Heather D. Whitehead

ORCID: 0000-0003-1817-604X
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About
Contact & Profiles
Research Areas
  • Per- and polyfluoroalkyl substances research
  • Toxic Organic Pollutants Impact
  • Forensic Toxicology and Drug Analysis
  • Opioid Use Disorder Treatment
  • Air Quality and Health Impacts
  • Particle accelerators and beam dynamics
  • Superconducting Materials and Applications
  • Atmospheric chemistry and aerosols
  • Particle Accelerators and Free-Electron Lasers
  • Cannabis and Cannabinoid Research
  • Metabolomics and Mass Spectrometry Studies
  • Biosensors and Analytical Detection
  • Neurotransmitter Receptor Influence on Behavior
  • Effects and risks of endocrine disrupting chemicals
  • Additive Manufacturing and 3D Printing Technologies
  • Molecular Biology Techniques and Applications
  • Advanced Chemical Sensor Technologies
  • Environmental Justice and Health Disparities
  • 3D Printing in Biomedical Research
  • Groundwater and Isotope Geochemistry
  • Fiber-reinforced polymer composites
  • Analytical Methods in Pharmaceuticals
  • Advanced biosensing and bioanalysis techniques
  • Innovative Microfluidic and Catalytic Techniques Innovation
  • HIV, Drug Use, Sexual Risk

Environmental Protection Agency
2025

Oak Ridge Associated Universities
2025

University of Notre Dame
2021-2024

University of Tulsa
2017-2019

Thomas Jefferson National Accelerator Facility
1991-2002

Continuous Electron Beam Accelerator Facility
2002

Per- and polyfluoroalkyl substances (PFAS), a highly persistent potentially toxic class of chemicals, are added to cosmetics increase their durability water resistance. To assess this potential health environmental risk, 231 cosmetic products purchased in the U.S. Canada were screened for total fluorine using particle-induced gamma-ray emission spectroscopy. Of eight categories tested, foundations, mascaras, lip had highest proportion with high ≥0.384 μg F/cm2. Twenty-nine including 20...

10.1021/acs.estlett.1c00240 article EN cc-by-nc-nd Environmental Science & Technology Letters 2021-06-15

A suite of analytical techniques was used to obtain a comprehensive picture per- and polyfluoroalkyl substances (PFAS) in selected Canadian food packaging for fast foods (n = 42). Particle-induced gamma ray emission spectroscopy revealed that 55% the samples contained <3580, 19% 3580–10 800, 26% > 10 800 μg F/m2. The highest total F (1 010 000–1 300 000 F/m2) measured molded "compostable" bowls. Targeted analysis 8 with high 4–15 individual PFAS each sample, 6:2 fluorotelomer methacrylate...

10.1021/acs.estlett.2c00926 article EN cc-by-nc-nd Environmental Science & Technology Letters 2023-03-28

Following the expiration of patents on fused-filament-fabrication (FFF), availability and uses this 3D-printing technology have exploded. Several recent reports describe how conductive composites can be used with FFF printers to generate 3D-printed electrodes (3DEs) for energy storage electrochemical analysis. As printed materials, these very high impedance values because content insulating thermoplastic required printers. To overcome challenge, deposition metals or activation harsh...

10.1021/acs.analchem.9b01331 article EN Analytical Chemistry 2019-03-27

We analyzed 72 children's textile products marketed as stain-resistant from US and Canadian stores, particularly school uniforms, to assess if clothing represents a significant route of exposure per- polyfluoroalkyl substances (PFAS). Products were first screened for total fluorine (total F) using particle-induced γ-ray emission (PIGE) spectroscopy (n = 72), followed by targeted analysis 49 neutral ionic PFAS 57). detected in all both markets, with the most abundant compound being 6:2...

10.1021/acs.est.2c02111 article EN cc-by-nc-nd Environmental Science & Technology 2022-09-21

Numerous per- and polyfluoroalkyl substances (PFASs) occur in consumer food packaging due to intentional unintentional addition, despite increasing concern about their health environmental hazards. We present a substance flow analysis framework assess the flows of PFASs contained plant fiber-based plastic waste stream environment. Each year between 2018 2020, an estimated 9000 (range 1100-25 000) 940 120-2600) tonnes per polymeric were used 2% U.S. Canada, respectively. At least 11...

10.1039/d2em00166g article EN cc-by-nc Environmental Science Processes & Impacts 2022-01-01

Direct fluorination of plastics is performed to impart chemical resistance via exposure polyethylene fluorine gas produce a fluorine-modified surface layer. Leaching experiments were on directly fluorinated container under various conditions and with different matrices, including foodstuffs. The average sum per- polyfluoroalkyl substances (PFAS) concentrations measured from extraction was 63.75 ± 13.2 ng/g plastic. Seven-day leaching containers water, methanol, acetone produced sums PFAS...

10.1021/acs.estlett.3c00083 article EN Environmental Science & Technology Letters 2023-03-06

The opioid epidemic continues to be associated with high numbers of fatalities in the USA and other countries, driven mainly by inclusion potent synthetic opioids street drugs. Drug checking means various technologies is being increasingly implemented as a harm reduction strategy inform users about constituent drugs their samples. We assessed how valued drug services (DCS) would for given ubiquity fentanyl related analogs supply, information they most value from checking, compared expected...

