A5030237269- Enzyme Catalysis and Immobilization
- Hydrogen Storage and Materials
- Fusion materials and technologies
- Nuclear Materials and Properties
- Chemical Synthesis and Characterization
- Cyclopropane Reaction Mechanisms
- Carbohydrate Chemistry and Synthesis
- Catalytic Processes in Materials Science
- Ammonia Synthesis and Nitrogen Reduction
- Catalytic C–H Functionalization Methods
- Microbial Metabolic Engineering and Bioproduction
- Radioactive element chemistry and processing
- Analytical Chemistry and Chromatography
- Metal-Organic Frameworks: Synthesis and Applications
- Pharmacogenetics and Drug Metabolism
- Copper-based nanomaterials and applications
- Nanomaterials for catalytic reactions
- Sulfur-Based Synthesis Techniques
- Asymmetric Synthesis and Catalysis
- Catalysis and Oxidation Reactions
- Nuclear Physics and Applications
- Muon and positron interactions and applications
- Superconducting Materials and Applications
- Boron and Carbon Nanomaterials Research
- Catalytic Alkyne Reactions
China Academy of Engineering Physics
2017-2025
Science and Technology on Surface Physics and Chemistry Laboratory
2015
Mianyang Normal University
2015
Sichuan University
2008-2014
Okayama University
2012
It was first observed that PPL, lipase from porcine pancreas, and several other lipases have a promiscuous ability to catalyse asymmetric aldol reactions between acetones aldehydes in the presence of water.
A novel lipase-catalysed direct Mannich reaction has been developed under aqueous conditions in a “one-pot” strategy. Interestingly, these promiscuous reactions can be greatly promoted by water and generally require aromatic aldehydes.
An efficient method for the synthesis of sulfones via nitrogen loss sulfonyl hydrazones is described. The reaction was performed in presence simple copper salt and base by utilization hydrazones, which were easily prepared from carbonyl compounds. A wide variety aryl alkyl obtained moderate to good yields.
Realizing ideal deuterium separation from isotopic mixtures remains a daunting challenge because of their almost identical sizes, shapes, and physicochemical properties. Using the quantum sieving effect in porous materials with suitable pore size open metal sites (OMSs) enables efficient hydrogen isotope separation. Herein, synthetic HKUST-1-derived microporous mixed-valence Cu(I)Cu(II)-BTC (BTC = benzene-1,3,5-tricarboxylate), featuring unique network distinct Cu(I) Cu(II) coordination...
Deuterium/Tritium (D/T) handling in defined proportions are pivotal to maintain steady-state operation for fusion reactors. However, the hydrogen isotope effect metal-hydrogen systems always disturbs precise D/T ratio control. Here, we reveal dominance of kinetic during desorption. To reconcile thermodynamic stability and effect, demonstrate a quantitative indicator T
Acrylic resin immobilized Candida antarctica lipase B (CAL-B) is able to catalyse decarboxylative aldol reaction and Knoevenagel with good excellent yields.
Tritium, a radioactive isotope of hydrogen, is exceptionally rare and valuable. The safe storage, controlled release efficient capture tritium are subject to focused research in the International Thermonuclear Experimental Reactor. However, application an tritium-getter material remains critical challenge. Zr2Fe alloys exhibit strong ability absorb low-concentration hydrogen isotopes, but their practicability suffers from disproportionation reaction. Yet, essential de-/hydrogenation...
The preparation of <italic>N</italic>-substituted triazole–polyethylene glycol-stabilized metal nanoparticles and their high catalytic activities for 4-nitrophenol reduction.
The launch of International Thermonuclear Experimental Reactor project paves the way to wide adoption DT fusion energy as future source. Efficient fuel cycle minimize strategic tritium inventory proves crucial for commercially viable technologies. ZrCo alloy is considered a promising candidate fast isotope handling. However, cycling degradation caused by hydrogen‐induced disproportionation results in severe trapping, thus impeding its practical application. Herein, an isostructural...
Abstract Catalytic oxidation plays a crucial role in the efficient treatment of hydrogen isotopes, with key technical challenge being development high‐performance catalysts to enhance isotope removal efficiency, thereby reducing environmental pollution and ensuring public radiation safety. Herein, strategic control platinum nanoclusters confined within silicalite‐1 zeolites is reported high efficiency for isotopes under low‐temperature conditions first time. Incorporating single lanthanum...