A5087706981- Crystallization and Solubility Studies
- X-ray Diffraction in Crystallography
- Metal complexes synthesis and properties
- Organometallic Complex Synthesis and Catalysis
- Crystallography and molecular interactions
- Asymmetric Hydrogenation and Catalysis
- Click Chemistry and Applications
- Ferrocene Chemistry and Applications
- Magnetism in coordination complexes
- Synthesis and Biological Evaluation
- Lanthanide and Transition Metal Complexes
- Organometallic Compounds Synthesis and Characterization
- Analytical Chemistry and Chromatography
- Coordination Chemistry and Organometallics
- Synthesis and Characterization of Heterocyclic Compounds
- Inorganic and Organometallic Chemistry
- Synthesis and characterization of novel inorganic/organometallic compounds
- Synthesis and biological activity
- Analytical Methods in Pharmaceuticals
- Computational Drug Discovery Methods
- Radiopharmaceutical Chemistry and Applications
- Free Radicals and Antioxidants
- Crystal structures of chemical compounds
- Molecular Junctions and Nanostructures
- Synthetic Organic Chemistry Methods
North Eastern Hill University
2015-2024
Sugen Life Sciences (India)
2023-2024
University of Washington
2022
Laboratoire de Chimie Moléculaire et Thioorganique
2016
Entrust
2016
Dr. Reddy's Laboratories (India)
2011
University of Salford
2009
Institut Català d'Investigació Química
2008
Universitat Autònoma de Barcelona
2008
University of Girona
2008
The main objective of this review is to give a general overview the structure, electrochemistry (when available), and catalytic performance Ru complexes, which are capable oxidizing water molecular dioxygen, highlight their more relevant features. description catalysts mainly divided into complexes that contain Ru−O−Ru bridging group those do not. Finally few conclusions drawn from global all presented here, some guidelines for future catalyst design given.
Half‐sandwich ruthenium, rhodium and iridium complexes ( 1 – 12 ) were synthesized with aldoxime L1 ), ketoxime L2 amidoxime L3 ligands. Ligands have the general formula [PyC(R)NOH], where R = H CH 3 NH 2 ). Reaction of [{(arene)MCl } ] (arene p ‐cymene, benzene, Cp*; M Ru, Rh, Ir) ligands in 1:2 metal precursor‐to‐ligand ratio yielded such as [{(arene)MLκ (N∩N) Cl}]PF 6 . All act bidentate chelating nitrogen donors κ fashion while forming complexes. In vitro anti‐tumour activity 10 against...
Half-sandwich organometallic rhodium and iridium complexes [1–6] have been synthesized with ligands L1 (L1 = Pyridin-2-ylmethylene picolinichydrazine) L2 (L2 Pyridin-3-ylmethylene picolinichydrazine). Treatment of [{Cp∗MCl2}2] (M Rh/Ir) in methanol has yielded mononuclear cationic such as [{Cp∗M(L1N∩N)Cl}]PF6 where {M Rh (1) Ir (2)} dinuclear [{(Cp∗MCl)2(L1N∩N, N∩N)}]PF6 (3) (4)} 1:2 1:1 metal dimer to ligand ratios respectively. Reactions both two metalla-macrocyclic dicationic...
The reaction of [( p ‐cymene)RuCl 2 ] and [Cp*MCl (M = Rh/Ir) with benzoyl (2‐pyrimidyl) thiourea (L1) (4‐picolyl) (L2) led to the formation cationic complexes bearing formula [(arene) M (L1)к (N,S) Cl] + (L2)к ( N,S ) ‐cymene, Ru, 1 , 4 ); Cp*, Rh 5 Ir 3 6 )]. Precursor compounds reacted (6‐picolyl) (L3) affording neutral having (L3)к S Cl [arene 7 8 ), 9 X‐ray studies revealed that methyl substituent attached pyridine ring in ligands L2 L3 affects its coordination mode. When group is at...