Xiang Shi Tan

ORCID: 0000-0003-1010-6776
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About
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Research Areas
  • Magnetism in coordination complexes
  • Metal complexes synthesis and properties
  • Metal-Catalyzed Oxygenation Mechanisms
  • Crystallization and Solubility Studies
  • Metal-Organic Frameworks: Synthesis and Applications
  • X-ray Diffraction in Crystallography
  • Crystallography and molecular interactions
  • Catalysis and Hydrodesulfurization Studies
  • Catalysis for Biomass Conversion
  • Lanthanide and Transition Metal Complexes
  • Breast Cancer Treatment Studies
  • Biodiesel Production and Applications
  • Photosynthetic Processes and Mechanisms
  • Insect Resistance and Genetics
  • Biofuel production and bioconversion
  • Crystal structures of chemical compounds
  • Polysaccharides and Plant Cell Walls
  • Neurobiology and Insect Physiology Research
  • Advanced biosensing and bioanalysis techniques
  • Metalloenzymes and iron-sulfur proteins
  • Global Cancer Incidence and Screening
  • Chemical Synthesis and Analysis
  • Electron Spin Resonance Studies
  • Lignin and Wood Chemistry
  • Ginseng Biological Effects and Applications

China Three Gorges University
2025

Citrus Research Institute
2023-2024

Southwest University
2023-2024

Guiyang Medical University
2020-2023

Guizhou University
2020-2023

Affiliated Hospital of Guizhou Medical University
2020-2023

Fudan University
1997-2013

Laboratoire de Chimie et Biologie des Métaux
2005

Texas A&M University
2002

Ibaraki University
1998-2002

The serum albumin-to-globulin ratio (A/G) has been widely used as a biomarker to assess inflammation, immunity, and nutritional status. However, relatively few studies have conducted on the predictive value of A/G in stroke. Therefore, this study aimed evaluate correlation between levels stroke prognosis, provide new reference for risk assessment management patients. Data were sourced from National Health Nutrition Examination Survey (NHANES) 2009-2020. utilized questionnaire responses 24-h...

10.3389/fnut.2025.1512165 article EN cc-by Frontiers in Nutrition 2025-02-25

The crystal structures of two CN- bridged bimetallic copper(II)−chromiun(III) complexes, [{(Cu(dien))2Cr(CN)6}n][Cu(dien)(H2O)Cr(CN)6]n·4nH2O (1) and [(Cu(edma))3Cr(CN)6] (2) (where dien edma are diethylenetriamine ethylenediaminemonoacetate respectively), have been determined. Complex 1 (C24H49N21O5Cr2Cu3) crystallizes in the monoclinic system, space group P21/c, with a = 20.509(2) Å, b 14.376(3) c 15.040(4) β 96.03(2),° Z 4. In structure, complex has distinct ionic units: one is cationic...

10.1021/ic960481g article EN Inorganic Chemistry 1997-01-01

p-Synephrine is a common alkaloid widely distributed in citrus fruits. However, the effects of p-synephrine on metabolic profiles individuals with energy abnormalities are still unclear. In study, we investigated effect homeostasis and using high fat diet (HFD)-induced mouse model. We found that inhibited gain body weight, liver weight white adipose tissues induced by HFD. supplementation also reduced levels serum total cholesterol (TC), triglyceride (TG) low-density lipoprotein (LDL-C) but...

10.3390/nu16020248 article EN Nutrients 2024-01-12

Abstract Flavonoids are a major class of polyphenolic compounds that occur naturally in plants and widely distributed various dietary products. exhibit prominent physicochemical properties biological activities, thereby garnering considerable attention. Notably, the functionalities flavonoids structurally dependent. Variations chemical structure lead to differences characteristics among different flavonoid types. Structural alterations can modify these characteristics, influencing activities...

10.1002/fft2.494 article EN cc-by-nc-nd Food Frontiers 2024-10-16

Kinetics of methyl group transfer between the Ni−Fe−S-containing acetyl-CoA synthase (ACS) and corrinoid protein (CoFeSP) from Clostridium thermoaceticum were investigated using stopped-flow method at 390 nm. Rates reaction CH3-Co3+FeSP + ACSred ⇄ Co1+FeSP CH3-ACSox in both forward reverse directions determined various reductant concentrations. Ti3+citrate, dithionite, CO used to reductively activate ACS (forming ACSred). The simplest mechanism that adequately fit data involved formation a...

10.1021/ja016676r article EN Journal of the American Chemical Society 2002-05-09

The novel tetranuclear copper(II) complex [Cu4(hpda)4][ClO4]4·H2O (Hhpda = N-(2-hydroxyethyl)-1,3-propanediamine) with an open cubane-like Cu4O4 framework has been obtained and characterized by X-ray crystallography magnetic measurements, exhibiting strongly ferromagnetic exchange interaction.

10.1039/a903524i article EN Journal of the Chemical Society. Dalton transactions 1999-01-01

Abstract Single‐atom catalysts (SACs) have attracted extensive attention since their emergence. During the single‐atomic catalytic process, “active center” exists in form of atomical monodispersion, with nearly 100 % utilization metal atoms. Uniform and atomically dispersed centers give SACs pronounced reaction activity chemical selectivity. Here, we review development processes, synthetic strategies, characterization methods, applications CO 2 reductive upgrading. Also, a comparison...

10.1002/cctc.202100966 article EN ChemCatChem 2021-08-27

A five-co-ordinate manganese(II) complex [Mn(ntb)(Hsal)][ClO4], where ntb is tris(benzimidazol-2-ylmethyl)amine and Hsal– the anion of salicyclic acid (H2sal), has been prepared characterized by X-ray crystallography. The manganese adopts a distorted trigonal-bipyramidal co-ordination geometry with N4O ligand donor set bears structural similarities to active site superoxide dismutase. electro-chemical properties were studied in MeCN cyclic voltammetry. can catalyse dismutation (O2–)...

10.1039/a707433f article EN Journal of the Chemical Society. Dalton transactions 1998-01-01

The continued interest in protein engineering has led to intense efforts developing novel stable enzymes, which could not only give boost industrial and biomedical applications, but also enhance our understanding of the structure-function relationships proteins. We present here generation three hybrid proteins cytochrome c (cyt c) peroxidase via structure-based rational mutagenesis cyt c. Several residues (positions 67, 70, 71 80) distal heme region were mutated highly conserved amino acids...

10.1093/protein/gzt008 article EN Protein Engineering Design and Selection 2013-03-20
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