A5027902006- Catalysis and Hydrodesulfurization Studies
- Catalysis for Biomass Conversion
- Asymmetric Hydrogenation and Catalysis
- Nanomaterials for catalytic reactions
- Catalytic C–H Functionalization Methods
- Synthetic Organic Chemistry Methods
- Cyclopropane Reaction Mechanisms
- Surface Chemistry and Catalysis
- Epoxy Resin Curing Processes
- Synthesis and Catalytic Reactions
- Supercapacitor Materials and Fabrication
- Asymmetric Synthesis and Catalysis
- Biofuel production and bioconversion
- Photopolymerization techniques and applications
- Mesoporous Materials and Catalysis
- Synthesis and properties of polymers
Novosibirsk State University
2021-2023
Heilongjiang University
2018-2021
The Synergetic Innovation Center for Advanced Materials
2020
Lanzhou Institute of Chemical Physics
2020
Suzhou Research Institute
2020
Chinese Academy of Sciences
2010-2020
Nanjing Tech University
2020
Beijing National Laboratory for Molecular Sciences
2010-2011
Institute of Chemistry
2010-2011
Northwestern Polytechnical University
2007
固定二氧化碳(CO2)的工业过程远远落后于人类活动产生的碳排放量.由于二氧化碳是一种丰富、无毒且廉价易得的碳资源,因此开发出将二氧化碳转化为有价值的产品,以实现可持续发展的化学合成是非常有意义的.基于过渡金属催化和有机催化活化CO2的机理研究,近年来已开发出多种有效的CO2的不对称化学固定方法.讨论了通过CO2的不对称化学固定实现的小分子化合物的手性合成的进展.通过阐述催化剂、CO2和底物之间的相互作用,旨在激发CO2不对称转化的新型催化系统的设计.
Levulinic acid and its esters (e.g., ethyl levulinate, EL) are platform chemicals derived from biomass feedstocks that can be converted to a variety of valuable compounds. Reductive amination levulinates with primary amines H2 over heterogeneous catalysts is an attractive method for the synthesis N-alkyl-5-methyl-2-pyrrolidones, which environmentally friendly alternative common solvent N-methyl-2-pyrrolidone (NMP). In present work, catalytic properties different nickel phosphide supported on...
Abstract A variety of acyclic chiral dienes were synthesized in a single step via palladium(0)‐catalyzed asymmetric allylic and homoallylic CH diamination terminal olefins. The applications such simple as steering ligands for rhodium(I)‐catalyzed 1,4‐additions afforded the corresponding adducts excellent yields up to 85% ee .
Abstract A series of metal phosphides were prepared by temperature programmed reduction and characterized X‐ray diffraction (XRD), scanning electron microscope (SEM), 31 P magic angle spinning nuclear magnetic resonance ( MAS NMR), ammonia desorption (NH 3 ‐TPD) pyridine infrared spectroscopy (Py‐IR), their catalytic performance investigated in the hydrodeoxygenation furfural to form 2‐methylfuran. The effects phosphide initial P/Ni molar ratios on studied, reaction conditions optimized....
A kinetic resolution of hindered Morita–Baylis–Hillman adducts has been successfully achieved in excellent selectivities via Rh(I)-catalyzed asymmetric 1,4-addition/β-hydroxyelimination with the use a chiral sulfinamide/olefin hybrid ligand. This study provides novel and efficient access to both optically active highly functionalized alkenes adducts.