Llew Rintoul

ORCID: 0000-0003-0489-4446
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About
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Research Areas
  • Porphyrin and Phthalocyanine Chemistry
  • Magnetism in coordination complexes
  • X-ray Diffraction in Crystallography
  • Crystallization and Solubility Studies
  • Microplastics and Plastic Pollution
  • Mineralogy and Gemology Studies
  • Metal-Catalyzed Oxygenation Mechanisms
  • Crystal Structures and Properties
  • Spectroscopy and Chemometric Analyses
  • Spectroscopy Techniques in Biomedical and Chemical Research
  • Clay minerals and soil interactions
  • Advanced Radiotherapy Techniques
  • Crystallography and molecular interactions
  • Paleontology and Stratigraphy of Fossils
  • Recycling and Waste Management Techniques
  • Conducting polymers and applications
  • Geochemistry and Elemental Analysis
  • Epoxy Resin Curing Processes
  • Osteoarthritis Treatment and Mechanisms
  • Electron Spin Resonance Studies
  • Glass properties and applications
  • Drug Solubulity and Delivery Systems
  • Cultural Heritage Materials Analysis
  • Photosynthetic Processes and Mechanisms
  • Radioactive element chemistry and processing

Queensland University of Technology
2012-2021

The University of Queensland
1995-2008

University of Pennsylvania
2008

Australian National University
2004

RMIT University
2004

Vietnam National University, Hanoi
1997

Royal Brisbane and Women's Hospital
1995

Queen's University
1990

University of Dundee
1985

Abstract Azurite [Cu 2+ 3 (CO ) 2 (OH) ] and malachite )(OH) are both monoclinic hydroxy carbonates of copper. The Raman spectra these two minerals were collected at 298 77 K together with the single crystal azurite K. contain modes three separate vibrational groups: OH, CO Cu O. Accordingly, for bands 3453 3427 cm −1 have been assigned as O H stretching mode bending found 1035 952 . Malachite displays hydroxyl 3474 3404 which shift to 3470 3400 while out‐of‐plane 1045 875 For carbonate...

10.1002/jrs.848 article EN Journal of Raman Spectroscopy 2002-03-08

Radical assembly: Halogen bonding has been observed for the first time between an isoindoline nitroxide and iodoperfluorocarbon (see figure), which cocrystallize to form a discrete 2:1 supramolecular compound in N--O(.)I halogen is dominant intermolecular interaction. This illustrates potential use of tectons assembly organic spin systems.The 1,1,3,3-tetramethylisoindolin-2-yloxyl (TMIO) 1,4-diiodotetrafluorobenzene readily complex that shows evidence relatively strong bonding. interaction...

10.1002/chem.200801920 article EN Chemistry - A European Journal 2009-03-12

Polyacrylamide gels (PAGs) are used for magnetic resonance imaging radiation dosimetry. Fourier transform (FT) Raman spectroscopy studies were undertaken to investigate cross-linking changes during the copolymerization of polyacrylamide in spectral range 200-3500 . Vibrational bands 1285 and 1256 assigned acrylamide bis-acrylamide single binding modes. Bands found decrease amplitude with increasing absorbed dose as a result copolymerization. Principal component regression was performed on...

10.1088/0031-9155/43/12/017 article EN Physics in Medicine and Biology 1998-12-01

Polarisation Raman microscopy is used to study tubular chrysotile. The OH-stretching region characterised by the inner surface OH bands at 3695, 3686 and 3678 cm-1 band 3643 cm-1. outer pointing away from Mg-layer gives rise two overlapping 3695 due a positional disorder caused folding of layers. These are in-phase vibrations whereas represent out-of-phase vibrations. 1102 an antisymmetric stretching mode Si–O perpendicular sheet. From 692 705 first one assigned symmetric Si–O–Si stretch...

10.1039/a809238i article EN Physical Chemistry Chemical Physics 1999-01-01

The effects of ionizing radiation in different compositions polymer gel dosimeters are investigated using FT-Raman spectroscopy and NMR T2 relaxation times. manufactured from concentrations comonomers (acrylamide N,N'-methylene-bis-acrylamide) dispersed an aqueous gelatin matrix. Results analysed a model fast exchange magnetization between three proton pools. fraction protons each pool is determined the known chemical composition dosimeter spectroscopy. Based on these results, physical...

10.1088/0031-9155/46/4/311 article EN other-oa Physics in Medicine and Biology 2001-03-14

10.1016/j.saa.2007.08.017 article EN Spectrochimica Acta Part A Molecular and Biomolecular Spectroscopy 2007-09-04

10.1016/j.saa.2011.03.002 article EN Spectrochimica Acta Part A Molecular and Biomolecular Spectroscopy 2011-03-16
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