual and society at large. Christian spirituality is centered on how a person’s relationship with God of Jesus Christ informs directs one’s approach to existence engagement world. The ecosystem concerns humanity it invariably influenced praxis. reality climate change convincing many people that humankind’s common homeland needs be treated care respect if created beings are have congenial...

Abstract In this research work, the extraction, characterization, device fabrication, and theoretical investigation of Hibiscus sabdariffa plant extract, for possible application in solid DSSCs, are reported. The extract was analyzed using FT-IR UV–Vis spectrophotometry. Polyaniline on graphene used as counter electrode whereas titanium (IV) oxide photo anode fabricated DSSCs. experimental results obtained open circuit voltage, short current density, field factor, maximum power conversion...

African Americans bear a greater burden of hypertension. Understanding prevailing epidemiologic patterns can facilitate the implementation and successful outcome community programs. The authors assessed practice antihypertensive drug utilization blood pressure (BP) control in predominantly American population Brooklyn, NY, from January 1 to 31, 2008. A total 416 (53.1%) had hypertension, with mean age 61 years, 267 (64%) were women. In general, 212 (50.9%) at goal BP 59.9% those taking least...

Background: Anaerobic bacterial meningitis is rare. It extremely unusual without a portal of entry as most cases reported have been associated with trauma or neurosurgery. Case Report: We describe this rare case clostridium and plesiomonas sepsis in an immunocompetent adult. A 71 year old man diabetes presented acute onset severe headaches, obtundation signs hemolysis following 2 week game hunting trip the Swiss Alps. His clinical status progressed rapidly; he died 3 hours after initial...

Religious language has the potential to shape mindsets of human beings. Further, it is probable that religious utterances will affect adherents’ responses real-life situations. With aid speech-act theory, this article investigates how used by church leaders in framing public discourse modified some social perceptions Christians during COVID-19 pandemic. The research shows impacts and limitations theory concerning influence over their adherents era. In dialogue with CAN-CRS Report, differed...

The West Nile virus (WNV) is the leading cause of mosquito-borne disease in United States. Bell's palsy (BP) a clinical syndrome associated with viral infections, but an association not well-described, only two cases reported literature. We present case 68-year-old woman presenting fevers and encephalopathy. Cerebrospinal fluid was positive for WNV. Following improvement, she developed facial weakness diagnosed BP secondary to WNV infection. Identifying infection may have significant...