A5081732598- Electrocatalysts for Energy Conversion
- Advanced Photocatalysis Techniques
- Catalytic C–H Functionalization Methods
- Advanced battery technologies research
- Fuel Cells and Related Materials
- Crystallization and Solubility Studies
- X-ray Diffraction in Crystallography
- Sulfur-Based Synthesis Techniques
- Crystal structures of chemical compounds
- Radical Photochemical Reactions
- Cyclopropane Reaction Mechanisms
- Catalytic Processes in Materials Science
- Synthesis and biological activity
- Advanced Nanomaterials in Catalysis
- Catalytic Cross-Coupling Reactions
- Carbon and Quantum Dots Applications
- Chemical Synthesis and Analysis
- Asymmetric Hydrogenation and Catalysis
- Glass properties and applications
- Copper-based nanomaterials and applications
- Luminescence Properties of Advanced Materials
- Luminescence and Fluorescent Materials
- Catalytic Alkyne Reactions
- Covalent Organic Framework Applications
- Analytical chemistry methods development
Henan University
2016-2025
Nanjing Tech University
2006-2025
Fluorochem (United States)
2025
Inner Mongolia University of Technology
2024-2025
Zhejiang Normal University
2025
Qingdao University of Technology
2021-2025
Anhui University of Science and Technology
2025
Beijing University of Technology
2025
Tsinghua University
2021-2025
Harbin Institute of Technology
2019-2024
A highly diastereo- and enantioselective BOX/Cu(II)-catalyzed C2,C3-cyclopentannulation of indoles with donor–acceptor cyclopropanes has been developed on the basis asymmetric formal [3 + 2] cycloaddition indoles. This reaction provides rapid facile access to a series enantioenriched cyclopenta-fused indoline products can be further extended construction tetracyclic pyrroloindolines. The synthetic potential was demonstrated in four-step synthesis core structure borreverine.
An efficient [4 + 3] cycloaddition reaction of D–A cyclopropanes with dienes has been successfully developed. The proceeds well various dienolsilyl ethers in the presence Lewis acid, delivering a variety cycloheptenes and [n,5,0]carbobicycles excellent stereoselectivity. asymmetric version this is also realized using newly designed chiral Cy-TOX ligand, providing new approach to access optically active [n,5,0]carbobicycles. Mechanisic study reveals that involves stepwise pathway, which...
The systematic summarization of synthesis–structure–property–mechanism correlations provides guidance for the rational design an atomically dispersed M–N–C catalyst ORR.
The most promising approach to mitigating the greenhouse effect and tackling energy crisis is convert carbon dioxide into valuable liquid fuels through artificial photosynthesis. Nevertheless, photocatalysts have poor product selectivity, low catalytic performance, cycling stability. Herein, we synthesized novel UiO-66(Zr/Ce) nanosheets bonding on g-C3N4 [g-C3N4/UiO-66(Zr/Ce)] by an in situ method using single atoms of Zr Ce as metal sources, are linked via N–Zr/Ce–O bonds g-C3N4/UiO-66...
Photocatalytic reduction of carbon dioxide (CO2) into high-value chemicals is a very effective way to solve the greenhouse effect, improve utilization ratio resources, and cope with energy crisis. However, low catalytic activity poor product selectivity catalyst have been largely restricting its large-scale application. Herein, we successfully synthesized an ultra-thin two-dimensional trimetallic metal–organic framework (NiZrCu-BDC) nanosheet as photocatalyst for CO2 reduction, average...
Abstract Although metal single‐atom (SA)‐based nanomaterials are explored as sonosensitizers for sonodynamic therapy (SDT), they normally exhibit poor activities and need to combine with other therapeutic strategies. Herein, the deposition of SAs on oxygen vacancy (OV)‐rich WO 3− x nanosheets generate a synergistic effect efficient SDT is reported. Crystalline 3 OV‐rich first prepared by simple calcination ·H 2 O under an air N atmosphere, respectively. Pt, Cu, Fe, Co, Ni then deposited...
An efficient strategy for the preparation of aryl phosphonates via blue-light-promoted single electron transfer process an EDA complex between phosphites and thianthrenium salts has been demonstrated. The corresponding substituted were obtained in good to excellent yields, byproduct thianthrene can be recovered reused quantity. This developed method realizes construction through indirect C-H functionalization arenes, which potential application value drug discovery development.
The difunctionalization of alkenes using aryl thianthrenium salts as the sources has been reported sporadically. However, four-component on basis not thus far and still remains a challenge. Herein, visible light/copper catalysis-enabled reaction salts, DABCO·(SO
A Ru-catalyzed defluorinative cyclization of polyfluoroalkyl tetralones has been developed under visible-light irradiation for the precise assembly γ-pyrones featuring α-perfluoroalkyl and β-fluorine substituents. Selective functionalization five C(sp3)–F bonds at three carbon sites on perfluoroalkyl chain provides a new mode utilizing polyfluorides as versatile synthons to access difficult-to-obtain heterocyclic scaffolds. Moreover, sulfinate salt serves dual roles an oxygen source creating...
A new fuse: The title reaction was realized using a bisoxazoline (BOX)/CuII catalyst. This works well with cyclic enol silyl ethers of different sizes, and can be extended to dienol benzene-fused substrates, thus providing an effective general access range 3a-hydroxy [n.3.0]carbobicycles which are found as core structure in many natural products. TBDPS=tert-butyldiphenylsilyl. As service our authors readers, this journal provides supporting information supplied by the authors. Such materials...
MgO and ZnCl<sub>2</sub> dual templates significantly optimize the accessibility of Fe–N<sub>x</sub> sites mass transfer.
A heterogeneous visible-light-induced tandem radical addition–cyclization of isocyanides by photoactive covalent organic frameworks was developed, delivering diverse phenanthridines with high reaction efficiency and easy catalyst recyclability.
An iron-catalyzed dehydrogenative sp3–sp2 coupling of acetonitrile and 2-arylimidazo[1,2-a]pyridine has been realized, which can serve as a novel approach toward heteroarylacetonitriles. The merit this strategy is illustrated by the breadth functional groups tolerated in transformation fast access to pharmaceuticals (such zolpidem) directly from