A5100370173- Metal-Organic Frameworks: Synthesis and Applications
- Metal complexes synthesis and properties
- Magnetism in coordination complexes
- Crystal structures of chemical compounds
- Lanthanide and Transition Metal Complexes
- Zeolite Catalysis and Synthesis
- Polyoxometalates: Synthesis and Applications
- Organometallic Compounds Synthesis and Characterization
- Crystallography and molecular interactions
- Vanadium and Halogenation Chemistry
- Synthesis and biological activity
- Metal-Catalyzed Oxygenation Mechanisms
- Catalytic Processes in Materials Science
- Synthesis and Characterization of Heterocyclic Compounds
- Supramolecular Self-Assembly in Materials
- Inorganic and Organometallic Chemistry
- Mesoporous Materials and Catalysis
- Supramolecular Chemistry and Complexes
- Inorganic Chemistry and Materials
- Fluorine in Organic Chemistry
- Molecular Sensors and Ion Detection
- Catalysis and Hydrodesulfurization Studies
- Porphyrin and Phthalocyanine Chemistry
- Nonlinear Optical Materials Research
- Synthesis of Organic Compounds
Jiaxing University
2023
Luoyang Normal University
2023
Jiangsu University of Technology
2019-2022
Anyang Institute of Technology
2017-2022
Liaoning Shihua University
2020-2021
North China Electric Power University
2021
Zhoukou Normal University
2017-2020
Guizhou University
2020
Qinghai Normal University
2015-2017
Weifang University
2014-2016
Silicoaluminophosphates (SAPO) with different framework structures and amounts of Brønsted acid sites, that is, SAPO-34, SAPO-41, SAPO-11, SAPO-46, were synthesized studied as catalysts for the methanol-to-olefin (MTO) conversion. Besides well-known SAPO-34 catalyst, also SAPO-41 exhibits a good MTO performance methanol conversion 100% selectivity to light olefins about 70% at reaction temperature 723 K, which maintains up time-on-stream 10 h. The sites silicoaluminophosphate employed in...
The photocatalytic activities of two novel different 2-D coordination polymers constructed from 5-hydroxy-1<italic>H</italic>-pyrazole-3-carboxylic acid ligand have been explored.
The simultaneous use of bicarboxylate- and bipyridine-containing linear ligands to react with d10 metals affords four new polymeric compounds, [Zn(cis-chdc)(bpp)]·6H2O (1), [Zn(cis-chdc)(bpmp)] (2), [Cd2(cis-chdc)2(bpmp)(H2O)2] (3) [Cd3(tp)3(bpp)2]•2DMF•6H2O (4) (H2chdc = 1,4-cyclohexanedicarboxylic acid; bpp 1,3-bis(4-pyridyl)propane; bpmp N,N′-bis(4-pyridylmethyl)piperazine; H2tp terephthalic acid), which have been structurally characterized by elemental analysis, IR, TG, powder X-ray...
A new Ca(II) coordination polymer, [{CaL2·(H2O)2·2H2O}]n (1) (L = 2-[(E)-(2-furoylhydrazono)methyl]benzenesulfonate), has been obtained by one-pot method, and characterized elemental analysis, IR spectrum, X-ray single-crystal diffraction. The results showed that the crystallizes in orthorhombic space group with P21212, a 16.355(3) Å, b 17.478(4) c 5.4549(11) α =β γ 90.00°, V 1559.3(5) Å3, Z 2, Mr 698.69, Dc 1.488 g/cm3, T 293(2) K, F(000) 724, μ(MoKa) 0.408 mm−1, R 0.0703 wR 0.1848. ion is...
Abstract Adsorption of N 2 on Mo 6 S 8 q _V x clusters ( =0, 1, 2; ±1) were systematically studied by density functional theory calculations with dispersion corrections. It was found that the can be chemisorbed and undergo non‐dissociative activation single or double metal atoms. The adsorption are influenced types (V Mo), coordination modes charge states clusters. Particularly, anionic − have remarkable ability to fix activate . In , two V atoms prefer adsorb adjacent S−Mo−S hollow sites,...
A novel secondary building unit, a Russian nesting doll [Ln4@Ln4] tetrahedron, was developed for metal–organic frameworks with an unprecedented binodal (3,20)-connected 3D network by using linear bridge-linking ligand.
In order to study the catalytic activity of Cu(II) coordination polymer material, a novel 1D chained [CuL(bipy)(H2O)5]n (A1) (H2L = 1,4-phenylenediacetic acid, bipy 2,2’-bipyridine), has been prepared by reaction 2,2’-bipyridine, Cu(CH3COO)2·H2O and NaOH. The composition A1 was determined elemental analysis, IR spectra single crystal X-ray diffraction. results characterization show that each atom adopts six-coordination forms distorted octahedral configuration. reusability catalyst for A3...
A new 1D Cd(II) coordination polymer, [{CdL2(H2O)}·(H2O)3]n (HL = N-nicotinoylglycine), has been synthesized by the assembly of Cd(NO3)2·4H2O with N-nicotinoylglycine, and its composition was determined elemental analysis, infrared, X-ray single-crystal diffraction analysis. In this complex, is seven-coordinated two N atoms N-nicotinoylglycine anions, four O one atom a coordinated water molecule. The complex forms looped polymer bridging anion. luminescent property ligand also studied.
A new 1D chained Ca(II) coordination polymer—namely, [CaL2(H2O)2]n (HL = 3,5-bis(4-pyridylmethoxy)benzoic acid)—was synthesized though the reaction of Ca(ClO4)2·4H2O, acid and NaOH in H2O/CH3CH2OH (v:v 1:2) solution. Its structure was determined by elemental analysis, infrared spectrum, single-crystal XRD. Structural analyses show that each ion is eight-coordinated six oxygen atoms four 3,5-bis(4-pyridylmethoxy)benzoate ligands two coordinated H2O molecules to form a square-antiprismatic...