A5009875260- Conducting polymers and applications
- Perovskite Materials and Applications
- Organic Electronics and Photovoltaics
- Crystallization and Solubility Studies
- X-ray Diffraction in Crystallography
- Molecular Junctions and Nanostructures
- Click Chemistry and Applications
- Organic Light-Emitting Diodes Research
- Catalytic Alkyne Reactions
- Chemical Synthesis and Analysis
- Cyclopropane Reaction Mechanisms
- Chalcogenide Semiconductor Thin Films
- Electrochemical Analysis and Applications
- Multicomponent Synthesis of Heterocycles
- Synthesis of Tetrazole Derivatives
- Synthesis and Biological Evaluation
- Advanced biosensing and bioanalysis techniques
- Quantum Dots Synthesis And Properties
- Synthesis and Reactivity of Heterocycles
- Organic and Molecular Conductors Research
- Photochemistry and Electron Transfer Studies
- Synthesis and biological activity
- Cancer therapeutics and mechanisms
- Advanced Memory and Neural Computing
- Synthetic Organic Chemistry Methods
National Central University
2019-2024
Khalifa University of Science and Technology
2024
National Research Institute of Chinese Medicine
2021
Ministry of Health and Welfare
2021
National Dong Hwa University
2013-2016
Hualien Tzu Chi Medical Center
2016
Abstract Four X‐shaped quinoxaline‐based organic dyes, PQx (1), TQx, (2), PQxD (3), and TQxD (4) (D = dye sensitizers) are developed served as p ‐type self‐assemble monolayer (SAM) for tin perovskite solar cells (TPSC). Thermal, optical, electrochemical properties of these SAMs thoroughly investigated characterized. Tin layers successfully deposited on four SAM surfaces according to a two‐step approach the devices exhibit power conversion efficiency in order (8.3%) > TQx (8.0%) (7.1%)...
The embedding of non-fullerene acceptor INDCDTT-b16 to PM6:Y6 binary blend devices enables the adjustment morphology, leading improvements in carrier mobility, bimolecular/trap-assisted recombination, and charge collection, promotes a PCE 16.27%.
High-performance and durable perovskite solar cells (PSCs) have advanced rapidly, enabled in part by the development of superior interfacial hole-transporting layers (HTLs). Here, a new series 2,3-diphenylthieno[3,4-b]pyrazine (DPTP)-based small molecules containing bis- tetrakis-triphenyl amino donors (1–3) was synthesized from simple, low-cost, readily available starting materials. The matched energy levels, ideal surface topographies, high hole mobilities 8.57 × 10–4 cm2 V–1 S–1, stable...
Abstract The effect of heteroalkyl (‐XR, X = Se, S, O) substitution on a series molecular semiconductors having 3,3′‐diheteroalkyl‐2,2′‐bithiophene (XBT) central core is studied. Thus, the selenotetradecyl (‐SeC 14 H 29 ) SeBT investigated by end‐functionalization with two dithienothiophene (DTT), thienothiophene (TT), and thiophene (T) units to give SeBTs 1 – 3 , respectively, for π‐conjugation examination. Furthermore, selenodecyl 10 21 selenohexyl 6 13 cores end‐capped DTTs 1B 1C are...
Well-performing organic–inorganic halide perovskites are susceptible to poor efficiency and instability due their various defects at the interphases, grain boundaries (GBs), surfaces. In this study, an in situ method is utilized for effectively passivating under-coordinated Pb2+ of perovskite with new non-fullerene acceptors (NFAs) (INXBCDT; X = H, Cl, Br) through carbonyl cyano functional groups during antisolvent dripping process. It reveals that bicyclopentadithiophene (BCDT) core highly...
A novel quinoidal thienoisoindigo (TII)-containing small molecule family with dicyanomethylene end-capping units and various alkyl chains is synthesized as n-type organic molecules for solution-processable field effect transistors (OFETs). The molecular structure of the 2-hexyldecyl substituted derivative, TIIQ-b16, determined via single-crystal X-ray diffraction shows that TIIQ core planar exhibits layers stacked in a "face-to-face" arrangement short intermolecular distances 3.28 Å. very...
New solution processable 3,5-dithioalkyl dithienothiophene (DSDTT) based small molecular semiconductors end functionalized with various (fused) thiophenes including (DTT), thienothiophene (TT), and thiophene (T) are synthesized characterized in organic field effect transistors (OFETs). The new DSDTT core was via a one-pot [1 + 1 1] methodology. For comparison, non-thiolated 3,5-dialkyl (DRDTT) molecules also prepared characterized. Optical, electrochemical, computed electronic structures of...
Abstract This work presents a series of novel quinoidal organic semiconductors based on diselenophene‐dithioalkylthiophene ( DSpDST ) conjugated cores with various side‐chain lengths (‐thiohexyl, ‐thiodecyl, and ‐thiotetradecyl, designated DSpDSTQ‐6 , DSpDSTQ‐10 DSpDSTQ‐14 respectively). The purpose this research is to develop solution‐processable using dicyanomethylene end‐capped small molecules for field effect transistors (OFETs) application. physical, electrochemical, electrical...
The molecular structure of INDCDT-b8-Cl, which is rich in carbonyl and cyano functional groups, used as an interfacial modified layer for PSCs.
Abstract Three functionalized thienopyrazines ( TP s), TP‐MN 1 ), TP‐CA 2 and TPT‐MN 3 ) were designed synthesized as self‐assembled monolayers (SAMs) deposited on the NiOx film for tin‐perovskite solar cells (TPSCs). Thermal, optical, electrochemical, morphological, crystallinity, hole mobility, charge recombination properties, well DFT‐derived energy levels with electrostatic surface potential mapping of these SAMs, have been thoroughly investigated discussed. The structure single crystal...
