A5022052654- Crystal Structures and Properties
- X-ray Diffraction in Crystallography
- Crystallization and Solubility Studies
- Luminescence Properties of Advanced Materials
- High-Temperature Coating Behaviors
- Inorganic Chemistry and Materials
- High Entropy Alloys Studies
- Solid-state spectroscopy and crystallography
- Advanced Condensed Matter Physics
- Chemical Synthesis and Characterization
- Advanced materials and composites
- Polyoxometalates: Synthesis and Applications
- Thermal Expansion and Ionic Conductivity
- Sulfur-Based Synthesis Techniques
- Inorganic Fluorides and Related Compounds
- Additive Manufacturing Materials and Processes
- Catalytic C–H Functionalization Methods
- Metal-Organic Frameworks: Synthesis and Applications
- Radical Photochemical Reactions
- nanoparticles nucleation surface interactions
- Magnesium Alloys: Properties and Applications
- Mercury impact and mitigation studies
- Polymer Synthesis and Characterization
- Iron-based superconductors research
- Optical properties and cooling technologies in crystalline materials
Northwest Normal University
2024-2025
Changji University
2020-2024
Chongqing University of Technology
2021-2024
Shenyang University of Technology
2024
Changchun University of Technology
2019
Hulunbuir University
2015-2017
University of Chinese Academy of Sciences
2014-2016
Xinjiang Technical Institute of Physics & Chemistry
2014-2016
Chinese Academy of Sciences
2014
Based on the combination of two different anionic groups (SiO4 and BO3) utility a XBa6 (X = Cl, Br) polar template, new salt-inclusion compounds, Ba4(BO3)3(SiO4)·Ba3X have been successfully synthesized by high-temperature solution method for first time. They are isostructural their structures feature ∞3[Ba4(BO3)3(SiO4)] framework with 1D channels along c axis, in which resided ∞1[Ba3X] chains. It is worth noting that they alkaline-earth metal borosilicate halides to be used as nonlinear...
A series of K3–xNaxB6O10Br (0.5 ≤ x 1.2) polycrystalline samples have been synthesized by the standard solid-state reaction method. Four stoichiometric crystals (x = 0.13, 0.67, 1.30, 2.20) successfully grown from high-temperature solution, and crystal structures were determined single-crystal X-ray diffraction. Interestingly, Na+ concentration plays a profound role to influence structure. Up about 23% 0.7) K+ ions can be substituted with same noncentrosymmetric (NCS) structure K3B6O10Br...
Herein, we present an unprecedented electrochemical approach for aminooxygenation of enamides with azoles under transition-metal- and oxidizing-reagent-free conditions. This method affords 4-azolated oxazolines directly from readily available starting materials in up to 95% yield. Central our success is the utilization electrical energy as primary driving force NaBr a mediator. Importantly, resulting exhibit potential utility ligands (pyrazole-oxazoline ligands) transition-metal-catalyzed reactions.
The perovskite structure is a good candidate for the design of functional materials. On basis combination B6O13 groups and XM6 (X = Cl, Br; M alkali metals) octahedra, three new perovskite-related crystals Na3B6O10Cl, RbNa2B6O10Cl, RbNa2B6O10Br have been synthesized by high-temperature solution method first time. Na3B6O10Cl RbNa2B6O10Cl are isostructural crystallize in noncentrosymmetric (NCS) space group P212121 (No. 19), while belongs to centrosymmetric (CS) Pnma 62). phenomenon that...
Two new borate halides consist of a B<sub>4</sub>O<sub>9</sub>framework and [Na<sub>3</sub>Br] chain which have not been found in other alkali metal halides.
A metal- and oxidizing reagent-free electrochemical dehydrogenative annulation of enamides with O -nucleophiles has been developed, leading to a series 4-oxo-oxazolines under environmentally friendly conditions.
Abstract The magnesium borate fluoride Mg 5 (BO 3 ) F was grown by spontaneous crystallization with molten flux based on the MgF 2 ‐LiF‐Na CO ‐H BO solvent. Structure solution from single‐crystal X‐ray diffraction shows that title compound crystallizes in orthorhombic space group Pnma (No. 62) cell dimensions of a = 10.068(5) Å, b 14.858(7) c 4.540(2) Å and Z 4. Its structure features three‐dimensional (3D) Mg‐O‐F framework composed MgO 6 polyhedra isolated groups. detailed comparison...
Abstract Two new borates, Sr8MB18O36 (M = Zn or Cd) with expected formulas representing the Sr:M ratio of 8:1, were synthesized. Their structures determined by single-crystal X-ray diffraction. They both crystallize in same space group R−3c and possess isolated [B18O36]18− anionic group. In this work, not only crystals designed but they also synthesized successfully. addition, reasons why is 8:1 are explained.
A new borate chloride, Li 2 B 5 O 8 Cl, has been obtained. It exhibits complicated interpenetrating 3D B–O frameworks composed of the functional building block (FBB) [B 10 ], enriching structural diversity configurations. The theoretical study indicates that birefringence is estimated to be 0.026 at 1064 nm. Meanwhile, structure-property relationships were analyzed through first-principles calculation with a bandgap 5.737 eV for GGA and 6.880 HSE06, electronic properties each group are by...
The adsorption of active coke is a good method to control mercury in coal-fired power plants, but spent powdered activated (SPAC) will cause secondary pollution and waste resources if it not properly treated. purpose this study was explore the desorption performance SPAC when heated drop-tube reactor under different atmospheres. carbon consumption 0.13%, 0.24%, 0.17%, 0.16%, 0.14%, conditions N
Two new tin(II) phosphates, SnII SnIV (PO4 )2 and SrSn(PO4 )PO2 (OH)2 , were synthesized by the high-temperature solution method hydrothermal method, respectively. Theoretical study indicates that introducing with stereochemical activity lone pairs (SCALP) in metal birefringence was enhanced, 0.048@1064 nm for 0.080@1064 .
Abstract A new sodium rubidium strontium borate, Na 2 Rb SrB 18 O 30 , has been successfully synthesized via the high temperature solution method and characterized by single crystal X ray diffraction. The compound crystallizes in monoclinic space group P 1 / c (No. 14) with following cell parameters: a =8.464(5) Å, b =8.516(5) =17.110(10) β =92.281(8)°, V=1232.3(12) Å 3 Z =2. fundamental building block (FBB) of is [B 9 19 ] 11− which consists three 7 5− groups bridged oxygen atoms. FBB...
Abstract The new title compounds are prepared by solid state reactions of stoichiometric mixtures MO 3 (M: Mo, W), Rb 2 CO , and Na (673 K for 10 h 843 48 h).