A5091581969- Metal-Organic Frameworks: Synthesis and Applications
- Covalent Organic Framework Applications
- X-ray Diffraction in Crystallography
- Crystallization and Solubility Studies
- Inorganic Fluorides and Related Compounds
- Nanoplatforms for cancer theranostics
- Catalytic Processes in Materials Science
- Machine Learning in Materials Science
- Nanoparticle-Based Drug Delivery
- Advanced Nanomaterials in Catalysis
- Dendrimers and Hyperbranched Polymers
- Mesoporous Materials and Catalysis
- Magnetism in coordination complexes
- Advanced Photocatalysis Techniques
- Electromagnetic wave absorption materials
- Crystallography and molecular interactions
- Zeolite Catalysis and Synthesis
- Chemical Synthesis and Reactions
- Catalysis for Biomass Conversion
- Advanced Sensor and Energy Harvesting Materials
- Membrane Separation Technologies
- Advanced biosensing and bioanalysis techniques
- Catalysis and Oxidation Reactions
- Luminescence and Fluorescent Materials
- Gas Sensing Nanomaterials and Sensors
Basque Center for Materials, Applications and Nanostructures
2019-2025
United Arab Emirates University
2025
Ikerbasque
2019-2024
Utrecht University
2024
Adam Mickiewicz University in Poznań
2024
Université de Versailles Saint-Quentin-en-Yvelines
2010-2024
Centre National de la Recherche Scientifique
2010-2024
École Nationale Supérieure d'Ingénieurs de Caen
2010-2024
Laboratoire Catalyse et Spectrochimie
2010-2024
Université de Caen Normandie
2012-2024
Gas grabber: Reduction of the porous metal–organic framework MIL-100(Fe) (see picture; X−: OH− or F−; red: O trimesate ligands) to form coordinatively unsaturated sites at iron(II) (depicted as a violet circle) is essential for selective gas purification removal impurities. Detailed facts importance specialist readers are published "Supporting Information". Such documents peer-reviewed, but not copy-edited typeset. They made available submitted by authors. Please note: The publisher...
This feature article covers the recent applications of metal‐organic framework nanoparticles (MOF NPs) in photodynamic therapy (PDT) cancer. It aims at giving reader an overview about these two current research fields, i.e., MOF and PDT, highlighting potential synergistic effect that could result from their association. After describing general photophysics photochemistry underlie relationship between photosensitizer (PS) properties PDT requirements is discussed throughout PSs historical...
A series of organically modified iron(III) terephthalate MIL-88B and 4,4′-biphenyl dicarboxylate MIL-88D flexible solids have been synthesized characterized through a combination X-ray diffraction, IR spectroscopy, thermal analysis (MIL stands for Material from Institut Lavoisier). The swelling amplitude the highly MOFs tuned by introducing functional groups onto phenyl rings shows clear dependence on steric hindrance number per aromatic ring. For instance, while introduction four methyl...
Abstract The pores in metal–organic frameworks (MOFs) can be functionalized by placing chemical entities along the backbone and within backbone. This chemistry is enabled architectural, thermal, robustness of ability to characterize them many diffraction spectroscopic techniques. pore MOFs articulated terms site isolation, coupling, cooperation relate that their functions guest recognition, catalysis, ion electron transport, energy transfer, pore‐dynamic modulation, interface construction....
Hierarchically porous metal–organic frameworks with mesoporous cages are demonstrated to behave as promising water adsorbents in energy-efficient dehumidification. Their low temperature desorption properties for huge sorption uptakes essential various applications including desiccant dehumidification and fresh production. Detailed facts of importance specialist readers published "Supporting Information". Such documents peer-reviewed, but not copy-edited or typeset. They made available...
Adsorption and release of the biologically active nitric oxide (NO) was evaluated over a series highly flexible iron(III) dicarboxylate MOFs MIL-88 structure type, bearing fumaric or terephthalic spacer functionalized not by polar groups (NO2, 2OH). As evidenced ex situ X-ray powder diffraction in IR spectroscopy, it appears that if contracted dried forms do expand their structures presence NO, combination very narrow pores trimers iron polyhedra leads to adsorption significant amounts NO...
Abstract Nanoparticles have become a vital part of vast number established processes and products; they are used as catalysts, in cosmetics, even by the pharmaceutical industry. Despite this, however, reliable reproducible production functional nanoparticles for specific applications remains great challenge. In this respect, reticular chemistry provides methods connecting molecular building blocks to whose chemical composition, structure, porosity, functionality can be controlled tuned with...
