A5067358905- Crystallization and Solubility Studies
- X-ray Diffraction in Crystallography
- Porphyrin and Phthalocyanine Chemistry
- Advanced Fiber Optic Sensors
- Radical Photochemical Reactions
- Catalytic C–H Functionalization Methods
- Photonic and Optical Devices
- Surface Chemistry and Catalysis
- RNA and protein synthesis mechanisms
- Fluorine in Organic Chemistry
- Photochemistry and Electron Transfer Studies
- Crystallography and molecular interactions
- Metal-Catalyzed Oxygenation Mechanisms
- Photodynamic Therapy Research Studies
- Advanced biosensing and bioanalysis techniques
- Molecular Junctions and Nanostructures
- Electrocatalysts for Energy Conversion
- Sulfur-Based Synthesis Techniques
- DNA and Nucleic Acid Chemistry
- Oxidative Organic Chemistry Reactions
- Advanced Fiber Laser Technologies
- Enzyme Catalysis and Immobilization
- Advanced battery technologies research
- Metalloenzymes and iron-sulfur proteins
- Remote-Sensing Image Classification
Sun Yat-sen University
2024-2025
Tianshui Normal University
2024
Chinese University of Hong Kong, Shenzhen
2021-2024
North University of China
2023-2024
Technion – Israel Institute of Technology
2018-2023
Anhui University
2022-2023
Xiamen University of Technology
2020
Huazhong University of Science and Technology
2017-2019
Wuhan National Laboratory for Optoelectronics
2017-2019
University of Haifa
2019
The direct coupling of aldehydes with petrochemical feedstock alkenes and alkynes would represent a practical streamlined approach for allylation allenylation chemistry. However, conventional approaches commonly require preactivated substrates or strong bases to generate allylic propargylic carbanions only afford branched propargylation products. Developing mild selective access synthetically useful linear products is highly desirable, albeit formidable challenges. We report strategy using...
In the field of condition monitoring, main measures for classification recognition are one‐dimensional (1D) signal analyses from time, frequency, or time—frequency domains. However, raw signals, unclear dominance features, weakness and sparsity characteristic frequencies, noise interference increase difficulty feature extraction 1D data. Therefore, to address these issues fully utilize phase information status a bispectral technology deep learning‐network‐based method image proposed in this...
Photocatalysis based on chromophores such as porphyrin, coumarin, anthraquinone, and pyrene is a promising technology to achieve green synthesis of various high-value chemicals, but the robust non-covalent immobilization onto light-inert scaffolds for industrialization-oriented heterogeneous photocatalysis remains challenging. In this work, simple universal strategy presented preparing highly efficient recyclable photocatalysts from chromophores, which achieved via biotinylation chromophore...
We proposed and experimentally demonstrated paralleled Mach-Zehnder interferometers (MZIs) in few-mode multicore fiber (FM-MCF) for temperature strain discriminative sensing. A section of FM-MCF is sandwich-spliced between two single-mode (SM-MCF) with a rotational offset. The arbitrarily controlled angular misalignment generates intentional intermodal interferences outer cores the thus multiple MZI structures are implemented. Experimental results show that sensitivities 105.8 pm/°C 223.6...
An eight-member series of CF3-substituted difluorophosphorus corroles was prepared for establishing a structure–activity profile these high-potential photosensitizers. It consisted preparing all four possible isomers the monosubstituted corrole and complexes with 2-, 3-, 4-, 5-CF3 groups on macrocycle's periphery. The synthetic pathway to derivatives, beginning (tpfc)PF2, involves two different initial routes: (i) direct electrophilic CF3 incorporation using FSO2CF2CO2Me copper iodide, or...
Abstract There have been few reports on the substituent effect of main‐group‐element corrole complexes as ligand‐centered homogeneous electrocatalysts for hydrogen evolution reaction (HER). The key to comprehend catalytic mechanism and develop efficient catalysts is elucidation effects electronic structure performance energy‐related small molecules. In this work, “push‐pull” substituents electrocatalytic HER phosphorus corroles was investigated by using 5,10,15‐tris(phenyl) (1P),...
Tris- and tetrakis-β-trifluoromethylated gallium (<bold>3CF3-Ga</bold>,<bold>4CF3-Ga</bold>) aluminum (<bold>3CF3-Al</bold>,<bold>4CF3-Al</bold>) corrole systems were synthesized by a facile “one-pot” approach studied in the context of photocatalytic C–H bond activation.
Abstract The economical consideration of using an electrocatalyst in energy‐related field, composed non‐precious/sustainable elements is quite noteworthy. In this work, the phosphorus(V) complex tris‐(pentafluorophenyl)corrole [(TPFC)P V (OH) 2 ] was reported as for hydrogen evolution reaction (HER). electrochemical studies revealed that HER experienced a ECEC pathway (E: electron transfer step, C: chemical step), and possible intermediate [P ]−H species suggested. (TPFC)P displayed...
Abstract Owing to the merits of automatic feature extraction and depth structure, intelligent fault diagnosis based on deep neural networks has become a great concern. However, non-fault state monitoring data volume actual industrial machinery is rich, whereas insufficient weak. Furthermore, achieving multiple mixed-fault diagnoses using skewed distributions extremely difficult. A reconstruction sparse auto-encoder (AE) model-based method for mixed faults proposed in this study bridge these...
Updated perspective and insights about contracted systems in one part of the periodic table which is ever expanding.
A set of gold corrole complexes containing four different β-substituent groups (Br/I/CF3), namely, 4Br–Au, 4I–Au, and 4CF3–Au, were investigated; all showed room temperature phosphorescence. The phosphorescence quantum yields the corroles determined using tetraphenylporphyrin as a reference: Φph (4I–Au, 0.75%) > (4Br–Au, 0.64%) (4CF3-Au, 0.38%). 4CF3–Au exhibited near-IR emission (858 nm, aerobic); absorbance intensity for Q-band was higher than that Soret band. Complex 4I–Au longer lifetime...
Abstract Although the affinity of metallocorroles to axial ligands is quite low, this not case when chelated element phosphorus. This work hence focused on mechanism ligand exchange six‐coordinate phosphorus corroles as a tool for affecting their chemical and physical properties. These fundamental investigations allowed development facile methodologies synthesis large series complexes establishment several new structure/activity profiles that may be used understand predict spectroscopic...
We successfully fabricated the long-period fiber gratings in few-mode fibers (FMF-LPFGs) with micro-tapered method, which are different from traditional LPFGs that only couple fundamental mode to cladding modes obtain multiple resonant dips. There two dips on transmission spectrum of FMF-LPFGs, induced by coupling between and low-order LP03 (dip 1) high-order core LP11 2). Due difference mechanism involved dips, shift wavelengths has characteristics variation external environment parameter....
Abstract Bromination of tris‐ and tetrakis‐trifluoromethylated gallium corroles ( 3CF 3 −Ga 4CF ) afforded tetrabrominated species −4Br−Ga (yields: 20 % 25 %) characterized by NMR, UV‐vis spectroscopy, mass spectrometry. Red‐shifted absorption emission bands were found; displayed 5–12 nm shifts in their Soret 8–17 for Q bands, compared to the respective nonbrominated ). The Φ F values found be 0.013 0.016; phosphorescence (lifetime=0.23 μs) was observed (anaerobic, RT). effect...