Energy storage technologies are required to make full use of renewable energy sources, and electrochemical cells offer a great deal flexibility in the design systems. For large scale be viable, materials employed device production methods need low cost, devices should long lasting safety during operation is utmost importance. power densities lesser concern. these reasons, battery chemistries that aqueous electrolytes favorable candidates where quantities stored. Herein we describe several...

The objective of this study was to clarify the effect grain size on corrosion rate across friction stir welded AZ31B joints when exposed in aqueous NaCl solutions. Grain variations were achieved by preparing using different tempers. Single potentiodynamic polarization measurements made isolated base metal and zone 0.6 M solution revealed no significant difference between anodic kinetics, but an apparent cathodic kinetics. attempt correlate extracted current density (icorr) values (d−0.5)...

Hydrogen evolution (HE) on anodically polarized Mg, commonly referred to as Negative Difference Effect, was studied by galvanodynamic measurements coupled with real-time gravimetric H 2 volume collection, the Scanning Vibrating Electrode Technique and potentiodynamic polarization experiments.High purity Mg (99.96% Mg) electrodes were in chloride-free 0.1 M citric acid solution buffered at pH aim of determining source anodic HE role corrosion film process.In such conditions pH, typical dark...

The scanning vibrating electrode technique (SVET) was utilized to experimentally validate the applicability of finite element modeling (FEM) in simulating macro-galvanic-induced corrosion AA7050 coupled SS316, environments representative boldly exposed surface an actual fastener couple. FEM boundary conditions were modified from SVET which AA7050-SS316 couple sample initially exposed, order better represent steady-state corroding localized corrosion-prone AA7050. Better agreements between...

The scanning vibrating electrode technique (SVET) was employed to examine the effect of 'galvanic throwing power' and distance over which a Mg-rich primer (MgRP) provided sacrificial anode-based cathodic protection AA2024-T351. Three systems were investigated in full immersion conditions where same MgRP used with three different pretreatments: Non-film forming (NFF), trivalent chromium pretreatment (TCP) anodization chromate seal (ACS). Experiments conducted two coating/defect area ratios...

Spent nuclear fuel in the U.K. is stored within ponds dosed with NaOH order to inhibit corrosion and, ensure efficiency of storage regimes, there a need define and quantify processes involved during immersion cladding. In this project, state-of-the-art characterisation techniques were employed image corroding surfaces two cladding materials: stainless steel Magnox. Advanced gas-cooled reactor consists 20Cr-25Ni-Nb stabilised irradiation microstructure undergoes significant changes, including...

The study of conducting polymers (CPs) is high current interest due to their wide application in a range optical and electronic devices. Poly(3,4-Ethylenedioxythiophene)-Poly(Styrene Sulfonate) (PEDOT:PSS) considered one the most electrochemically thermally stable CPs currently available. In many applications there requirement for electrical contact be made between an organic PEDOT:PSS layer metallic substrate. order gauge long term stability metal-CP interface, understanding interaction CP...

The efficacy of an electrocoated system that uses a Zr-based conversion coating was assessed to protect galvannealed (GA) steel. aim determine if has the potential replace with traditional zinc phosphate (ZnP) coating, where there are concerns for environmental and economic sustainability. A comparative study between two coatings, control no is presented. Data from AC DC electrochemistry utilized surface analysis investigations pristine specimens, scanning electron microscopy, x-ray...

In-coating phenyl phosphonic acid (H2PP) additions are investigated as inhibitors of corrosion-driven organic coating disbondment on hot-dip galvanized (HDG) steel surfaces. In-situ scanning Kelvin probe (SKP) experiments under atmospheric corrosion conditions used to study the influence quantity dissolved H2PP in kinetics delamination. It is demonstrated that increasing levels in-coating progressively lengthen time for delamination become established. Once underfilm becomes initiated, rates...

Phenylphosphonic acid (H2PP) is investigated as a corrosion inhibitor of hot dip galvanized steel (HDG) fully immersed in 5% (w/v) sodium chloride electrolyte. An in-situ Scanning Vibrating Electrode Technique (SVET) used where concentrations H2PP are systematically added to the electrolyte neutral conditions. H2PP, at concentration 5 × 10−2 mol dm−3, shown effectively inhibit localized over 24 h period with 96% efficiency. compared phosphate (Na3PO4) same wide pH range.

This study investigates the effect of surface treatment on formation Zr-based conversion coatings AA7075-T6 automotive aluminum alloys and their resistance to filiform corrosion (FFC). Two different treatments were studied: (i) alkaline-cleaning (ii) with a subsequent acid deoxidation step. A model poly-vinyl butyral primer coating was used as topcoat specimens studied without application coating. Comparisons made against control that had no treatment. The FFC filament initiation time...

The performance of chromate in protecting AA7050-T7451 coupled to 316SS simulated fastener environments, including those representative the boldly exposed surfaces and downhole conditions, was investigated utilizing a number electrochemical surface characterization techniques. influence pH Al 3+ on galvanic coupling behavior damage evolution AA7050 as function concentration were assessed. degree inhibition observed decrease decreased, owing speciation reduced capacity suppress hydrogen...