A5002601291- Corrosion Behavior and Inhibition
- Anodic Oxide Films and Nanostructures
- Concrete Corrosion and Durability
- Aluminum Alloy Microstructure Properties
- Magnesium Alloys: Properties and Applications
- Electron and X-Ray Spectroscopy Techniques
- Aluminum Alloys Composites Properties
- Hydrogen embrittlement and corrosion behaviors in metals
- Material Properties and Applications
- Recycling and Waste Management Techniques
- Nanoporous metals and alloys
- Cultural Heritage Materials Analysis
- Cyclopropane Reaction Mechanisms
- Non-Destructive Testing Techniques
- Chemical Reactions and Mechanisms
- Layered Double Hydroxides Synthesis and Applications
- Microstructure and Mechanical Properties of Steels
- High voltage insulation and dielectric phenomena
- Extraction and Separation Processes
- Synthesis of β-Lactam Compounds
- Metal Alloys Wear and Properties
- Green IT and Sustainability
- Epoxy Resin Curing Processes
- Molecular Junctions and Nanostructures
- Bauxite Residue and Utilization
AkzoNobel (Netherlands)
2015-2024
AkzoNobel (Canada)
2015-2024
Delft University of Technology
2008-2021
AkzoNobel (United States)
2021
Philips (Finland)
2006-2008
The University of Queensland
1996-1997
Kyushu University
1997
Mintek
1992
Nanoscopic characterization of heterogeneous intermetallic particles (IMPs) which microstructurally and compositionally evolve during local corrosion is crucial in unravelling the mechanisms sequence initial events. Herein, we study site-specific initiation events focused on microscopic constituent compounds nanoscopic dispersoids AA2024-T3 at nanoscale using a combined quasi in-situ ex-situ analytical TEM approach. Our findings show dealloying-driven studied IMPs that have been considered...
In the present work, a flash-PEO coating is developed on AZ31B alloy in combination of silicate, phosphate, and fluoride based electrolyte order to offer green alternative chromate conversion coatings. Multilevel active protection achieved through synergetic self-sealing effect PEO itself inhibition provided by an organic inhibitor impregnated pores post-treatment step. The results indicate that coatings, loaded with corrosion inhibitors, can be recommended for exploitation industrial level...
Dealloying is involved in materials science responsible for fabrication of nanoscale structures beneficially but corrosion degradations detrimentally. Detailed understanding related to the latter critical designing corrosion-resistance alloys and dedicated inhibition systems. Thus, direct nanoscopic observations nano-structural compositional evolutions during process are essential. Here using liquid phase-transmission electron microscopy (LP-TEM), first time, we show dynamic evolution...
The quest for novel alternatives to hexavalent-chromium-based corrosion inhibitors is of utmost significance and urgency. Strict international health safety regulations, due growing concerns regarding the impact hexavalent chromium on human environment, have pushed commercial introduction many alternative inhibitor types, but implementation active protective primers structural parts in aerospace industry still pending. This endeavour has proven be remarkably challenging, as potential...
Lithium carbonate and lithium oxalate were incorporated as leachable corrosion inhibitors in model organic coatings for the protection of AA2024-T3. The coated samples artificially damaged with a scribe. It was found that lithium-salts are able to leach from coating form protective layer scribe on AA2024-T3 under neutral salt spray conditions. present paper shows first observation analysis these layers, generated lithium-salt loaded coatings. scribed areas examined by scanning transmission...
Lithium salts are being investigated as leachable corrosion inhibitor and potential replacement for hexavalent chromium in organic coatings. Model coatings loaded with lithium carbonate or oxalate demonstrated active inhibition the formation of a protective layer damaged area during neutral salt spray exposure. The present paper provides an abridged overview initial studies into this novel technology protection aluminum alloys. Coating defects were by microscopic techniques before after...
