R. Gopalan

ORCID: 0000-0003-2871-8682
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About
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Research Areas
  • Magnetic Properties of Alloys
  • Magnetic properties of thin films
  • Crystallization and Solubility Studies
  • X-ray Diffraction in Crystallography
  • Magnetic and transport properties of perovskites and related materials
  • Magnetic Properties and Applications
  • Advancements in Battery Materials
  • Crystallography and molecular interactions
  • Advanced Battery Materials and Technologies
  • Metallic Glasses and Amorphous Alloys
  • Shape Memory Alloy Transformations
  • Advanced Thermoelectric Materials and Devices
  • Rare-earth and actinide compounds
  • Advanced Battery Technologies Research
  • Thermal Expansion and Ionic Conductivity
  • Supercapacitor Materials and Fabrication
  • Advanced Condensed Matter Physics
  • Physics of Superconductivity and Magnetism
  • Multiferroics and related materials
  • Magnetic Properties and Synthesis of Ferrites
  • Thermal properties of materials
  • Heusler alloys: electronic and magnetic properties
  • Hydrogen Storage and Materials
  • Metal complexes synthesis and properties
  • Nonlinear Optical Materials Research

International Advanced Research Centre for Powder Metallurgy and New Materials
2016-2025

Vel Tech Rangarajan Dr. Sagunthala R&D Institute of Science and Technology
2025

Indian Institute of Technology Madras
2016-2024

Institute of Magnetism
2019

Defence Metallurgical Research Laboratory
1999-2015

National Institute for Materials Science
2004-2014

Unilever (India)
2011-2013

National Institute of Technology Karnataka
2011

Jawaharlal Nehru Centre for Advanced Scientific Research
1996-2005

University of Madras
2003

10.1557/jmr.1997.0057 article EN Journal of materials research/Pratt's guide to venture capital sources 1997-02-01

Here, we report facile fabrication of Fe3O4-reduced graphene oxide (Fe3O4-RGO) composite by a novel approach, i.e., microwave assisted combustion synthesis porous Fe3O4 particles followed decoration RGO. The characterization studies Fe3O4-RGO demonstrate formation face centered cubic hexagonal crystalline Fe3O4, and homogeneous grafting nitrogen adsorption-desorption isotherm shows presence structure with surface area pore volume 81.67 m(2) g(-1), 0.106 cm(3) g(-1) respectively. Raman...

10.1039/c3cp54778g article EN Physical Chemistry Chemical Physics 2013-12-19

Sodium ion battery technology is gradually advancing and can be viewed as a viable alternative to lithium batteries in niche applications. One of the promising positive electrode candidates P2 type layered sodium transition metal oxide, which offers attractive conductivity. However, reversible capacity phases limited by inability directly synthesize stoichiometric compounds with ratio equal 1. To alleviate this issue, we report herein situ synthesis P2-NaxMO2 (x ≤ 0.7, M = ions)-Na2CO3...

10.1021/acs.chemmater.7b01542 article EN Chemistry of Materials 2017-07-03

Abstract Orthorhombic α‐MoO 3 is a potential anode material for lithium‐ion batteries due to its high theoretical capacity of 1100 mAh g −1 and excellent structural stability. However, intrinsic poor electronic conductivity volume expansion during the charge–discharge process impede it from achieving practical capacity. A novel composite nanobelts single‐walled carbon nanohorns (SWCNHs) synthesized by facile microwave hydrothermal technique demonstrated as high‐performance batteries. The...

10.1002/aenm.202001627 article EN Advanced Energy Materials 2020-07-30

Due to natural abundance, low cost, and compatibility with sustainable green technology, Mg3Sb2-based Zintl compounds are comprehensively explored as potential thermoelectric materials for near-room temperature applications. The effective use of these in devices requires both p n-type Mg3Sb2 having comparable efficiency. However, p-type has inferior efficiency compared its counterpart due electrical conductivity (∼103Sm-1). Here, we show that codoping monovalent atoms (Li-Ag, Na-Ag) at the...

10.1021/acsami.3c02151 article EN ACS Applied Materials & Interfaces 2023-04-17

The [Sm(Co,Cu)5∕Fe]6 multilayer film that was fabricated by annealing Cr[a-(Sm-Co)(9nm)∕Cu(xnm)∕Fe(5nm)∕Cu(xnm)]6∕Cr(x=0–0.75) has shown good in-plane texture and a high maximum energy product (BH)max of 32 MGOe with coercivity 7.24 kOe. addition the Cu layer between a-d-SM-Co6 Fe layers optimum thickness increases significantly, thereby improving product. single-phase behavior irreversible rotation in demagnetization process indicates strong exchange coupling Sm(Co,Cu)5 layers.

