A5035499808- Asymmetric Hydrogenation and Catalysis
- Ionic liquids properties and applications
- Metal complexes synthesis and properties
- Organometallic Complex Synthesis and Catalysis
- Catalytic Cross-Coupling Reactions
- Chemical Synthesis and Analysis
- Inorganic and Organometallic Chemistry
- Catalysis for Biomass Conversion
- Analytical Chemistry and Chromatography
- Catalysis and Hydrodesulfurization Studies
- Crystallization and Solubility Studies
- Synthesis and biological activity
- Nanomaterials for catalytic reactions
- Surface Chemistry and Catalysis
- Synthesis and Biological Evaluation
- Cancer therapeutics and mechanisms
- Coal Combustion and Slurry Processing
- X-ray Diffraction in Crystallography
- Polyoxometalates: Synthesis and Applications
- Catalytic Processes in Materials Science
- Petroleum Processing and Analysis
- GABA and Rice Research
- Chemical Reaction Mechanisms
- Ferrocene Chemistry and Applications
- Electrochemical Analysis and Applications
Kazakh-British Technical University
2015-2025
Satbayev University
2018-2022
National Academy of Sciences of the Republic of Kazakhstan
2022
Institute of Chemical Engineering
2018-2019
Dicle University
2014-2015
Korea Institute of Science and Technology
2009
Kyung Hee University
2009
University of Kentucky
2007
Kazan Federal University
1998-2006
The Karazhanbas oil field in the Mangystau region of Kazakhstan contains high-sulfur (1.6-2.2 %). It is known that sulfur negatively affects operational properties petroleum products, causes corrosion pipelines, and adversely environment human body. Therefore, development biodesulfurization technology, taking into account local features, relevant for this field. purpose study to develop from using deep eutectic solvents. Research objectives: isolation sulfate-oxidizing sulfate-reducing...
Imidazolium-based zinc-containing ionic liquids (ILs), [1-R-3-R′-imidazolium]alkylsulfate-ZnCl2 (R and R′ = H or alkyl), were highly effective for the denitrogenation of a model oil containing quinoline, indole, acridine in n-heptane. Fast atom bombardment (FAB)−mass spectra computational study imply that interaction 1-ethyl-3-methylimidazolium ethylsulfate ([EMIm]EtSO4) with ZnCl2 produces Zn-containing ILs, presumably [EMIm]ZnCl2(EtSO4) [EMIm]ZnCl(EtSO4)2 as major species. The EtSO4−...
Abstract In this article the regulations and policy about S‐ N‐containing compounds in fuels, general information methods of desulfurization (DS) denitrogenation (DN) ionic liquids (ILs) assisted DS DN are considered. We presented most effective novel sulfur nitrogen removal using ILs from model real fuels.
Two new phosphinite ligands based on ionic liquids [(Ph 2 PO)C 7 H 14 N Cl]Cl ( 1 ) and [(Cy were synthesized by reaction of 1‐(3‐chloro‐2‐hydoxypropyl)‐3‐methylimidazolium chloride, [C 15 OCl]Cl, with one equivalent chlorodiphenylphosphine or chlorodicyclohexylphosphine, respectively, in anhydrous CH Cl under argon atmosphere. The reactions MCl (cod) (M = Pd, Pt; cod 1,5‐cyclooctadiene) yield complexes cis ‐[M([(Ph Cl]Cl) ] ‐[M(Cy ], respectively. All isolated as analytically pure...
A series of novel neutral mononuclear rhodium(I) complexes the P―NH ligands have been prepared starting from [Rh(cod)Cl] 2 complex. Structural elucidation was carried out by elemental analysis, IR and multinuclear NMR spectroscopic data. The were applied to transfer hydrogenation acetophenone derivatives 1‐phenylethanol in presence 2‐propanol as hydrogen source. Catalytic studies showed that all are also excellent catalyst precursors for aryl alkyl ketones 0.1 m iso‐PrOH solution. In...
Spiroconnected N-alkoxyalkylpiperidine hydantoins were obtained via the Strecker reaction of cyanohydrin with ammonium carbonate. 1,3,8-Triazaspiro[4.5]decane-2,4-diones have shown myelostimulating activity in artificially induced (with cyclophosphamide) myelodepressive syndrome. The compounds significantly accelerated regeneration lymphocyte and granulocyte cell pool bone marrow hematopoiesis.
Four metal complexes, IL‐OPPh 2 ‐Ru‐ p ‐cymene (3) , ‐Ru‐benzene (4) ‐Ir‐Cp* (5) ‐Rh‐COD (6) have been evaluated for in vitro antioxidant activity such as 2,2‐diphenyl‐1‐picrylhydrazyl (DPPH) radical scavenging and reducing power activity. Maximum (71.43%) was obtained with ‐cymene, whereas showed the highest ability. The complexes were also studied their antimicrobial against three Gram‐positive Gram‐negative bacteria. In addition, DNA binding of using calf thymus DNA. Both Ru(II) exhibited...
: In this review article, we present the latest research in field of ionic liquids containing biologically active anions and cations, their potential application agrochemistry agriculture. The article describes examples use as herbicides, fungicides, antimicrobial agents, deterrents plant growth stimulants. It also indicates advantages disadvantages using liquids, such multitasking, toxicity, thermal stability solubility water comparison with commercial chemicals. Readers will find prospects...
Abstract Forming complexes with β-cyclodextrin can enhance stability, dissolution rate, solubility, and bioavailability of an active pharmaceutical ingredient. In this study, the inclusion behavior between (β-CD) diphenhydramine, clonidine, tolperisone in DMSO-d 6 was investigated using NMR spectroscopy. 1 H, 13 C, COSY, HMQC, ROESY data were applied to determine structure complexes, molecular docking analysis engaged identify most favorable host–guest interactions complexes. Complexation...
Reaction of (±)-1-(2-furyl) ethanol with an equivalent Ph2PCl in the presence Et3N proceeds dry toluene under argon atmosphere to give 1-(furan-2-yl)ethyl diphenylphosphinite (1) good yield. Mononuclear complexes [dichloro(η6-p-cymene)(1-furan-2-ylethyl diphenylphosphinite)ruthenium(II)] (2), [dichloro(η6-benzene)(1-furan-2-ylethyl (3), [chloro(η4-1,5-cyclooctadiene)(1-furan-2-ylethyl diphenylphosphinite)rhodium(I)] (4) and [dichloro(η5-pentamethylcyclopentadienyl)(1-furan-2-ylethyl...
A study of myelostimulating activity ionic compounds-trimecaine alkyl iodide derivatives under the cipher BIV (BIV-117, BIV-118, and BIV-119) was conducted on a model doxorubicin pancytopenia in white laboratory rats. It established that compounds BIV-117 BIV-119 had pronounced leukopoiesis-stimulating activity, exceeding methyluracil as comparison drug. Compounds erythropoiesis- thrombocytopoiesis-stimulating at level methyluracil.