Abstract Widespread access to greener energy is required in order mitigate the effects of climate change. A significant barrier cleaner natural gas usage lies safety/efficiency limitations storage technology. Despite highly porous metal-organic frameworks (MOFs) demonstrating record-breaking gas-storage capacities, their conventionally powdered morphology renders them non-viable. Traditional powder shaping utilising high pressure or chemical binders collapses porosity creates low-density...
Selective functionalization of the external surface porous nanoparticles is great interest for numerous potential applications in field nanotechnology. Regarding metal–organic frameworks (MOFs), few methods such modifications have been reported literature. Herein, we focus on covalent attachment functional polymers MIL-100(Fe) order to implement properties as increased chemical and colloidal stability or dye-labeling investigation particles by fluorescence based techniques. We prove...
Green chemistry, in particular, the principle of atom economy, has defined new criteria for efficient and sustainable production synthetic compounds. In complex nanomaterials, number embedded functional entities energy expenditure assembly process represent additional compound-associated parameters that can be evaluated from an economic viewpoint. this Perspective, we extend economy to study characterization multifunctionality nanocarriers, which define as "multifunctional efficiency". This...
Here we describe the synthesis and postsynthetic modification of stable β-ketoenamine TpBD(NH2)2 covalent organic framework (COF), having primary amine groups integrated into pore walls. For this purpose initially synthesized nitro version COF, TpBD(NO2)2. Afterward, TpBD(NO2)2 was reduced to afford desired functionality. We demonstrate accessibility robustness by a second step, aminolysis acetic anhydride, obtain corresponding amide form TpBD(NHCOCH3)2. Taking advantage high stability these...
We report the synthesis of MOF@lipid nanoparticles as a versatile and powerful novel class nanocarriers based on metal–organic frameworks (MOFs).
Self-assembly of individual units into multicomponent complexes is a powerful approach for the generation functional superstructures. We present coordinative interaction oligohistidine-tags (His-tags) with metal-organic framework nanoparticles (MOF NPs). By this novel concept, different molecular can be anchored on outer surface MOF NPs in self-assembly process generating multifunctional nanosystems. The article focuses two main objectives: first, detailed investigation assembly and...
ADVERTISEMENT RETURN TO ISSUEPREVCommunicationNEXTExosome-Coated Metal–Organic Framework Nanoparticles: An Efficient Drug Delivery PlatformBernhard Illes†, Patrick Hirschle†, Sabine Barnert§, Valentina Cauda‡, Stefan Wuttke*†⊥, and Hanna Engelke*†View Author Information† Chemistry Department Center for NanoScience, Ludwig-Maximilians-Universität München, 80539 Munich, Germany‡ of Applied Science Technology, Politecnico di Torino, 10129 Italy§ Pharmaceutical Universität Freiburg, 79085...
Reticular chemistry is a growing field of science with multitude practitioners diverse frames thinking, making the need for standard practices and quality indicators ever more compelling.
Abstract Porous silica‐based materials have burgeoning applications ranging from fillers and additives, to adsorbents, catalysts, recently therapeutic agents vaccines in nanomedicine. The preponderance of these is made by sol–gel processing wherein soluble silica precursors are reacted form amorphous networks composed siloxane bonds. facile approach allows for an unlimited variety binary tertiary more complex chemical compositions including organic ligands resulting so‐called...
Abstract Ion homeostasis is essential for cellular survival, and elevated concentrations of specific ions are used to start distinct forms programmed cell death. However, investigating the influence certain on cells in a controlled way has been hampered due tight regulation ion import by cells. Here, it shown that lipid‐coated iron‐based metal–organic framework nanoparticles able deliver release high amounts iron into While often trigger ferroptosis, here, released induces pyroptosis, form...
Metal-organic frameworks (MOFs) are promising platforms for the synthesis of nanoparticles diverse medical applications. Their fundamental design principles allow significant control framework architecture and pore chemistry, enabling directed functionalization nanomedical However, before applying novel nanomaterials to patients, it is imperative understand their potential health risks. In this study, nanosafety different MOF analyzed comprehensively The authors first evaluate effects MOFs...
Controlled on-surface film growth of porous and crystalline frameworks is a central prerequisite for incorporating these materials into functional platforms operational devices. Here, we present the synthesis thin zirconium-based metal-organic framework (MOF) films by vapor-assisted conversion (VAC). We established protocols adequate UiO-66, UiO-66(NH2), UiO-67, UiO-68(NH2) as well interpenetrated Zr-organic framework, PPPP-PIZOF-1, highly oriented films. Through VAC approach, precursors in...