A5031425757- X-ray Diffraction in Crystallography
- Crystallization and Solubility Studies
- Synthesis and Properties of Aromatic Compounds
- Porphyrin and Phthalocyanine Chemistry
- Molecular Sensors and Ion Detection
- Crystallography and molecular interactions
- Chemical Synthesis and Analysis
- Molecular spectroscopy and chirality
- Photochromic and Fluorescence Chemistry
- Axial and Atropisomeric Chirality Synthesis
- Asymmetric Synthesis and Catalysis
- Magnetism in coordination complexes
- Origins and Evolution of Life
- Mass Spectrometry Techniques and Applications
- Luminescence and Fluorescent Materials
- Analytical Chemistry and Chromatography
- Radiopharmaceutical Chemistry and Applications
- Electron Spin Resonance Studies
- Photoreceptor and optogenetics research
- Photosynthetic Processes and Mechanisms
- Molecular Junctions and Nanostructures
University of Wrocław
2021-2024
University of Oxford
2016-2020
Oxfam
2019
Science Oxford
2017
A novel strategy for the recognition of anions in water using charge-neutral σ-hole halogen and chalcogen bonding acyclic hosts is demonstrated first time. Exploiting intrinsic hydrophobicity bond donor atoms integrated into a foldamer structural molecular framework containing hydrophilic functionalities, series water-soluble receptors was constructed an anion investigation. Isothermal titration calorimetry (ITC) binding studies with range revealed to display very strong selective large,...
Diradicaloid helicenes constructed formally by non-benzenoid double π-extension of phenanthrene were synthesized a common strategy involving electrophilic benzannulation. Steric effects in the second benzannulation step led to considerable structural diversity among products, yielding symmetrical dinor[7]helicene 1 and two isomeric unsymmetrical 2 3, containing nor[5]helicene [4]helicene fragment, respectively, addition nor[6]helicene motif. Geometries, configurational dynamics, electronic...
A tetradentate halogen bond donor foldamer receptor framework is shown to exhibit enhanced anion recognition and chiral discrimination properties.
A novel halogen-bonding foldamer molecular film was utilised to achieve anion sensing in pure water <italic>via</italic> non-faradaic capacitance spectroscopy.
Abstract Replication and compartmentalization are fundamental to living systems may have played important roles in life’s origins. Selection compartmentalized autocatalytic might provide a way for evolution occur life arise from non-living systems. Herein we report selection system of self-reproducing lipids where predominant species can emerge pool competitors. The lipid replicators metastable their out-of-equilibrium population be sustained by feeding the with starting materials. Phase...
A triskelion-shaped triradical triindeno[1,2-a:1',2'-g : 1'',2''-m]triphenylen-7-yl (1) and its internally fused derivative (2) obtained by oxidative cyclization were prepared in a straightforward synthetic sequence. Both compounds confirmed to be triradicals possess intramolecular antiferromagnetic exchange interactions between spins, displaying spin-frustrated doublet ground state with doublet-quartet energy gaps of -0.14 kcal/mol for 1 -0.06 2. Despite their open-shell character, they...
Abstract Diradicaloid helicenes constructed formally by non‐benzenoid double π‐extension of phenanthrene were synthesized a common strategy involving electrophilic benzannulation. Steric effects in the second benzannulation step led to considerable structural diversity among products, yielding symmetrical dinor[7]helicene 1 and two isomeric unsymmetrical 2 3 , containing nor[5]helicene [4]helicene fragment, respectively, addition nor[6]helicene motif. Geometries, configurational dynamics,...
Abstract A triskelion‐shaped triradical triindeno[1,2‐ a :1′,2′‐ g : 1′′,2′′‐ m ]triphenylen‐7‐yl ( 1 ) and its internally fused derivative 2 obtained by oxidative cyclization were prepared in straightforward synthetic sequence. Both compounds confirmed to be triradicals possess intramolecular antiferromagnetic exchange interactions between spins, displaying spin‐frustrated doublet ground state with doublet‐quartet energy gaps of −0.14 kcal/mol for −0.06 . Despite their open‐shell character,...
Abstract Review: 247 refs.