Psidium guajava (guava) is well known tropic tree which abundantly grown for fruit. Many countries have a long history of using guava medicinal purposes. This plant finds applications the treatment diarrhea, dysentery, gastroenteritis, hypertension, diabetes, caries and pain relief improvement in locomotors coordination. Its leaf’s extract being used as medicine cough, oral ulcers some swollen gums wound. fruit rich vitamins A, C, iron, phosphorus calcium minerals. It contains high content...

Green synthesis of nanoparticles (NPs) has attracted the researcher's attention due to its rapid, cost-effective, sustainable and eco-friendly nature. Current studies were carried out perform investigate green NiO NPs with aqueous (NiO(aqueous)) ethanolic extracts (NiO(ethanolic)) Acacia nilotica leaves, respectively. The characterized by spectroscopic, microscopic thermometric techniques including FTIR, Raman, XRD, SEM, TGA DSC. electrochemical properties, antibacterial potential haemolytic...

Organic solar cells (OSCs) made of electron-acceptor and electron-donor materials have significantly developed in the last decade, demonstrating their enormous potential cutting-edge optoelectronic applications. Consequently, we designed seven novel non-fused ring electron acceptors (NFREAs) (BTIC-U1 to BTIC-U7) using synthesized electron-deficient diketone units reported end-capped acceptors, a viable route for augmented properties. The DFT TDDFT approaches were used measure power...

A series of novel azomethine precursors were synthesized by the condensation reactions 3-(trifluoromethyl)benzenamine (tfmb) with 2-hydroxybenzaldehyde (HL1) (tfmbs), 2,3-dihydroxybenzaldehyde (HL2) (tfmbdh), 2-hydroxy-1-naphthaldehyde (HL3) (tfmbnd) and 5-chloro-2-hydroxybenzaldehyde (HL4) (tfmbCl). The oxidovanadium(IV) complexes type [VO(tfmbs)2] (1), [VO(tfmbdh)2] (2), [VO(tfmbnd)2] (3) [VO(tfmbCl)2] (4) also prepared reaction ligands HL1–HL4 vanadyl(V) isopropoxide [VO(OCHMe2)3]....

Nonlinear optical (NLO) materials have several uses in many fields such as solid physics, biology, medicine, nuclear and material research. Therefore, a series of nonfullerene-based derivatives (CC10D1-CC10D8) with D-π-A configuration was planned for the NLO investigation using CC10R reference molecule structural alternations at acceptor moieties. Natural bonding orbital (NBO), UV-vis spectra, frontier molecular orbitals (FMOs), global reactivity parameters (GRPs), transition density matrix...

The design of nonlinear optical (NLO) materials using conjugated molecules via different techniques is reported in the literature to boost use these systems NLO.

Chromium oxide (Cr2O3) nanoparticles (NPs) find applications in modern science and technology due to their chemical stabilities, high-density corners magnetic/electrical/catalytic properties. Current studies were performed produce the (Cr2O3)aq (Cr2O3)et NPs by treating chromium acetate with aqueous ethanolic extracts, respectively of Cassia fistula leaves; same reaction was also presence NaOH yield (Cr2O3)aqNa (Cr2O3)etNa NPs, respectively. The synthesized characterized XRD, FTIR, Raman...

Current studies were performed to investigate the phytochemistry, synergistic antibacterial, antioxidant, and hemolytic activities of ethanolic aqueous extracts Azadirachta indica (EA WA) Cymbopogon citratus (EC WC) leaves. Fourier transform infrared data verified existence alcoholic, carboxylic, aldehydic, phenyl, bromo moieties in plant The EC) significantly richer phenolics flavonoids as compared (WA WC). extract C. (EC) contained higher concentrations caffeic acid (1.432 mg/g), synapic...

Abstract The Biswas–Mollivic equation is a special type of nonlinear Schrödinger equation, which explains the spatio-temporal behaviour excitable media. In this paper, we investigate optical soliton solutions with cubic–quintic–septic–nonic nonlinearities using generalized Riccati mapping method. This method efficient and provides new perspectives. It also novel insights into dynamics Our findings add to better understanding complex patterns that develop in media have potential applications...

