A5017138252- Crystallization and Solubility Studies
- X-ray Diffraction in Crystallography
- Metal complexes synthesis and properties
- Organometallic Complex Synthesis and Catalysis
- Lanthanide and Transition Metal Complexes
- Microwave-Assisted Synthesis and Applications
- Magnetism in coordination complexes
- Semiconductor materials and devices
- MXene and MAX Phase Materials
- Catalytic Cross-Coupling Reactions
- Muon and positron interactions and applications
- Catalytic C–H Functionalization Methods
- Asymmetric Hydrogenation and Catalysis
- Gyrotron and Vacuum Electronics Research
- Inorganic Chemistry and Materials
- Luminescence Properties of Advanced Materials
- Planetary Science and Exploration
- Catalytic Alkyne Reactions
- Catalysis and Oxidation Reactions
- Nanotechnology research and applications
- Chromatography in Natural Products
- Metal and Thin Film Mechanics
- Oxidative Organic Chemistry Reactions
- Carbon dioxide utilization in catalysis
- Coordination Chemistry and Organometallics
Prokhorov General Physics Institute
2023-2025
MIREA - Russian Technological University
2019-2025
Russian Academy of Sciences
2006-2025
Moscow Institute of Physics and Technology
2024
Moscow Power Engineering Institute
2024
Moscow State University of Fine Chemical Technologies
2014-2019
Skolkovo Foundation
2017-2018
NS Kurnakova Institute of General and Inorganic Chemistry
2006-2015
Lomonosov Moscow State University
2015
Kurchatov Institute
2013
Neophylpalladium complexes of the type [Pd(CH(2)CMe(2)Ph)(N-O)(L)], where N-O is picolinate or a related bidentate, monoanionic ligand (6-methylpyridine-2-carboxylate, quinoline-2-carboxylate, 2-pyridylacetate pyridine-2-sulfonate) and L pyridine derivative, efficiently catalyze oxidation range aliphatic, benzylic allylic alcohols with oxygen, without requiring any additives. A versatile method described which allows synthesis above-mentioned minimum synthetic effort from readily available...
Gold(III) complexation with the octadecahydrido-eicosaborate anion [B20H18]2− was studied for first time. It found that when gold(III) complexes [Au(L)Cl2]BF4 (L = bipy, phen) reacted [B20H18]2−, [Au(L)Cl2]2[B20H18] were isolated. The compounds consisted of a cationic complex [Au(L)Cl2]+ and hydridoborate cluster as counterion. X-ray diffraction studies revealed weak B–H...Au interactions both compounds. Note more reactive anions [BnHn]2− (n 10, 12) in similar reactions resulted gold mirror...
An original plasma chemical process initiated by microwave discharge in a mixture of metal and dielectric powders was applied to prepare specific materials, which consisted microsized spherical particles aluminum oxide covered with silver nanoparticles. The prepared materials are highly uniform shape, size distribution, composition. Their cytotoxicity investigated using the human cell lines MCF7, HEK293T, A549, VA-13 bacterial strains E. coli JW5503 (ΔtolC) K12. found not exceed starting...
Palladium(I) carbonyl carboxylate complexes [Pd(μ-CO)(μ-RCO2)]n (R = Me, n 4; R CMe3, 6) and the corresponding palladium(II) carboxylates (acetate pivalate) catalyze cyclopropanation of olefins with ethyl diazoacetate. The performance these catalysts is similar in terms selectivity cyclopropane yields, regardless oxidation state metal center. However rates reactions are significantly higher for acetate based than pivalate derivatives, which suggests that main catalytic species containing...
Reactions of the polynuclear palladium carboxylate complexes (binary carboxylates and nitrosyl carboxylates) with acetonitrile in some common organic solvents are described. It was found that reaction acetate Pd(3)(μ-CH(3)CO(2))(6) benzene leads to formation a binuclear complex Pd(2)(C(6)H(4)-o-C(=NH)CH(3))(2)(CH(3)CO(2))(2) containing molecules orthometallated 1-phenylethanimine formed as result C-C-coupling benzene. Nitrosyl Pd(4)(NO)(2)(RCO(2))(6) promote more complicated transformations...
Abstract New gold(III) carboxylate complexes [(L)Au( R CO 2 ) ]BF 4 ( = CH 3 , CMe CF with N, N‐chelating ligands L (L phenanthroline, 2, 2′‐bipyridine), were obtained by the treatment of corresponding chloride [(L)AuCl silver(I) carboxylates. The structure [(bipy)Au(CF complex was determined X‐ray diffraction analysis. When five‐coordinate ] 9‐dimethyl‐1, 10‐phenanthroline, 2′‐biquinoline) used as starting materials same reaction led to unstable products, which could not be isolated and...