Rosangela Santalucia

ORCID: 0000-0002-8775-5697
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About
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Research Areas
  • Advanced Photocatalysis Techniques
  • 2D Materials and Applications
  • Astro and Planetary Science
  • Catalytic Processes in Materials Science
  • Astrophysics and Star Formation Studies
  • MXene and MAX Phase Materials
  • Gas Sensing Nanomaterials and Sensors
  • Catalysis and Hydrodesulfurization Studies
  • Electrochemical Analysis and Applications
  • Nanoparticles: synthesis and applications
  • Lipid Membrane Structure and Behavior
  • Arsenic contamination and mitigation
  • Molecular Spectroscopy and Structure
  • Catalysis and Oxidation Reactions
  • Graphene research and applications
  • Brake Systems and Friction Analysis
  • Building materials and conservation
  • Ammonia Synthesis and Nitrogen Reduction
  • Water Quality Monitoring and Analysis
  • CO2 Reduction Techniques and Catalysts
  • Lubricants and Their Additives
  • Atmospheric Ozone and Climate
  • Nanoparticle-Based Drug Delivery
  • Advancements in Battery Materials
  • RNA Interference and Gene Delivery

University of Turin
2020-2025

International Training Centre of the ILO
2025

National Interuniversity Consortium of Materials Science and Technology
2020-2022

Interface (United States)
2020

Significance Silica particles with a population of nearly free silanols damage cellular membranes and initiate inflammatory reactions. Nearly are found on the surface both fractured quartz amorphous silica particles, their occurrence initiates toxicity silica, thus revisiting ancient paradigm whereby crystallinity is critical for toxicity. This finding resolves lingering questions about origin variability particles. The discovery biological activity opens perspectives prevention silicosis...

10.1073/pnas.2008006117 article EN cc-by-nc-nd Proceedings of the National Academy of Sciences 2020-10-23

Water is a molecule always present in the reaction environment photocatalytic and biomedical applications of TiO2 better understanding its interaction with surface nanoparticles crucial to develop materials improved performance. In this contribution, we first studied nature structure exposed facets three commercial samples (i.e., P25, SX001, PC105) by electron microscopy IR spectroscopy adsorbed CO. The morphological information was then correlated water adsorption properties, investigated...

10.3390/molecules25204605 article EN cc-by Molecules 2020-10-10

Cholesterol, the essential building block of cellular membranes, has proven to be a useful tool for increasing biocompatibility and bioavailability drug delivery systems in cancer treatment. Resveratrol, natural polyphenolic compound with promising anticancer properties, faces significant limitations due its low solubility bioavailability, hindering clinical utility. Therefore, present study, we aimed design cholesterol-functionalized cyclodextrin nanosponges (Chol-NSs) tunable cholesterol...

10.3390/ijms26031213 article EN International Journal of Molecular Sciences 2025-01-30

HCN in the gas form is considered as a primary nitrogen source for synthesis of prebiotic molecules extraterrestrial environments. Nevertheless, research mainly focused on reactivity and its derivatives aqueous systems, often using external high-energy supply cosmic rays or high energy photons. Very few studies have been devoted to chemistry phase at gas/solid interphase, although they represent more common scenarios outer space. In this paper we report about highly pure 150-300 K range...

10.1039/d1cp05407d article EN cc-by Physical Chemistry Chemical Physics 2022-01-01

Understanding the interaction between hydrogen cyanide (HCN) and silicate surfaces is crucial for elucidating prebiotic processes occurring on interstellar grain cores as well in cometary meteoritic matrices. In this study, we characterized adsorption features of HCN crystalline forsterite (Mg2SiO4) surfaces, one most abundant cosmic silicates, by combining experimental infrared spectra at low temperatures (100–150 K) with periodic DFT simulations. Results showed coexistence both molecular...

10.1021/acs.jpcc.4c03454 article EN The Journal of Physical Chemistry C 2024-08-20

MoS2/TiO2-based nanostructures have attracted extensive attention due to their high performance in many fields, including photocatalysis. In this contribution, MoS2 were prepared via an situ bottom-up approach at the surface of shape-controlled TiO2 nanoparticles (TiO2 nanosheets and bipyramids). Furthermore, a multi-technique by combining electron microscopy spectroscopic methods was employed. More detail, morphology/structure vibrational/optical properties slabs on anatase bipyramidal...

10.3390/catal12111414 article EN Catalysts 2022-11-11

The photoreduction of the Mo6+/SiO2 system with CO was investigated in situ, employing a recently developed experimental setup allowing for acquisition transmission FT-IR spectra under simultaneous UV irradiation. Carbon monoxide, besides acting as reducing agent such processes, is also useful probe molecule able to detect coordinatively unsaturated sites exposed on surface. unprecedented quality spectroscopic data, obtained function reduction time, allowed us better rationalize different...

10.3390/molecules26061700 article EN cc-by Molecules 2021-03-18

MoS2/TiO2 nanostructures made of MoS2 nanoparticles covering TiO2 nanosheets have been synthesized, either via ex situ or in approaches. The morphology and structure the hybrid investigated imaged by means X-ray diffraction (XRD) analysis high-resolution transmission electron microscopy (HRTEM), while vibrational optical properties Raman, Fourier-transform infrared (FTIR), UV−visible (UV–vis) spectroscopies. Different stacking levels distribution on carefully evaluated from HRTEM images....

10.3390/app11010143 article EN cc-by Applied Sciences 2020-12-25

Asteroids are the most ancient bodies of a planetary system, mostly formed during accretion protoplanetary disk. They can be made either rocky and metallic materials, they sources important species which fundamental for emergence life on planets. In our history, heavy late bombardment (4.0−3.8 Gya ago), large quantity meteorites (the asteroids that impact planet) fall onto earth crust, bringing several interstellar complex organic molecules, as well other (like phosphorus),...

10.5194/epsc2024-1177 preprint EN 2024-07-03

MoS2/TiO2 nanostructures made of MoS2 nanoparticles covering TiO2 nanosheets have been synthesized, either via ex-situ or in-situ approaches. Morphology and structure hybrid investigated imaged by means X-ray diffraction (XRD) analysis high-resolution transmission electron microscopy (HRTEM), while the vibrational optical properties Raman, Fourier-transform infrared spectroscopy (FTIR) UV−visible (UV-Vis) techniques. The different stacking degrees together with size distribution...

10.20944/preprints202011.0579.v1 preprint EN 2020-11-23

Owing to its excellent photoactivity, good stability and low cost, TiO<sub>2</sub> is one of the most studied semiconductor materials convert CO<sub>2</sub> into useful chemicals, contributing mitigate global warming. In this review, starting from basic kinetic thermodynamic principles photoreduction, focus on surface processes involved in capture subsequent reactivity TiO<sub>2</sub>. particular, role different morphologies, facets heterostructures...

10.2174/2665976x01999201022142435 article EN Journal of Photocatalysis 2020-10-23

Forsterite is a nesosilicate with Mg2SiO4 composition, representing the iron-free endmember of family olivines. Interestingly, aside its finding as mineral component Earth’s crust and mantle, it has been observed in extraterrestrial environments where have found principal inorganic constituents meteorites, comets core dust grains interstellar medium protoplanetary disks [1]. It often indicated that these could be possible sites for occurrence astrochemical reactions involving...

10.5194/epsc2020-875 article EN 2020-10-08
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