Silvia Pugliese

ORCID: 0000-0003-1299-9918
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About
Contact & Profiles
Research Areas
  • Crystallization and Solubility Studies
  • X-ray Diffraction in Crystallography
  • CO2 Reduction Techniques and Catalysts
  • Crystallography and molecular interactions
  • Ionic liquids properties and applications
  • Carbon dioxide utilization in catalysis
  • Advanced Chemical Sensor Technologies
  • Molecular Junctions and Nanostructures
  • Catalytic Processes in Materials Science
  • Perovskite Materials and Applications
  • Olfactory and Sensory Function Studies
  • Electrocatalysts for Energy Conversion
  • Indoor Air Quality and Microbial Exposure
  • Advanced Thermoelectric Materials and Devices

University of Namur
2020-2022

Laboratoire de chimie des processus biologiques
2020-2022

Collège de France
2020-2022

Université Paris Sciences et Lettres
2020-2022

Sorbonne Université
2020-2022

Centre National de la Recherche Scientifique
2020-2022

University of Copenhagen
2020

The exploitation of molecular catalysts for CO2 electrolysis requires their immobilization on the cathode electrolyzer. As an illustration this approach, a Ni-cyclam complex with cyclam derivative functionalized pyrene moiety is synthesized, found to be selective catalyst electroreduction CO, and immobilized carbon nanotube-coated gas diffusion electrode by using noncovalent binding strategy. as-prepared efficient, selective, robust electrocatalytic reduction CO. Very high turnover numbers...

10.1002/cssc.202002092 article EN ChemSusChem 2020-10-21

The development of molecular catalysts for CO2 electroreduction within electrolyzers requests their immobilization on the electrodes. While a variety methods have been explored heterogenization homogeneous complexes, novel approach using hierarchical porous carbon material, derived from metal-organic framework, is reported as support well-known catalyst [Re(bpy)(CO)3 Cl] (bpy=2,2'-bipyridine). This cathodic hybrid named Re@HPC (HPC=hierarchical carbon), has tested mixture an ionic liquid...

10.1002/cssc.202002014 article EN ChemSusChem 2020-09-25

Molecular catalysis for selective CO2 electroreduction into CO can be achieved with a variety of metal complexes. Their immobilization on cathodes is required their practical implementation in electrolytic cells and benefit from the advantages solid material such as easy separation products catalysts, efficient electron transfer to catalyst, high stability. However, this approach remains insufficiently explored up now. Here, using an appropriate original modification cyclam ligand, we report...

10.1021/acs.inorgchem.2c01645 article EN Inorganic Chemistry 2022-09-27

Environmental contextThe fresh pleasant smell of laundry dried outside in sunlight is recognised by most people, but despite decades speculation the origin has not been demonstrated. We show that line-dried due to unique combination traces atmospheric hydrocarbons, and a wet fabric surface. This surface photochemistry likely be widespread environment on surfaces natural materials. AbstractIn this study, we find drying method key element generating well-known scent laundry, which argue...

10.1071/en19206 article EN Environmental Chemistry 2020-01-01
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