Takeshi Hashimoto

ORCID: 0000-0002-7601-5511
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Research Areas
  • Crystallization and Solubility Studies
  • X-ray Diffraction in Crystallography
  • Molecular Sensors and Ion Detection
  • Advanced Wireless Communication Techniques
  • Wireless Communication Networks Research
  • Advanced biosensing and bioanalysis techniques
  • Electrochemical sensors and biosensors
  • Advanced Wireless Network Optimization
  • Luminescence and Fluorescent Materials
  • Analytical Chemistry and Sensors
  • Mobile Ad Hoc Networks
  • Metal complexes synthesis and properties
  • Opportunistic and Delay-Tolerant Networks
  • Biosensors and Analytical Detection
  • Supramolecular Self-Assembly in Materials
  • Electrochemical Analysis and Applications
  • Organometallic Complex Synthesis and Catalysis
  • Supramolecular Chemistry and Complexes
  • PAPR reduction in OFDM
  • Analytical Chemistry and Chromatography
  • Vehicular Ad Hoc Networks (VANETs)
  • Conducting polymers and applications
  • Cellular Automata and Applications
  • Cooperative Communication and Network Coding
  • Coding theory and cryptography

Hashimoto Municipal Hospital
2025

Sophia University
2015-2024

Saitama University
2023

Nagoya University
2022

Nano Carbon (Poland)
2021

University of Electro-Communications
1992-2016

Hiroshima City University
2010-2016

Usman Institute of Technology
2016

KDDI Research (Japan)
2016

Kyoto Institute of Technology
2011

The phenylboronic acid azoprobe (BA-Azo)/gamma-cyclodextrin (gamma-CD) complex exhibits a selective response for D-glucose by forming supramolecular 2:1 inclusion of the azoprobes with inside gamma-CD cavity.

10.1039/b819938h article EN Chemical Communications 2009-01-01

The complete complementary code (CCC) that was proposed by Suehiro and Hatori is a sequence family, set of sets, with ideal correlation sums. Numerous studies in the literature show its applications to direct-spread code-division multiple access (DS-CDMA) systems for interchannel interference (ICI)-free communication improved spectral efficiency. In this paper, we propose systematic framework construction CCCs based on <i xmlns:mml="http://www.w3.org/1998/Math/MathML"...

10.1109/tit.2011.2162182 article EN IEEE Transactions on Information Theory 2011-09-01

There is an urgent need to develop a rapid and selective method for the detection of bacteria because delayed diagnosis overuse antibiotics have triggered drug resistance in bacteria. To this end, we prepared boronic acid-modified poly(amidoamine) generation 4 (B-PAMAM(G4)) dendrimer as cross-linking molecules that form aggregates with Within 5 min adding B-PAMAM(G4) solution bacterial suspension, large were observed. Interestingly, aggregate formation various was pH-dependent. In basic pH,...

10.1021/acs.analchem.8b04870 article EN publisher-specific-oa Analytical Chemistry 2019-01-17

Stable water-in-oil emulsion membranes can be prepared using [dilauryl(dimethyl)ammonium] bromide (DDAB), a cationic surfactant. We ultrasmall cyclodextrin (γ-CyD) nanogels (γ-CyDngs) by forming ionic pairs between the secondary hydroxyl groups of γ-CyDs and DDAB. Fluorescence NMR characterisation obtained γ-CyDngs revealed superior inclusion affinities compared with native γ-CyDs, beneficial for solubilisation hydrophobic compounds in water.

10.1039/d3cc00523b article EN cc-by Chemical Communications 2023-01-01

Abstract Background Self‐help programs without therapist involvement for obsessive–compulsive disorder (OCD) are promising, but the high dropout rate is a significant issue. Our software, which incorporates entertainment elements, showed completion of over 80% in pre–post comparison study, with superior effectiveness. This protocol study that aims to evaluate efficacy and tolerability video‐based mobile application OCD treatment through randomized controlled trial. Methods designed as trial...

