A5016453270- Asymmetric Hydrogenation and Catalysis
- Chemical Synthesis and Reactions
- Catalytic C–H Functionalization Methods
- Chemical Synthesis and Analysis
- Radical Photochemical Reactions
- Advanced Synthetic Organic Chemistry
- Catalytic Cross-Coupling Reactions
- Catalysis and Oxidation Reactions
- Oxidative Organic Chemistry Reactions
- Synthetic Organic Chemistry Methods
- Cyclopropane Reaction Mechanisms
- Sulfur-Based Synthesis Techniques
- Chemical Reactions and Isotopes
- Asymmetric Synthesis and Catalysis
- Traditional and Medicinal Uses of Annonaceae
- Alkaloids: synthesis and pharmacology
- Synthesis of β-Lactam Compounds
- Innovative Microfluidic and Catalytic Techniques Innovation
- Environmental remediation with nanomaterials
- Phosphorus compounds and reactions
- Synthesis and Catalytic Reactions
- Catalytic Processes in Materials Science
- Catalysis and Hydrodesulfurization Studies
Université Claude Bernard Lyon 1
2011-2014
Centre National de la Recherche Scientifique
2010-2012
Université Toulouse III - Paul Sabatier
2010
Boronic esters have long been considered as poor partners in cross-coupling reactions with arene diazoniums. Here is reported an unprecedented application of self-activated boronic a base-free reaction diazonium salts under mild and user friendly conditions.
Abstract An efficient reduction of aromatic and aliphatic esters with 1,1,3,3‐tetramethyldisiloxane in combination [MoO 2 (acac) ] or [V(O)(O i Pr) 3 is reported. In the former system, presence triphenylphosphane oxide allows high conversion good isolated yield to be reached. For latter no ligand necessary obtain corresponding alcohols similar results.
Abstract An efficient reduction followed by cyclization of diacid compounds with the InBr 3 /TMDS system is reported. This allows formation five‐ and six‐membered ring ethers substituted in 3‐ or 4‐position.
<p> Electrochemical techniques have long been heralded for their innate sustainability as efficient methods achieving redox reactions. Carbonyl desaturation, a fundamental organic oxidation, is an oft-employed transformation to unlock adjacent reactivity. To date, the most reliable it relied on transition metals (Pd/Cu) or stoichiometric reagents based I, Br, Se, S. Herein we report operationally simple pathway such structures from enol silanes and phosphates using electrons primary...
A selective photochemical monochlorination of 2-fluorotoluene has been developed by a continuous flow process using two different reactors, one for the tuning conditions and second scale-up. The key reaction parameters were optimized one-factor-at-a-time design experiment methods, with goal minimizing formation dichlorinated by-product. This transformation performed on multi decagram scale.
Electrochemical techniques have long been heralded for their innate sustainability as efficient methods achieving redox reactions. Carbonyl desaturation, a fundamental organic oxidation, is an oft-employed transformation to unlock adjacent reactivity. To date, the most reliable it relied on transition metals (Pd/Cu) or stoichiometric reagents based I, Br, Se, S. Herein we report operationally simple pathway such structures from enol silanes and phosphates using electrons primary reagent....
Abstract The presented two titanium‐based systems reduce aliphatic and aromatic nitriles in the presence of various functional groups.
The authors report an unprecedented application of self-activated boronic esters in a base-free cross-coupling reaction with diazonium salts under mild and user-friendly conditions. protocol tolerates wide range functional groups affords unsymmetrical biaryls high yields.
Abstract For the most phosphines, it is necessary to protect them as borane adducts.
Abstract A series of dioxazaborocanes (III) is prepared and successfully used as starting compounds in a base‐free Suzuki—Miyaura reaction with diazonium salts (IV).
Abstract The present new and efficient reduction of aromatic aliphatic esters employes 1,1,3,3‐tetramethyldisiloxane as reducing agent to give the corresponding alcohols.