A5008209750- Photopolymerization techniques and applications
- Advanced Polymer Synthesis and Characterization
- Radical Photochemical Reactions
- Photochromic and Fluorescence Chemistry
- Oxidative Organic Chemistry Reactions
- Carbon dioxide utilization in catalysis
- Organometallic Complex Synthesis and Catalysis
- Synthetic Organic Chemistry Methods
Universidade Estadual Paulista (Unesp)
2021-2025
Faculdade de Tecnologia e Ciências
2025
Université de Haute-Alsace
2025
Centre National de la Recherche Scientifique
2025
Copper(I) complexes have attracted considerable attention as efficient redox photocatalysts (PCs) in photopolymerization. In this study, two copper(I) bearing a pyridine-benzothiazole ligand were thoroughly investigated for the free radical photopolymerization of ethoxylated trimethylolpropane triacrylate under violet and green light irradiation. A three-component system comprising copper complex, di-tert-butyl-diphenyl iodonium hexafluorophosphate, ethyl dimethylaminobenzoate additives was...
The evaluation of NiII complexes bearing bidentate N-heterocyclic carbene (NHC) ligands has shown great potential as catalysts in various reactions. However, their luminescence properties and photocatalytic applications remain underexplored. Two...
The role of manganese in photo‐induced organometallic‐mediated radical polymerization (photo‐OMRP) under LED (light‐emitting diode) irradiation has not been previously explored. In this study, four (II) complexes, namely [Mn(6‐ tert ‐butyl‐N,N′‐propanebis [salicylimine])] ( Mn‐Bu ), [Mn(6,3‐di‐ 2 [Mn(6‐ethoxy‐N,N′‐propanebis Mn‐Ethoxy and [Mn(6,3‐di‐ethoxy ‐ N,N′‐propanebis were synthesized using both symmetrical non‐symmetrical tetradentate N O Schiff base ligands. ligands characterized by...
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Photoinduced atom transfer radical polymerization (photo-ATRP) has emerged as a prominent technique in contemporary polymer chemistry, offering potent means to create precisely structured materials. Well-defined catalysts are essential for controlling the growth of polymers with reproducible results; however, most photo-ATRP catalytic systems involve mixing metal salt ligand. Herein we present well-defined iron(III) based catalyst bearing bidentate NHC ligand,...