10.1002/pcn5.70065 article EN cc-by-nc-nd Psychiatry and Clinical Neurosciences Reports 2025-02-16

Binuclear β-diketonatoruthenium(III) complexes [{Ru(acac)2}2(tae)], [{Ru(phpa)2}2(tae)], and [(acac)2Ru(tae)Ru(phpa)2] binuclear mononuclear bipyridine [{Ru(bpy)2}2(tae)](PF6)2 [Ru(bpy)2(Htae)]PF6 (acac = 2,4-pentanedionate ion, phpa 2,2,6,6-tetramethyl-3,5-heptanedionate tae 1,1,2,2-tetraacetylethanate dianion, bpy 2,2'-bipyridine) were synthesized. The new have been characterized by 1H NMR, MS, electronic spectral data. Crystal molecular structures of [{Ru(acac)2}2(tae)] solved...

10.1021/ic030216c article EN Inorganic Chemistry 2004-09-03

In this study, we have developed a rational design strategy to obtain highly selective supramolecular recognition systems of cyclodextrins (CyDs) on the basis lock and key principle. We designed synthesized dipicolylamine (dpa)-modified γ-CyD-Cu2+ complexes possessing an azobenzene unit (Cu·1-γ-CyD) examined how they recognized phosphoric acid derivatives in water. The results revealed that Cu·1-γ-CyD ATP with high selectivity over other derivatives. significant blue shift UV-vis spectra 1H...

10.1021/acs.joc.6b02513 article EN The Journal of Organic Chemistry 2016-12-20

Fluorescence recognition of d-glucose in water with excellent sensitivity, selectivity, and chiral selectivity is desired because an essential component biological pathological processes. We report innovative approach that exploits the 1:2 stoichiometric inclusion complexes γ-cyclodextrin (γ-CyD) two molecules fluorescent monoboronic acid-based receptors, which form a pseudo-diboronic acid moiety as site for water. Two acids (1F 2N) were easily synthesized without heating or column...

10.1021/acssensors.2c02087 article EN ACS Sensors 2022-12-20

Nanomaterial-based photothermal therapy is a noninvasive treatment approach that selectively destroys cancer cells by utilizing the ability of nanomaterials to convert photon energy into heat. Although plasmonic gold nanoparticles are promising, this study focuses on developing cost-effective alternatives. We developed aluminum open-shell nanostructures (AlOSNs) as symmetry-breaking structures nanoshells for purpose. The intrinsic low chemical stability AlOSNs in aqueous media (water and...

10.1021/acsanm.3c05176 article EN ACS Applied Nano Materials 2024-01-30

Abstract A solid‐phase extraction (SPE)‐gas chromatography (GC)‐mass spectrometry (MS) analytical method was developed for the simultaneous analysis of natural free estrogens and their conjugates in wastewater samples. Natural were successfully separated by oasis hydrophilic‐lipophilic balance solid phase (Oasis HLB SPE) method, initially enzyme hydrolyzed β‐glucuronidase or arylsulfatase from Helix pomatia prior to derivatization. N ‐methyl‐ ‐(tert‐butyldimethylsilyl)trifluoroacetamide...

10.1002/clen.200900149 article EN CLEAN - Soil Air Water 2010-02-01

ATP recognition has been achieved by exploiting the self-assembly of boronic acid-appended cyclodextrin, a fluorescent probe, and through multiple interactions.

10.1039/d3nj00139c article EN cc-by-nc New Journal of Chemistry 2023-01-01

Lipopolysaccharide (LPS) is a bacterial toxin that causes fever in humans. Our small-molecule chemosensor named Zn-dpa-C2OPy shows rapid ratiometric fluorescence response to LPS water with detection limit of 11 pM, which lower than our previously reported sensor. Spectroscopic measurements (fluorescence, absorbance, 1H NMR, and lifetime), dynamic light scattering measurements, transmission electron microscopy observations revealed the was induced by changes aggregation state via multi-point...

10.1021/acs.analchem.3c01870 article EN cc-by-nc-nd Analytical Chemistry 2023-07-31

Various diboronic acid-based chemosensors for d-glucose have been developed use in diabetes diagnostic systems. However, most of these limitations, such as poor water solubility, difficulties synthesis, and inability to selectively detect from among other saccharides. We report a simple chemosensor based on supramolecular complex fluorophenylboronic acid-appended β-cyclodextrin (FPB-βCyD) an anthracene-based probe having boronic acid moiety (1). Hydrophobic 1 is encapsulated the cyclodextrin...

10.1039/d2ra03567g article EN cc-by-nc RSC Advances 2022-01-01
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