A5079320931- Crystallization and Solubility Studies
- X-ray Diffraction in Crystallography
- Crystallography and molecular interactions
- Metal complexes synthesis and properties
- Magnetism in coordination complexes
- Metal-Organic Frameworks: Synthesis and Applications
- Crystal structures of chemical compounds
- Lanthanide and Transition Metal Complexes
- Synthesis of Tetrazole Derivatives
- Synthesis and Characterization of Heterocyclic Compounds
- Metal-Catalyzed Oxygenation Mechanisms
- Synthesis and biological activity
- Analytical Chemistry and Chromatography
- Dendrimers and Hyperbranched Polymers
- Chemical Thermodynamics and Molecular Structure
- Organometallic Complex Synthesis and Catalysis
- Chemical Synthesis and Reactions
Jadavpur University
2012-2016
Institute of Inorganic Chemistry of the Slovak Academy of Sciences
2014-2015
Three new copper(<sc>ii</sc>) Schiff base complexes have been prepared and characterized. DFT calculations were employed to estimate the contribution of different non-covalent interactions in extended supra-molecular networks.
A hooked cross-shaped anion, [Cu(N 3 ) 4 ] 2− , in a synthesized hetero-metallic pentanuclear copper( ii )–sodium complex provides π-basic surface adequate for establishing strong CH⋯[Cu(N interaction.
Three copper(<sc>ii</sc>) Schiff base complexes have been synthesized and characterized. Supramolecular assemblies in the solid state are analyzed by DFT calculations.
A dinuclear cadmium(II) complex, [Cd2(Hhqc)2(H2O)4] (H3hqc= 4,8‐dihydroxyquinoline‐2‐carboxylic acid) was synthesized and characterized by single crystal X‐ray diffraction studies, elemental analyses thermo‐gravimetric studies. The metal centers are found to be six coordinated with distorted pentagonal pyramidal geometry around them. complex shows few significant intermolecular hydrogen bonding interactions produce a three dimensional supramolecular network comprising of T8(2) water tapes....
Abstract Two monomeric octahedral complexes {[Ni(N(CN) 2 ) (bpy) ] ·H O ( 1 and [Mn(N(CN) where bpy = 2,2′‐bipyridine} were synthesized characterized by single crystal X‐ray diffraction, elemental analysis, UV–visible, IR spectra. The geometry optimization through DFT measurements predicts that both the have similar structures with hexa‐coordinated metal centers having a couple of mononegative dca anions thus satisfying geometry. Moreover, it is found HOMO–LUMO energy gaps are Δ E 4.981...
Correction for ‘Diminishing accessibility of electrophilic nickel(<sc>ii</sc>) centres due to incorporation a methylene spacer in the pendant side arm series heterotrinuclear nickel(<sc>ii</sc>)/sodium complexes: DFT study using homodesmotic equation’ by Prasanta Kumar Bhaumik <italic>et al.</italic>, <italic>CrystEngComm</italic>, 2020, <bold>22</bold>, 2970–2977, DOI: 10.1039/D0CE00251H.