A5063190451- Enhanced Oil Recovery Techniques
- Organometallic Complex Synthesis and Catalysis
- Zeolite Catalysis and Synthesis
- Catalysis and Oxidation Reactions
- Ferrocene Chemistry and Applications
- Surface Chemistry and Catalysis
- Catalysis and Hydrodesulfurization Studies
- Catalysis for Biomass Conversion
- Asymmetric Hydrogenation and Catalysis
- Petroleum Processing and Analysis
- Metal complexes synthesis and properties
Satbayev University
2022-2024
Two betaine-based deep eutectic solvents (DESs), betaine/glycerol [1:2] and betaine/ethylene glycol [1:3], were used in separation processes encountered the petroleum industry. Liquid–liquid equilibrium of six ternary systems {thiophene + or [1:3] n-heptane}, {pyridine {toluene n-heptane} measured at 298.15 K under atmospheric pressure. Phase diagrams represented by using COnductor-like Screening MOdel for Real Solvents (COSMO-RS) Non Random Two-Liquids equation (NRTL) models. In terms...
Reaction of (±)-1-(2-furyl) ethanol with an equivalent Ph2PCl in the presence Et3N proceeds dry toluene under argon atmosphere to give 1-(furan-2-yl)ethyl diphenylphosphinite (1) good yield. Mononuclear complexes [dichloro(η6-p-cymene)(1-furan-2-ylethyl diphenylphosphinite)ruthenium(II)] (2), [dichloro(η6-benzene)(1-furan-2-ylethyl (3), [chloro(η4-1,5-cyclooctadiene)(1-furan-2-ylethyl diphenylphosphinite)rhodium(I)] (4) and [dichloro(η5-pentamethylcyclopentadienyl)(1-furan-2-ylethyl...
Abstract Mononuclear transition metal complexes 1‐(furan‐2‐yl)ethyldiphenyl[dichloro(η 6 ‐p‐cymene)ruthenium(II)]phosphinite, ( 2) , ‐benzene) ruthenium(II)] phosphinite (3) 1‐(furan‐2‐yl)ethyldipheny[chloro(η 4 ‐1,5‐cyclooctadiene)rhodium(I)]phosphinite (4) 1‐(furan‐2‐yl)ethyldiphenyl[dichloro (η 5 pentamethylcyclopentadienyl)iridium (III)] (5) were synthesized and characterized by microanalysis, infrared, MS, NMR spectroscopy. The biological activities of the also tested. Compounds 2 best...