Miłosz Siczek

ORCID: 0000-0002-4214-6492
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About
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Research Areas
  • Crystallization and Solubility Studies
  • X-ray Diffraction in Crystallography
  • Magnetism in coordination complexes
  • Crystallography and molecular interactions
  • Lanthanide and Transition Metal Complexes
  • Metal complexes synthesis and properties
  • Metal-Organic Frameworks: Synthesis and Applications
  • Metal-Catalyzed Oxygenation Mechanisms
  • Organometallic Complex Synthesis and Catalysis
  • Asymmetric Hydrogenation and Catalysis
  • Perovskite Materials and Applications
  • Organic and Molecular Conductors Research
  • Crystal structures of chemical compounds
  • Porphyrin and Phthalocyanine Chemistry
  • Luminescence Properties of Advanced Materials
  • Conducting polymers and applications
  • Solid-state spectroscopy and crystallography
  • Polyoxometalates: Synthesis and Applications
  • Catalytic Cross-Coupling Reactions
  • Radiopharmaceutical Chemistry and Applications
  • Catalytic C–H Functionalization Methods
  • Synthetic Organic Chemistry Methods
  • Nanocluster Synthesis and Applications
  • Inorganic Chemistry and Materials
  • Catalytic Alkyne Reactions

University of Wrocław
2015-2024

Faculty (United Kingdom)
2014-2021

Wroclaw University of Applied Informatics "Horizon"
2015-2020

ShanghaiTech University
2020

Riga Technical University
2020

A.E. Arbuzov Institute of Organic and Physical Chemistry
2020

Russian New University
2020

Peoples' Friendship University of Russia
2020

A.E. Favorsky Irkutsk Institute of Chemistry
2020

The X-ray single crystal structure determination of Lu2O3 sesquioxide and polycrystalline transparent ceramic fabricated by the unconventional spark plasma sintering (SPS) method is presented for first time. High quality crystals samples were obtained using both micropulling-down (μ-PD) laser heated pedestal growth (LHPG) technique. SPS promising obtaining high-density ceramics with fine grains at a relatively low temperature within short holding structural characterizations helped to...

10.1021/cg500225v article EN Crystal Growth & Design 2014-05-09

Nine dioxidomolybdenum(VI) complexes were synthesized through the reactions of MoO 3 with tridentate hydrazone Schiff base ligands obtained from aromatic acid hydrazides (3‐hydroxy‐2‐naphthoic hydrazide, 4‐pyridinecarboxylic hydrazide and 2‐furoic hydrazide) ortho ‐hydroxy aldehyde derivatives (5‐iodo‐2‐hydroxybenzaldehyde, 2‐hydroxy‐1‐naphthaldehyde 2‐hydroxy‐3‐methoxybenzaldehyde). All characterized by elemental analysis spectroscopic methods. The structures seven further elucidated...

10.1002/ejic.201601359 article EN European Journal of Inorganic Chemistry 2016-12-13

Layered hybrid halide perovskites are known to be more environmentally stable than their 3D analogues. The enhanced stability is particularly relevant for Dion–Jacobson-type layered due promising photovoltaic performances. However, in contrast the expected resilience moisture, we reveal that structure of Dion–Jacobson perovskite phases based on a 1,4-phenylenedimethanammonium spacer disrupted humid conditions using X-ray diffraction, UV–vis spectroscopy, thermogravimetric analysis, and...

10.1021/acsenergylett.0c02344 article EN ACS Energy Letters 2020-12-31

A diradical/biradical character of organic derivatives is one the key aspects contemporary research focusing on fundamental studies followed by potential applicability relying unique optical, electronic, or magnetic properties assigned to unpaired electrons. precise involvement two p-phenylenes into a cyclophane-like conjugated, diatropic system creates flexible molecule with different characters both subunits (benzene and quinone) imprinting structure Kekulé delocalized system. dynamic...

