A5030613063- Synthesis and Reactivity of Sulfur-Containing Compounds
- Synthesis and Characterization of Heterocyclic Compounds
- Synthesis of heterocyclic compounds
- Chemical Synthesis and Analysis
- Synthesis and biological activity
- Biochemical effects in animals
- Structural and Chemical Analysis of Organic and Inorganic Compounds
- Sulfur-Based Synthesis Techniques
- Chemical Reaction Mechanisms
- Asymmetric Synthesis and Catalysis
- Synthesis of Organic Compounds
- Chemical Synthesis and Reactions
- Oxidative Organic Chemistry Reactions
- Inorganic and Organometallic Chemistry
- Supramolecular Self-Assembly in Materials
- Synthesis and Reactions of Organic Compounds
- Synthesis of β-Lactam Compounds
- Phenothiazines and Benzothiazines Synthesis and Activities
- Radical Photochemical Reactions
- Electrochemical sensors and biosensors
- Receptor Mechanisms and Signaling
- Axial and Atropisomeric Chirality Synthesis
- Biochemical Acid Research Studies
- Agricultural Productivity and Crop Improvement
- Catalysis and Oxidation Reactions
A.E. Arbuzov Institute of Organic and Physical Chemistry
2021-2024
Kazan State Technological University
2024
Ural Branch of the Russian Academy of Sciences
2023
Institute of Organic Synthesis
2023
National Research University Higher School of Economics
2022
Institute of Pharmacology Russian Academy of Medical Sciences
1969-2020
Kazan Federal University
2020
Samara State Technical University
2016
Academy of Medical Sciences
1972-2013
Russian Academy of Sciences
2013
A series of novel 4-(het)arylimidazoldin-2-ones were obtained by the acid-catalyzed reaction (2,2-diethoxyethyl)ureas with aromatic and heterocyclic C-nucleophiles. The proposed approach to substituted imidazolidinones benefits from excellent regioselectivity, readily available starting materials a simple procedure. regioselectivity was rationalized quantum chemistry calculations control experiments. anti-cancer activity compounds tested in vitro.
In contrast to hypervalent iodine compounds, the chemistry of their sulfur analogues has been considerably less explored. Herein, we report direct C–H bond thiolation electron-rich heterocycles, arenes, and 1,3-dicarbonyls by dichlorosulfuranes under mild conditions. Mechanistic studies density functional theory calculations suggest radical chain mechanism disclosed transformation. The key success is attributed a strikingly low S–Cl dissociation energy, which enables generation species upon...
The method for the synthesis of complex alkaloid-like aza-heterocycles has been developed through Povarov reaction in situ generated 2-oxoimidazolium cations. lead to formation 2 C-N, C-C bonds and three stereocentres, features excellent regio- diastereoselectivity. Based on controlled experiments quantum chemistry data, mechanism cyclization was proposed diastereoselectivity origins were rationalized. Additionally, a straightforward hardly accessible 4,4'-bi(imidazol-2-one) derivatives...
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The article discusses the Russian practice of promoting food delivery services during COVID-19 pandemic. study is based on analysis documents with elements statistical and comparative analysis. authors attempted to collect systematize data use communication tools by business enterprises lockdown period. presents from various studies retail market ready-made in Russia. As a result this study, come following conclusions: (1) websites applications have become main platforms interacting...