New organotin(IV) carboxylates, R2SnL2 (R=n-Bu: 1), R2Sn(Cl)L 2), and R3SnL (R=Me: 3; n-Bu: 4; Ph: 5) have been synthesized by stirring 5-chloro-2-hydroxybenzoic acid HL with KOH R2SnCl2 (R=n-Bu)/R3SnCl (R=Me, n-Bu, Ph) in methanol at room temperature. The complexes along ligand characterized FTIR, (1H, 13C) NMR, EI-MS, single-crystal XRD crystallography. FTIR data indicated bidentate coordination of carboxylate. NMR suggested six- or five-coordinate geometry carboxylates. Single-crystal 1...

Abstract Aflatoxins gain entry into food products when proper drying, storage, and transport conditions are not applied. They comprise of closely related compounds for example, aflatoxins B1, B2, G1, G2, M1, M2. The order toxicity among aflatoxis is B1 > G1 B2 G2. In developing countries, the serious illness deaths common due to acute aflatoxicosis human children more prone their attack. Chronic affects on animal nutrition status. commonly extracted from foodstuffs by liquid–liquid...

The objective of the study was to explore incidence patulin (PAT) mycotoxin in mango and orange fruits derived products marketed Pakistan. A total 274 samples, including 70 fruits, 63 mango-based (juices, pulp, jam), 77 64 orange-based products, were collected. PAT determined by reverse-phase high-performance liquid chromatography (HPLC) with UV-Vis detector (276 nm). Linear response observed (R2 > 0.99), limit detection (LOD) 5 µg/kg recovery percentage 97.4%. samples 61.7%, concentration...

The present review provides a comprehensive overview of the phytochemistry, nutritional composition, and therapeutic implications associated with consumption pomegranate (Punica granatum) fruit, renowned for its dual role as taste delicacy medicinal agent. A detailed exploration phytochemical composition is undertaken. Recognized myriad health benefits, this fruit has been historically employed remedy diverse disorders, leaves, peel, bark demonstrating efficacy in treating gastrointestinal...

A palladium complex, [KLCSS]2Pd (1), has been prepared by stirring sarcosine (HLH), KOH and CS2 in methanol subsequently treating with palladium(II) chloride. Six heterobimetallic derivatives of the type [R2(Cl)SnLCS2]2Pd (R = Me: 2; Bu: 3; Ph: 4)/[R3SnLCS2]2Pd 5; 6; 7) were also synthesized (HLH) followed an addition R2SnCl2/R3SnCl then PdCl2. FT-IR data demonstrated bidentate binding dithiocarbamate carboxylate four- five-coordinate environments around Pd(II) Sn(IV) centers, respectively,...

Organic compounds having significant nonlinear optical (NLO) applications are being employed in the optoelectronics field. In current work, a series of non-fullerene acceptor (NFA) based designed by modifying acceptors with different substituents using DTS(FBTTh2)2R1 as reference compound. To study NLO responses to tuning various acceptors, DFT and TD-DFT parameters were calculated at M06 level along 6-31G(d,p) basis set. The (MSTD2-MSTD7) showed smaller values energy gap comparison gaps...

The stochastic dynamical ϕ4 equation is obtained by adding a multiplicative noise term to the classical equation. represents random fluctuations that are present in system and modeled Wiener process. powerful tool for modeling behavior of complex systems exhibit randomness nonlinearity. It has wide range applications physics, chemistry, biology, finance. Our goal this paper use new extended direct algebraic method find traveling wave solutions We explore trigonometric, hyperbolic, rational...

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Background: Inguinal hernias occur in 0.5% to 15% of cases, with factors like location, type, and surgical technique influencing outcomes. This study compares postoperative pain (VAS) hospital stay duration between laparoscopic trans-abdominal pre-peritoneal (TAPP) mesh repair open for inguinal hernia treatment. Methods: A six-month Randomised Controlled Trial, from January 2024 June was conducted at Holy Family Hospital, Rawalpindi, involving 90 patients (45 each group). included aged 18-55...