Periyasamy Anushkkaran

ORCID: 0000-0002-8284-4826
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About
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Research Areas
  • Advanced Photocatalysis Techniques
  • Iron oxide chemistry and applications
  • Copper-based nanomaterials and applications
  • Mine drainage and remediation techniques
  • TiO2 Photocatalysis and Solar Cells
  • Advanced oxidation water treatment
  • Polymer composites and self-healing
  • Adsorption and biosorption for pollutant removal
  • Electrocatalysts for Energy Conversion
  • Arsenic contamination and mitigation
  • Advanced Nanomaterials in Catalysis
  • Quantum Dots Synthesis And Properties
  • Catalytic Processes in Materials Science

Jeonbuk National University
2021-2024

University of Jaffna
2023

Nutrasource
2021

Chonbuk National University Hospital
2021

Herein, in order to improve the conductivity and slack water oxidation kinetics of hematite (α-Fe2O3) photoanode, we propose Nb-doped Co(OH)x cocatalyst-deposited α-Fe2O3 thin film photoanode (Nb-HT/Co(OH)x) via situ diluted hydrothermal microwave-assisted methods. The as-prepared Nb-HT/Co(OH)x thin-film exhibited a photocurrent density 1.78 mA cm–2 at 1.23 V versus reversible hydrogen electrode (RHE), which is 1.7-fold higher than that Bare-Fe2O3 photoanode. dual effect Nb-doping deposition...

10.1021/acssuschemeng.2c07258 article EN ACS Sustainable Chemistry & Engineering 2023-04-04

Ru–FeOOH and FeNi(OH) x dual-layer cocatalysts passivated the recombination surface states, resulting in Fermi level de-pinning effect, while tailoring intermediate states for effective hole transfer to electrolyte.

10.1039/d3ta07823j article EN Journal of Materials Chemistry A 2024-01-01

The influence of CTAB and metallic Au NPs on the PEC activity a Zr-doped Fe 2 O 3 photoanode is described. surfactant assists in situ adsorption Zr-FeOOH during hydrothermal synthesis.

10.1039/d3ta05014a article EN Journal of Materials Chemistry A 2023-01-01

Hematite (α-Fe2O3)-based photoanodes offer great potential for use in solar hydrogen production as part of efforts to construct a sustainable and renewable energy economy based on photoelectrochemical (PEC) water splitting. A co-doping modification is the utmost significance improving PEC performance. To develop an efficient photoanode, comprehensive grasp co-dopants with diverse valence states necessary. Herein, we describe hydrothermal dip-coating approach fabrication Hf-doped Fe2O3...

10.1021/acssuschemeng.3c08529 article EN ACS Sustainable Chemistry & Engineering 2024-03-15

Phenol is one of the most prevalent contaminants discovered in water bodies. The adsorption process gaining popularity as a viable method removing phenolic chemicals from contaminated aquatic resources. elimination using Palmyra kernel shell activated charcoal has been extensively investigated. removal effectiveness was calculated physically, chemically (H3PO4 and NaOH) magnetically for various amounts components varying durations. According to this research study, physically much higher...

10.1016/j.crgsc.2023.100355 article EN cc-by-nc-nd Current Research in Green and Sustainable Chemistry 2023-01-01

The erratically ZrO<sub>2</sub> loaded hematite cauliflower photoanodes quenched at 650 °C showed 14 times higher PEC performance than the conventionally prepared nanorod photoanode (PQ650).

10.1039/d1se00327e article EN Sustainable Energy & Fuels 2021-01-01

The interplay between diffusion/doping and surface passivation of TZF NCs exhibits a breakthrough photocurrent density 0.73 mA cm<sup>−2</sup> (1.23 V <italic>vs.</italic> RHE) with 98% stability over 10 h in the TZF/Al<sub>2</sub>O<sub>3</sub>/CoO<sub>x</sub> photoanode.

10.1039/d0cy02255a article EN Catalysis Science & Technology 2021-01-01

The development of efficient photoanodes for solar fuel generation via photoelectrochemical (PEC) water splitting is becoming a bottleneck. These limitations necessitate the design iron-containing metal oxides, like "ferrites-based electrode materials" with improved oxygen evolution kinetics, light absorptivity, and intrinsic stability, yet at low cost. Herein, we report in-situ formation Zr–ZnFe2O4/Fe2O3 heterojunction (ZZFO/HT) photoelectrodes using facile magnetron sputtering hydrothermal...

10.1021/acsaem.1c03322 article EN ACS Applied Energy Materials 2021-12-22

Dual elemental doping strategies have been employed for the fabrication of fluorine and zirconia co-doped hematite (F–Zr:Fe2O3/FTO) photoanodes. The F–Zr:Fe2O3/FTO photoanode has a (110)-oriented structure, remarkable photocurrent density 1.91 mA cm-2 without any catalyst supports, at water oxidation potential 1.23 VRHE. enhancement in net is attributed to synergistic effect two doping. situ doped Zr4+ ions substituted iron increase photogenerated free electrons within bulk resulting...

10.2139/ssrn.4033132 article EN SSRN Electronic Journal 2022-01-01

Al/Ti co-doping was performed through an effective microwave-assisted surface attachment method. The synergistic effect of and Al 2 O 3 passivation layer significantly boosts the PEC performance in Al(5 mM)/Ti(4%):Fe photoanode.

10.1039/d2se00459c article EN Sustainable Energy & Fuels 2022-01-01
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