A5101788579- Electrocatalysts for Energy Conversion
- Nanomaterials for catalytic reactions
- Catalytic Processes in Materials Science
- Catalysis for Biomass Conversion
- Nicotinic Acetylcholine Receptors Study
- Advanced battery technologies research
- Catalysis and Hydrodesulfurization Studies
- Advanced Photocatalysis Techniques
- Receptor Mechanisms and Signaling
- Supercapacitor Materials and Fabrication
- Ion channel regulation and function
- Fuel Cells and Related Materials
- Metal-Organic Frameworks: Synthesis and Applications
- Graphene research and applications
- Copper-based nanomaterials and applications
- Catalysts for Methane Reforming
- Chemical Synthesis and Reactions
- Advancements in Battery Materials
- Electrochemical Analysis and Applications
- Covalent Organic Framework Applications
- Electrochemical sensors and biosensors
- Catalytic Cross-Coupling Reactions
- Catalytic C–H Functionalization Methods
- Oral and Maxillofacial Pathology
- Advanced biosensing and bioanalysis techniques
Hebei University
2017-2025
National Center for Women and Children’s Health, China CDC
2023-2024
Suzhou Research Institute
2023
Stanford University
2022
Baoding University
2017-2020
Zhejiang Energy Group (China)
2019
Shanghai University of Medicine and Health Sciences
2017
Jiading District Central Hospital
2017
Zhejiang University of Technology
2016
Beijing National Laboratory for Molecular Sciences
2011-2016
Thanks to nitrogen introduced into the layered carbon framework of graphite, chemical reactivity atoms was increased. N-doped graphitic catalysts generate reactive oxygen species and display excellent activity for hydrocarbon activation even at room temperature. As a service our authors readers, this journal provides supporting information supplied by authors. Such materials are peer reviewed may be re-organized online delivery, but not copy-edited or typeset. Technical support issues...
Reduced graphene oxide was used as a catalyst for reduction of nitrobenzene at room temperature. High catalytic activity and stability were exhibited in circular experiments. The procedure situ monitored by NMR N-phenylhydroxylamine proved to be the intermediate this reaction.
We report an efficient, highly selective, and low temperature graphene-catalyzed reaction process for one-step oxidation of benzene to phenol with hydrogen peroxide as the oxidant. The chemically converted graphene (CCG) from small graphite was used catalyst. conversion reaches 18%, being sole product. catalyst reusable very stable. By XPS, C K-edge X-ray absorption spectra, benzene-TPD, kinetic measurements, it concluded that moderate H2O2 activation rate, good adsorption ability, balanced...
Because of limited framework stability tolerance, de novo synthesis sulfonated covalent organic frameworks (COFs) remains challenging and unexplored. Herein, a two-dimensional crystalline COF, termed TFP-DABA, was synthesized directly from 1,3,5-triformylphloroglucinol 2,5-diaminobenzenesulfonic acid through previously reported Schiff base condensation reaction, followed by irreversible enol-to-keto tautomerization, which strengthened its structural stability. TFP-DABA is highly efficient...
Single-atom catalysts (SACs) have attracted much attention due to their outstanding catalytic performance in heterogeneous catalysis. Here, we report a template sacrificial method fabricate an atomically dispersed Co catalyst; three kinds of silica templates with different microstructures (MCM-41, SBA-15, and FDU-12) were employed the effect pore structure on dispersity was investigated. The fabricated presented dispersities, leading distinguishing performance. optimized Co1@NC-(SBA)...
Monodisperse bimetallic Pd-Cu nanoparticles with controllable size and composition were synthesized by a one-step multiphase ethylene glycol (EG) method. Adjusting the stoichiometric ratio of Pd Cu precursors afforded different compositions, such as Pd(85)-Cu(15), Pd(56)-Cu(44), Pd(39)-Cu(61). The separated from solution mixture extraction non-polar solvents, n-hexane. narrow size-distribution obtained without need for size-selection process. Capping ligands that bound to surface particles...
