A5057449718- Crystallization and Solubility Studies
- X-ray Diffraction in Crystallography
- Organometallic Complex Synthesis and Catalysis
- Crystallography and molecular interactions
- Metal complexes synthesis and properties
- Metal-Organic Frameworks: Synthesis and Applications
- Asymmetric Hydrogenation and Catalysis
- N-Heterocyclic Carbenes in Organic and Inorganic Chemistry
- Electrocatalysts for Energy Conversion
- Electrochemical Analysis and Applications
- Synthesis and characterization of novel inorganic/organometallic compounds
- Crystal structures of chemical compounds
- Coordination Chemistry and Organometallics
- Magnetism in coordination complexes
- CO2 Reduction Techniques and Catalysts
- Synthesis and Characterization of Heterocyclic Compounds
- Catalytic Cross-Coupling Reactions
- Organophosphorus compounds synthesis
- Radical Photochemical Reactions
- Conducting polymers and applications
- Organic Light-Emitting Diodes Research
- Porphyrin and Phthalocyanine Chemistry
- Organic and Molecular Conductors Research
- Organometallic Compounds Synthesis and Characterization
- Carbon dioxide utilization in catalysis
A.E. Arbuzov Institute of Organic and Physical Chemistry
2015-2024
Deleted Institution
2024
South Ural State University
2021-2024
Kazan Scientific Center
2019-2021
Kazan Federal University
2015-2016
Reactions of [SbBr6]3– containing HBr solutions with bromide salts 1,1′-(1,2-ethanediyl)bis(pyridine) (PyC22+) or 1,1′-(1,2-ethanediyl)bis(3,5-dimethylpyridine) (3,5-MePyC22+) initially result in the formation deep orange complexes Cat[SbBr5] (1 and 2), featuring unusual Sb···Br interactions solid state. In mother liquor, 1 transforms into discrete binuclear (C2Py)2[Sb2Br10], which demonstrates polymorphism (triclinic 3 monoclinic 4), while 2 polymeric (3,5-MePy){[SbBr4]} (5). DFT...
Four metal halides of the (tBuPCN)NiX family [X = F (1), Cl (2), Br (3), or I (4); PCN 1-[3-[(di-tert-butylphosphino)methyl]phenyl]-1H-pyrazole] have been prepared through a direct reaction corresponding anhydrous NiX2 salts and unsymmetrical pincer ligand. Structural information from single-crystal X-ray data, 19F solution nuclear magnetic resonance, combined electrochemical results [cyclic voltammetry (CV) in situ electron paramagnetic resonance spectro-electrochemistry] reveal that...
Metal-organic frameworks [M2(2-I-bdc)2bpe] (M = Zn(II) (1), Co(II) (2), 2-I-bdc 2-iodoterephtalic acid, and bpe 1,2-bis(4-pyridyl)ethane) were prepared characterized by X-ray diffractometry. Both compounds retain their 3D structure after the removal of guest DMF molecules. Selectivity sorption different organic substrates from gas phase was investigated for both complexes.
The interaction between (PNP)PdH (1); PNP = bis(2-diisopropylphosphino-4-methylphenyl)amide and different acids (CF3SO3H, HBF4∙Et2O, fluorinated alcohols formic acid) was studied in benzene or toluene as well neat by IR NMR spectroscopies. structures of hydrogen-bonded complexes were also optimized at the DFT/ωB97-XD/def2-TZVP level. nitrogen atom amidophosphine pincer ligand readily accepts proton not only from strong Brønsted but relatively weak alcohols. That suggests that binding to...
GRAPHICAL ABSTRACTThe formation of secondary arylphosphines in the reaction organonickel sigma-complex [NiBr(Mes)(bpy)], where Mes = 2,4,6-trimethylphenyl, bpy 2,2′-bipyridine, with phenylphosphineAll authorsZufar N. Gafurov, Lenar I. Musin, Il'yas F. Sakhapov, Vasily M. Babaev, Elvira Musina, Andrey A. Karasik, Oleg G. Sinyashin & Dmitry Yakhvarovhttps://doi.org/10.1080/10426507.2016.1212045Published online:25 July 2016
A Pt(II) complex bearing chelating tridentate bis-aryloxide tetrahydropyrimidinium-based N-heterocyclic carbene (NHC) was synthesized and characterized by using different techniques. Both cyclic voltammetry differential pulse were used to study the electrochemical properties of complex, revealing two reversible one-electron oxidation processes. The chemical generation isolation one-electron-oxidized species performed oxidizing initial means AgBF4. combination spectroscopic (UV-Vis/NIR- EPR-)...
Quantum-chemical calculations were performed to rationalize the experimental molecular weight distribution of α-olefin products, revealing main mechanistic models process.
The reactivity of the previously reported organonickel σ-complex [NiBr(Mes)(bpy)], where Mes = 2,4,6-trimethylphenyl, bpy 2,2′-bipyridine, toward phosphine PH3 was investigated. reaction leads to primary mesitylphosphine MesPH2 as main product and dimesitylphosphine Mes2PH secondary with nickel complex transmetalating agent. formed reacts an excess giving major product.