The effect of the presence an anodic film and hybrid sol-gel coating loaded with corrosion inhibitors was evaluated as a strategy for enhanced barrier active protection aluminium alloy 2024-T3. In this study, AA2024-T3 specimens were anodized in modified sulphuric-citric acid bath (SCA) first layer protective multilayer system subsequently protected by application silica-based coatings. These coatings doped LiNO3 Ce(NO3)3 studied comparison inhibitor-free terms morphology, composition intact...
An investigation into corrosion inhibition properties of a primer coating containing lithium carbonate as inhibitive pigment for AA2024 aluminum alloy was conducted. It found that, during neutral salt spray exposure, protective film about 0.2 to 1.5 μm thickness formed within the area where an artificial defect introduced by scribing through base alloy. This showed multilayered structure consisting relatively compact layer near substrate, porous middle and columnar outer layer. The...
This work presents the electrochemical evaluation of protective layers generated in a coating defect from lithium-leaching organic coatings on AA2024-T3 aluminum alloys as function neutral salt spray exposure time. Electrochemical impedance spectroscopy was used to study properties macroscopic scale. An model allowed quantitatively link behavior with physical layer damaged area studied by scanning electron microscopy. Local potentiodynamic polarization curves obtained micro-cell measurements...
This study focuses on the elucidation of formation mechanism passive layers AA2024-T3 during exposure to alkaline lithium carbonate solutions in presence sodium chloride. Under controlled conditions, an electrochemical cell, a protective layer was generated comprising amorphous inner and crystalline outer-layer. In order resolve mechanism, were characterized using surface analytical techniques characterize morphology, thickness elemental composition at different stages process. addition,...
This study presents the active protective properties of lithium‐leaching coatings for a range aluminium alloys. Coatings with and without lithium carbonate as leachable inhibitor were applied on alloys, artificially damaged exposed to neutral salt spray. A combined approach scanning electron microscopy electrochemical measurements revealed that leaching coating provided effective corrosion inhibition AA2024, AA7075, AA5083, AA6014 by formation layer in defect area preventing local processes...
Flash plasma electrolytic oxidation (flash-PEO) with in situ incorporation of inhibitors is explored as a strategy for corrosion protection 2024 aluminium (Al) alloys. Thin (~5 μm) and energy-efficient coatings were successfully developed on the Al substrate 100 s treatment time using different electrolytes based molybdate, stannate, tungstate, vanadate lanthanum or cerium salts additives without complexing agent (EDTA). Screening optimum combination search minimum thickness best protective...
The corrosion inhibiting effect of lithium carbonate has been studied over the pH range relevant for atmospheric conditions at polymer/metal interface. It is demonstrated that offers optimum protection under moderately alkaline attributed to formation a protective layer identified as aluminum-lithium layered double hydroxide. proposed an active-to-passive transition occurs in presence where anodic dissolution aluminum matrix important step prior layer. After prolonged exposure, uniformly...
In this work, the study of time-dependent behaviour lithium carbonate based inhibitor technology for active corrosion protection aluminium alloy 2024-T3 is presented. Odd random phase electrochemical impedance spectroscopy (ORP-EIS) selected as tool to protective properties a model organic coating with and without function immersion time, by examination non-linearities non-stationarities in system. A dedicated qualitative quantitative analysis allows linking presence certain frequency range...
Dicarbalkoxyketenes 8a and 8b are obtained by photolysis of diazo esters 7 in cryogenic matrices or FVT followed matrix isolation. The photochemical Wolff rearrangement diazomalonates 1 Ar at temperatures as low 6.5 K produces alkoxy(alkoxycarbonyl)ketenes 3, also 1. Photolysis CO ≥6.5 the dicarbalkoxyketenes 8. Ketenes 8, 12 react with pyridine above 40 to produce ketene−pyridine ylides (zwitterions) 9, 10, 13, respectively.
The protective film formed in a defect by leaching of lithium oxalate from model organic coatings during neutral salt spray exposure has been investigated. A scribed area about 1 mm width was introduced on the coated AA2024‐T3 aluminium alloy. examined before and after environment for 4, 8, 24 168 h scanning transmission electron microscopies. It found that able to leach coating it promoted formation provided effective corrosion protection typical morphology consists three different layers,...