We developed three Self-assembled monolayer (SAM) molecules, PTz2 (1), and PTz (2) PTzBr (3) investigated the mixing of guanidinium (GA) methylammonium (MA) cations at A-site, alongside...
Abstract This review highlights our recent efforts in the development of organic semiconductors based on anthradithiophene (ADT), dithienothiophene (DTT), tetrathienoacene (TTA), benzothienodithiophene (BTDT), benzothienothiophene (BTT), chalcogen‐planarized BT, and some quinoidal oligothiophenes for application thin‐film transistors (OTFTs). We visualized various strategies that have been employed molecular architecture to improve stability as well solubility, energy levels are tuned...
New dicyclopentadithienothiophene (DCDTT) based non-fullerene acceptors 1–3 are introduced into PSC films. The INCl-DCDTT−perovskite hybrid film exhibits an excellent power conversion efficiency of 21.39%.
A one-pot green and highly efficient method for the synthesis of propargylamines distereoselective fused triazoles <italic>via</italic> three-component coupling in presence manganese(<sc>ii</sc>) chloride a catalyst-free 1,3-dipolar cycloaddition reaction without using co-catalyst is reported.
The 3,5-dithiooctyl dithienothiophene based small molecular semiconductor DDTT-DSDTT (1), end functionalized with fused (DTT) units, was synthesized and characterized for organic field effect transistors (OFET). thermal, optical, electrochemical, computed electronic structural properties of 1 were investigated contrasted. single crystal structure reveals the presence intramolecular locks between S(alkyl)···S(thiophene), a very short S–S distance 3.10 Å, planar core. When measured in an OFET...
Regioregular polythiophenes have been widely used in organic electronic applications due to their solution processability with chemical modification through side chain engineering, as well microstructural organization and good hole transport properties. Here, we introduce alkylthio chains, (poly[(3-alkylthio)thiophene]s; P3ATTs), strong noncovalent sulfur molecular interactions, main thienyl backbones. These P3ATTs were compared alkyl-substituted polythiophene (poly(3-alkylthiophene); P3AT)...
Three functionalized thienopyrazines (TPs), TP-MN (1), TP-CA (2), and TPT-MN (3) were designed synthesized as self-assembled monolayers (SAMs) deposited on the NiOx film for tin-perovskite solar cells (TPSCs). Thermal, optical, electrochemical, morphological, crystallinity, hole mobility, charge recombination properties, well DFT-derived energy levels with electrostatic surface potential mapping of these SAMs, have been thoroughly investigated discussed. The structure (1) single crystal was...
Improving perovskite film quality is essential for making solar cells with enhanced performance. A critical bottleneck progress in cell science the lack of a scalable coating method that can be used industrial manufacturing. This study investigated combined cooperation methylammonium acetate (MAAc) additive doping precursor solution and mixed nonfullerene small-molecule semiconductor (DCDTT) chlorobenzene an antisolvent spraying treatment preparation ultrasonic spray-coated film....
Abstract A practical and efficient two‐step protocol for the synthesis of several new 4,6,7,8,8 a ,9‐hexahydropyrrolo[1,2‐ ][1,2,3]triazolo[1,5‐ d ]pyrazines is described. The first step involves AuBr 3 ‐catalyzed three‐component coupling reaction terminal alkynes, aldehydes, amines under solvent‐free conditions to provide requisite propargylamines. tolerates high structural diversity, requires only short times, gives diastereoselectivities, environmentally benign. Furthermore,...
Abstract Three new solution‐processable organic semiconductors ( 1–3 ) are synthesized and characterized for p‐type field effect transistors (OFETs). The backbone of these small molecules is modified by expanding the central core conjugation from thienothiophene TT to dithienothiophene DTT tetrathienoacene TTA ), which end‐capped with soluble β‐substituted alkyl chains dithienothiophenes DTTR generate DTTR‐TT 1 DTTR‐DTT 2 DTTR‐TTA 3 ). highest mobility 0.016 cm V −1 s achieved using...
Abstract Triphenylamine‐based Y‐shaped organic sensitizers, specifically TPA‐MN ( 1 ), TPA‐CA (2 TPAT‐MN 3 and TPAT‐CA 4 are synthesized utilized as p ‐type self‐assembled monolayers (SAMs) for tin‐based perovskite solar cells (TPSCs). These SAMs developed using low‐cost starting materials, primarily from triphenylamine (TPA) components. An extensive analysis is conducted to examine the crystalline, morphological, thermal, optical, electrochemical, optoelectronic characteristics of – ,...
Abstract A simple method to synthesize propargylamines along with the highly diastereoselective synthesis of a series 4,6,7,8,8a,9‐hexahydropyrrolo[1,2‐ ][1,2,3]triazolo[1,5‐ d ]pyrazines has been developed. The three‐component coupling aldehydes, amines, and alkynes (A 3 ‐coupling), which proceeds through C−H activation process tin(II) chloride as catalyst, metal‐free [3+2] cycloaddition reaction were used prepare fused heterocycles, respectively, without need cocatalyst or activator. is...
The ternary strategy boosts the performance of organic photovoltaics (OPVs) by optimizing light-harvesting, energy level alignment, and blend morphology. Herein, three non-fullerene acceptors (NFAs), IN-DTPT-b20 (1), INF-DTPT-b20(2) INCl-DTPT-b20 (3)...