10.1002/anie.202400780 article EN cc-by Angewandte Chemie International Edition 2024-02-26

The synthesis and magnetic properties of 13 new homo- heterometallic Co(II) complexes containing the artificial amino acid 2-amino-isobutyric acid, aibH, are reported: [CoII4(aib)3(aibH)3(NO3)](NO3)4·2.8CH3OH·0.2H2O (1·2.8CH3OH·0.2H2O), {Na2[CoII2(aib)2(N3)4(CH3OH)4]}n (2), [CoII6LaIII(aib)6(OH)3(NO3)2(H2O)4(CH3CN)2]·0.5[La(NO3)6]·0.75(ClO4)·1.75(NO3)·3.2CH3CN·5.9H2O (3·3.2CH3CN·5.9H2O),...

10.1021/ic2024007 article EN Inorganic Chemistry 2011-12-22

A Cu(II) complex, [Cu(HL)(NO3)(CH3OH)]·CH3OH (1), was obtained by the reaction of Cu(NO3)2·3H2O and H2L in methanol solvent (H2L is (E)-4-amino-N'-(2-hydroxy-3-methoxybenzylidene)benzohydrazide). compound 1 were characterized various spectroscopic analyses molecular structure determined single-crystal X-ray analysis. The results indicated product a mononuclear complex contains free NH2 functional group on ligand. used for preparation heterogeneous catalyst supporting it functionalized silica...

10.1039/d2dt03054c article EN Dalton Transactions 2022-11-29

The light induced [2+2] cyclization of the flexible coumarin-based ligand ( L ) converts spin crossover active HS1DLS1 mononuclear system [Fe( 6 ](BF 4 2 ·4CH 3 CN 1 into high 1D coordination polymer ). The...

10.1039/d4sc05587j article EN cc-by Chemical Science 2025-01-01

Employment of the artificial amino acid 2-amino-isobutyric acid, aibH, in CuII and CuII/LnIII chemistry led to isolation characterization 12 new heterometallic heptanuclear [Cu6Ln(aib)6(OH)3(OAc)3(NO3)3] complexes consisting trivalent lanthanide centers within a hexanuclear copper trigonal prism (aibH = 2-amino-butyric acid; Ln Ce (1), Pr (2), Nd (3), Sm (4), Eu (5), Gd (6), Tb (7), Dy (8), Ho (9), Er (10), Tm (11), Yb (12)). Direct curent magnetic susceptibility studies have been carried...

10.1021/ic300538q article EN Inorganic Chemistry 2012-05-01

Syntheses, structure and spectroscopic studies of a new cobalt complex with hydrazine ligand. The first report on highly oxidative resistant in the ORR electrocatalysis at liquid–liquid interface.

10.1039/c5cp04695e article EN Physical Chemistry Chemical Physics 2015-01-01

The sulfonic esters of N-oxyimides are a group compounds with wide range biological activities, as well unique reactivity toward amines. They undergo this reaction primary amines and other nucleophilic reagents according to Lossen-like rearrangement. is initiated by attack on carbonyl in the succinimide ring followed isocyanate formation, which next interacts another nucleophile molecule forming an addition product (e.g., ureido or urethane derivative). However, secondary also susceptible...

10.3389/fchem.2021.662533 article EN cc-by Frontiers in Chemistry 2021-04-15

The use of 2-amino-isobutyric acid in Co/Ln chemistry has led to the isolation two unique [Co(II)(6)Ln(III)] 3d-4f metallic cages which Ln(III) centre (Ln = Eu, Dy) is encapsulated within a Co(II)(6) trigonal prism.

10.1039/c1dt10052a article EN Dalton Transactions 2011-01-01

Two organic–inorganic hybrid halobismuthates(<sc>iii</sc>), (NH<sub>2</sub>CHNH<sub>2</sub>)<sub>3</sub>[Bi<sub>2</sub>Cl<sub>9</sub>] <bold>(FBC)</bold> and (NH<sub>2</sub>CHNH<sub>2</sub>)<sub>3</sub>[Bi<sub>2</sub>Br<sub>9</sub>] <bold>(FBB)</bold>, have been prepared with their structures revealed by single-crystal X-ray diffraction at various temperatures.

10.1039/c9dt02916h article EN Dalton Transactions 2019-01-01
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