A5051427074- Catalytic C–H Functionalization Methods
- Sulfur-Based Synthesis Techniques
- Radical Photochemical Reactions
- Wastewater Treatment and Nitrogen Removal
- Organoboron and organosilicon chemistry
- Catalytic Cross-Coupling Reactions
- Chemical Synthesis and Reactions
- Asymmetric Hydrogenation and Catalysis
- Oxidative Organic Chemistry Reactions
- Synthesis and Catalytic Reactions
- Microbial Fuel Cells and Bioremediation
- Chemical Synthesis and Analysis
- Synthesis and biological activity
- Cyclopropane Reaction Mechanisms
- Asymmetric Synthesis and Catalysis
- Ammonia Synthesis and Nitrogen Reduction
- Synthesis and Biological Evaluation
- Geochemistry and Elemental Analysis
- Luminescence and Fluorescent Materials
- Fluorine in Organic Chemistry
- Constructed Wetlands for Wastewater Treatment
- Microbial Community Ecology and Physiology
- Quinazolinone synthesis and applications
- Advanced Photocatalysis Techniques
- Crystal structures of chemical compounds
Shihezi University
2016-2025
Xi'an University of Architecture and Technology
2020-2025
Chinese Academy of Sciences
2012-2025
Shanghai Institute of Materia Medica
2025
Nanjing University of Chinese Medicine
2025
Guizhou Normal University
2025
Xinjiang Production and Construction Corps
2016-2024
Xi'an Jiaotong University
2013-2024
China University of Petroleum, East China
2024
Changchun Institute of Optics, Fine Mechanics and Physics
2024
Not only symmetrical, but also unsymmetrical α,α-diaryl allylic alcohols are employed as substrates in the title reaction. A number of arenes and even heteroarenes underwent radical 1,2-aryl migration (“neophyl rearrangement”) to produce α-aryl β-trifluoromethyl ketones. The preferential electron-deficient aryl groups over electron-rich ones supports mechanism, which was further confirmed by DFT calculations. As a service our authors readers, this journal provides supporting information...
In contrast to the traditional and widely-used cycloaddition reactions involving at least a π bond component, [2σ + 2σ] radical between bicyclo[1.1.0]butanes (BCBs) cyclopropyl ketones has been developed provide modular, concise, atom-economical synthetic route substituted bicyclo[3.1.1]heptane (BCH) derivatives that are 3D bioisosteres of benzenes core skeleton number terpene natural products. The reaction was catalyzed by combination simple tetraalkoxydiboron(4) compound B2pin2 3-pentyl...
Abstract Ring structures such as pyridine, cyclopentane or their combinations are important motifs in bioactive molecules. In contrast to previous cycloaddition reactions that necessitated a directly bonded initiating functional group, this work demonstrated novel through‐(hetero)arene radical transmission concept for selective activation of remote bond. An efficient, metal‐free and atom‐economical [3+2] between 4‐pyridinyl cyclopropanes alkenes alkynes has been developed modular synthesis...
Abstract The metasurface refractive index sensor has a high degree of tunability and flexibility, providing excellent performance for precision sensing applications. absorber with metallic structure been hindered in further applications due to the inherent Ohmic loss material. In this study, dual nanorod based on semiconductor Si was designed, introducing symmetry-breaking excite ultra-narrow q-BIC resonance peaks Fano line shapes. Both are located near-infrared region, multipole analysis...
The Rh(III)-catalyzed C-H functionalizations of benzamide derivatives with olefin were studied by DFT calculations to elucidate the divergent pathways controlled N-OR internal oxidants. For substrates N-OMe and N-OPiv oxidants, energy profiles for consecutive N-H deprotonation/C-H activation/olefin insertion sequences similar, different properties reactivities generated 7-membered rhodacycles predicted. When is involved, this intermediate generally unstable, olefination occurs easily via a...
A dual catalytic sp3 α C–H arylation and alkylation of benzamides with organic halides is described. This protocol exhibits an exquisite site selectivity, chemoselectivity, enantioselectivity pattern, offering a complementary reactivity mode to existing or alkylations via transition metal catalysis photoredox events.
Although pyridine derivatives are versatile supporting ligands in catalysis, the development of their chiral versions has been relatively limited. Herein, we report design, synthesis, and proof-of-concept application a structurally tunable framework featuring an annulated compact ring system. Using N,B-bidentate ligand skeleton containing moiety, have developed enantioselective iridium-catalyzed desymmetrizing C–H borylation reaction diaryl(2-pyridyl)methane compounds with up to 96% ee 93%...
A new class of chiral 2,2'-bipyridine ligands, SBpy, featuring minimized short-range steric hindrance and structural tunability was rationally designed developed, the effectiveness demonstrated in first highly enantioselective Ni-catalyzed addition aryl halides to aldehydes. In comparison with known approaches using preformed metallic reagents, this reaction is more step-economical functional group tolerant. The mechanism a model stereocontrol were proposed based on experimental...
In contrast to the extensive but non-recyclable use of tetraalkoxydiboron(4) compounds as stoichiometric reagents in diverse reactions, this article reports an atom-economical reaction using a commercial diboron(4) catalyst. The key success was designing catalytic cycle for radical [3 + 2] cycloaddition involving pyridine cocatalyst generate from catalyst and reversibly mediate transfer boronyl radicals. comparison with known transition metal-based catalysts, current features not only...
A highly efficient and selective oxidation of sulfides to sulfones with periodic acid catalyzed by CrO(3) is described. variety electron-rich electron-deficient were oxidized 2 mol % in acetonitrile at room temperature excellent yields. Sulfides other readily functional groups selectively high yields 10 ethyl acetate/acetonitrile -35 degrees C.
Boryl ligands hold promise in catalysis due to their very high electron-donating property. In this communication double N,B-type boryl anions were designed as bidentate promote an sp(2) C-H borylation reaction. A symmetric pyridine-containing tetraaminodiborane(4) compound (1) was readily prepared the ligand precursor that could be used, combination with [Ir(OMe)(COD)]2, situ generate a highly active catalyst for broad range of (hetero)arene substrates including electron-rich and/or...
Effective synthetic methods, involving silyl radical intermediates and furnishing silafluorenes silaindenes <italic>via</italic> direct Si–H C–H cleavage in one step, have been developed.
Nicht nur symmetrische, sondern auch unsymmetrische α,α-Diarylallylalkohole wurden in der Titelreaktion als Substrate eingesetzt. Eine Reihe von Arenen und sogar Heteroarene reagierten radikalischen 1,2-Arylmigration („Neophyl-Umlagerung“) zu α-Aryl-β-trifluormethylketonen. Die bevorzugte Migration elektronenarmer gegenüber elektronenreichen Arylgruppen unsymmetrischen Substraten spricht für den Mechanismus, mit DFT-Rechnungen bestätigt wurde. As a service to our authors and readers, this...