The direct synthesis of metal–organic frameworks (MOFs) with strong Brønsted acidity is challenging because the functional groups exhibiting (e.g., sulfonic acid groups) often jeopardize framework integrity. Herein, we report two hierarchically porous MOFs named NUS-6 composed either zirconium (Zr) or hafnium (Hf) clusters high stability and acidity. Via modulated hydrothermal (MHT) synthesis, these can be easily synthesized at a low temperature (80 °C) throughput. They exhibit BET surface...
Abstract A heterogeneous, inexpensive, and environmentally friendly graphene oxide catalytic system for the C−H bond arylation of benzene enables formation biaryl compounds in presence aryl iodides. The oxygen functional groups these sheets addition KO t Bu are essential observed activity. Reactions with various model DFT calculations confirmed that negatively charged atoms promote overall transformation by stabilizing activating K + ions, which turns facilitates activation C−I bond....
Metallic nanocrystals (NCs) with well-defined sizes and shapes represent a new family of model systems for establishing structure-function relationships in heterogeneous catalysis. Here this study, we show that catalyst poisoning can be utilized as an efficient strategy shape composition control, well way to tune the catalytic activity catalysts. Lead species, well-known poison noble-metal catalysts, was investigated growth Pd NCs. We discovered Pb atoms incorporated into lattice NCs form...
Chitin treatment using different methods, including ball mill grinding, steam explosion, alkaline treatment, phosphoric acid, and ionic liquid (IL) dissolution/reprecipitation have been systematically investigated. The chitin structures were thoroughly investigated by a series of analytical techniques, the reactivity after each was evaluated in dehydration liquefaction reactions. parallel studies enable direct comparisons these methods help to establish structure-activity correlations. Ball...
Through the adsorption/intercalation of cobalt phthalocyanine (CoPc) onto/into graphene oxide (GO) layers, CoPc–GO nanocomposite was prepared via a simple solvent evaporation method driven by electronic interaction between CoPc and GO. The GO has been studied in detail various methods. result suggests that does not follow donor–acceptor mode, but, instead, it is complicated two-way process including transfer electron from graphitic domain to adsorbed/intercalated CoPc, feedback Co ions...
Nitrogen-doped graphene treated with ammonia under different temperatures was used as the catalysts for epoxidation of trans-stilbene and styrene at 373 K. NG-800 (N-doped 800 °C 8 h) performed best gave highest recyclable catalytic activity trans-stilbene, 95.8% conversion 94.4% selectivity to epoxide. The center has been identified reaction mechanism elucidated by DFT calculation.
The production of a series mesoporous, nitrogen-containing (N-containing) carbon materials directly from pure chitin by means carbonization at different temperatures under template-free conditions is reported. Thermogravimetric analysis combined with infrared spectroscopy was applied to follow the temperature-dependent chemical events during process, thereby shedding light on automated pore formation mechanism. physicochemical properties N-containing have been extensively investigated, which...
Herein we report an efficient and recyclable catalytic system for tandem CO2 capture N-formylation to value-added chemicals. is apt be captured by morpholine solution, while a highly heterogeneous catalyst, isolated iridium atoms supported over nanadiamond/graphene, discovered reactive the formylation of morpholine, leading formation N-formylmorpholine with excellent productivity (with turnover number 5 120 000 in single batch reaction) selectivity (>99 %). In addition, under atmospheric...
The increasing accumulation of plastic waste in the environment poses a serious threat to ecosystem and health sector, urging us develop sustainable strategies tackle this issue. Converting into platform chemicals using energy primary resources can mitigate environmental pollution reduce CO2 emissions. In study, polyolefins were transformed syngas through wet reforming process over nickel-supported oxygen vacancy-rich titanium dioxide (Ni/TiO2-x) catalyst with water as reactant under light...
The effectiveness of sulfated mesoporous niobium oxide (MNO-S) as a catalyst for the production 5-hydroxymethylfurfural (5-HMF) from sugar was studied and is reported herein. structures synthesized MNO-S catalysts commercial Nb2O5 were characterized by scanning electron microscopy (SEM), X-ray photoelectron spectroscopy (XPS), diffraction (XRD), Brunauer–Emmett–Teller (BET) analysis, Fourier transform infrared (FTIR) spectroscopy. Compared with Nb2O5, MNO-S-based showed much higher surface...