10.1186/s12954-023-00821-x article EN cc-by Harm Reduction Journal 2023-07-07

Purpose If NHS hospitals wish to influence patients choose them and, as the literature review suggests, cleanliness will be a key‐influencing factor in making that choice, it would seem important for understand what factors lead people decide whether hospital is clean or dirty. The research aims identify key are patients' perceptions of and rank these order importance. Design/methodology/approach project utilised mixed methodology collect data. staff who had been recent took part focus...

10.1108/14725960710822268 article EN Journal of Facilities Management 2007-09-08

Per- and polyfluoroalkyl substances (PFAS) distribute bioaccumulate within aquatic organisms food webs. Many PFAS are proteinophilic compounds that display higher concentrations in the blood, liver, kidney of vertebrates than muscle. Several studies have shown birds mammals exhibit maternal offloading to offspring through transport placenta, milk, egg deposition, but no study date has observed fish. We analyzed muscle tissue eggs with targeted LC-MS/MS for sexually mature Lake Michigan...

10.1021/acs.estlett.2c00627 article EN Environmental Science & Technology Letters 2022-10-25

Ultraviolet–visible (UV–vis) spectroscopy represents one of the most popular analytical techniques in chemical research labs. A variety vendors provide instruments that are suited for analysis liquid samples at moderate concentrations. However, to accommodate more specialized experiments, expensive accessories required and often do not fit specific needs experimental scientists. In this work, we present a generalized adapter can be 3D printed used with existing spectrometers enable wide...

10.1021/acsomega.7b01310 article EN cc-by ACS Omega 2017-09-25

A new method for rapidly screening drinking water the presence of per- and polyfluoroalkyl substances (PFAS) has been developed. This involves gravity filtering through an activated carbon felt subsequently analyzing surface with particle induced gamma-ray emission (PIGE) spectroscopy. Using this technique, total fluorine measurements by PIGE produced linear calibration curves adequate to measure below 50 ppt from PFAS in as little 2 L sample. Inorganic fluoride were successfully...

10.1021/acsestwater.1c00215 article EN ACS ES&T Water 2021-11-18

ADVERTISEMENT RETURN TO ISSUEPREVCorrectionNEXTORIGINAL ARTICLEThis notice is a correctionCorrection to "Fluorinated Compounds in North American Cosmetics"Heather D. WhiteheadHeather WhiteheadMore by Heather Whitehead, Marta VenierMarta VenierMore Venierhttps://orcid.org/0000-0002-2089-8992, Yan WuYan WuMore Wuhttps://orcid.org/0000-0001-7876-261X, Emi EastmanEmi EastmanMore Eastman, Shannon UrbanikShannon UrbanikMore Urbanik, Miriam L. DiamondMiriam DiamondMore...

10.1021/acs.estlett.1c00903 article EN cc-by-nc-nd Environmental Science & Technology Letters 2021-12-03

Many "smart" and "fitness" watch bands are advertised to contain fluoroelastomers, a type of synthetic rubber designed be resilient against skin oils sweat. Fluoroelastomers, which considered polymeric form per- polyfluoroalkyl substances (PFAS), have historically involved the use shorter-chain PFAS as surfactants in polymerization process. In this study, 22 were analyzed across numerous brands price points for presence PFAS. Products first screened total fluorine using particle-induced...

10.1021/acs.estlett.4c00907 article EN Environmental Science & Technology Letters 2024-12-18

The use of nucleic acid tests (NAT) for sensitive and rapid detection pathogens relevant to human health has increased due the ubiquity amplification techniques such as polymerase chain reaction. tools amplified (NA) in field clinical settings is limited by need complex instrumentation trained users. To address these limitations we developed a rapid, robust, instrument-free colorimetric method acids using visible region dye, Nile Blue (NB). NB cationic benzophenoxazine dye with well-known...

10.1039/d1ay01598b article EN Analytical Methods 2022-01-01

Abstract Background: The opioid epidemic continues to cause high numbers of fatalities in the US and other countries, driven mainly by inclusion potent synthetic opioids street drugs. Drug checking means various technologies is being increasingly implemented as a harm reduction strategy inform users about constituent drugs their samples. We assessed how valued drug services (DCS) would be for given ubiquity fentanyl related analogs supply, information they most value from checking, compared...

10.21203/rs.3.rs-2273560/v1 preprint EN cc-by Research Square (Research Square) 2022-11-18

In order to support the planned CEBAF upgrade at Jefferson Lab a new cryomodule has been designed. A key component of is upgraded RF input waveguide, which may couple as much 10 kW power superconducting radio frequency (SRF) cavities contained in bath superfluid helium. The coupler consists straight copper plated stainless steel waveguide thermal transition between 2 K and 300 one ceramic window warm end waveguide. interior shares common vacuum with cavity. Initial testing conducted...

10.1109/pac.2001.986611 article EN PACS2001. Proceedings of the 2001 Particle Accelerator Conference (Cat. No.01CH37268) 2002-11-14
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