A5114376138- Organometallic Compounds Synthesis and Characterization
- Crystal structures of chemical compounds
- Metal complexes synthesis and properties
- Crystal Structures and Properties
- Crystallography and molecular interactions
- Chemical Thermodynamics and Molecular Structure
- Advanced NMR Techniques and Applications
- Magnetism in coordination complexes
- Crystallization and Solubility Studies
- X-ray Diffraction in Crystallography
- Inorganic Chemistry and Materials
- Organometallic Complex Synthesis and Catalysis
- Solid-state spectroscopy and crystallography
- Synthesis and Reactivity of Sulfur-Containing Compounds
- Thermal and Kinetic Analysis
- Metal Extraction and Bioleaching
- Lanthanide and Transition Metal Complexes
- Inorganic and Organometallic Chemistry
- Analytical Chemistry and Chromatography
- Synthesis and Characterization of Heterocyclic Compounds
- Chemical Synthesis and Characterization
- Fire effects on ecosystems
- Minerals Flotation and Separation Techniques
- NMR spectroscopy and applications
- Analytical Chemistry and Sensors
Institute of Geology and Nature Management, Far Eastern Branch of the Russian Academy of Sciences
2015-2024
All-Russian Research Institute for Optical and Physical Measurements
2019-2024
N.D. Zelinsky Institute of Organic Chemistry
1998-2023
Pedagogical University
2023
Practical Action
2023
Moscow State Pedagogical University
2023
NewYork–Presbyterian Hospital
2022
St Petersburg University
2022
NewYork–Presbyterian Brooklyn Methodist Hospital
2018
Far Eastern Branch of the Russian Academy of Sciences
1999-2015
Adsorption of diphenyl-, phenyl- and orthophosphate on γ-Al2O3 was studied with a combination macroscopic 31P solid-state NMR measurements. Results for adsorption suggest that diphenyl phosphate bound largely as an outer-sphere complex, while phenyl held inner-sphere surface complexes complex present only at higher pH values. Both the edge cross polarization magic angle spinning spectra were consistent interaction between being driven by electrostatic forces. more evidence outer-...
The article gives an answer to the question – who built mud graves in Bosporus? In Russian historiography, there was idea according which barbarians were buried raw graves, them for their dead. Archaeological realities contradict this traditional view. To solve a debatable and extremely important issue Bosporus archeology, examples of mud-brick house-building use burial practice Greek world Mediterranean are given, place time origin tradition building mudbrick structures determined, ways...
Different potassium salts and zinc(II) nickel(II) O,O'-dialkyldithiophosphate complexes were studied by solid-state 31P CP/MAS static NMR ab initio quantum mechanical calculations. Spectra obtained at different spinning frequencies, the intensities of sidebands used to estimate chemical shift anisotropy parameters. Useful correlations between shapes tensor type ligand found: terminal ligands have negative values skew κ, while bridging ionic positive for this parameter. The experimental...
The interaction of acetylene with surface sites SiO2, TiO2, CaO, MgO, Al2O3, Ga2O3, La2O3, and ZrO2 oxides was studied. Two main types adsorption complexes were found: first, formed by weak reversible at O2− basic OH groups and, second, stable the dissociative Meδ+–Oδ− pairs formation acetylide species. position C–H band in weakly adsorbed CC bands strongly can be used for sensitive characterization oxide basicity. measurements performed elevated pressures (10–20 Torr) give information on...
Nitric oxide, •NO, is one of the most important molecules in biochemistry living organisms. By contrast, nitroxyl, NO-, one-electron reduced analog •NO which exists at physiological conditions its protonated form, HNO, has been relatively overlooked. Recent data show that HNO might be produced endogenously and display unique biological effects. However, there a lack specific quantitative methods detection endogenous production. Here we present new method for discriminative by nitronyl...