10.1063/1.1889238 article EN Applied Physics Letters 2005-03-18

Four new iron(III) complexes of the bis(phenolate) ligands N,N-dimethyl-N',N'-bis(2-hydroxy-3,5-dimethylbenzyl)ethylenediamine [H2(L1)], N,N-dimethyl-N',N'-bis(2-hydroxy-4-nitrobenzyl)ethylenediamine [H2(L2)], N,N'-dimethyl-N,N'-bis(2-hydroxy-3,5-dimethylbenzyl)ethylenediamine [H2(L3)], and N,N'-dimethyl-N,N'-bis(2-hydroxy-4-nitrobenzyl)ethylenediamine [H2(L4)] have been isolated studied as structural functional models for intradiol-cleaving catechol 1,2-dioxygenases (CTD). The [Fe(L1)Cl]...

10.1021/ic020569w article EN Inorganic Chemistry 2003-11-13

In the ongoing pursuit toward a high-performance lithium-ion battery (LIB), an understanding of solid electrolyte interface (SEI) layer is important to enhance performance and lifetime LIB. Despite many years dedicated research on study SEI layer, well-known mosaic model has not yet been fully established experimentally. Herein, we report comprehensive experimental evidence formation growth process structure by using specially designed cell. Sequential in situ ex characterizations provide...

10.1021/acs.jpcc.8b09210 article EN The Journal of Physical Chemistry C 2018-11-27

The charge ordering in , which occurs on cooling the ferromagnetic metallic ground state, is readily destroyed application of a magnetic field 6 T. For for state ordered, other hand, fields have no effect ordering. In order to understand such marked difference charge-ordering behaviour manganates, we investigated structure as well electrical and properties compositions (Ln = Nd, Sm, Gd Dy) wherein varies over range 1.17-1.13 Å. lattice distortion index, D, transition temperature, manganates...

10.1088/0953-8984/10/38/010 article EN Journal of Physics Condensed Matter 1998-09-28

Nickel‐rich LiNi0.8Co0.15Al0.05O2 (NCA) is a promising alternative to LiNi1‐x‐yCoxMnyO2 (NMC) with x + y ≤ 0.2, high specific energy and power density makeing it ideal for long‐range electric vehicles. However, the formation of surface residual impurities extreme sensitivity moisture detrimental large scale synthesis electrochemical performance NCA. In this paper, Li2CO3 elemental distribution lithium ions within secondary particle investigated by synthesizing different Li transition metal...

10.1002/batt.202400752 article EN Batteries & Supercaps 2025-02-06

Abstract In this study, discarded neem ( Azadirachta indica ) mature-wood twigs are charred at 473 K to yield charcoal ash. Material characterizations reveal that the ash is composed of various minerals and organic functionalities has a flaky, macroporous surface consisting protrusions. Elementary property analyses performed, twig compared characteristically with similar wood-derived, organic, bottom ashes. The inherently gray color (∼50 % absorbance ∼50 reflectance) changes reddish when...

10.1515/ijmr-2024-0171 article EN International Journal of Materials Research (formerly Zeitschrift fuer Metallkunde) 2025-04-01

Liquid crystal plates called q-plates are routinely used to generate vector vortex beams. These have a fixed retardance and topological charge designed for specific wavelengths. Inspired by Pancharatnam’s work on achromatic wave-retarders, we realized wavelength-tunable three q-plate device that is shown broad range of wavelengths other than the one. An effective π demonstrated at different realize complete conversion spin angular momentum Orbital Angular Momentum. The present technique can...

10.1364/opticaopen.28765007.v1 preprint EN 2025-04-10

Liquid crystal plates called q-plates are routinely used to generate vector vortex beams. These have a fixed retardance and topological charge designed for specific wavelengths. Inspired by Pancharatnam’s work on achromatic wave-retarders, we realized wavelength-tunable three q-plate device that is shown broad range of wavelengths other than the one. An effective π demonstrated at different realize complete conversion spin angular momentum Orbital Angular Momentum. The present technique can...

10.1364/opticaopen.28765007 preprint EN 2025-04-10

The thermoelectric properties of nanostructured Ni doped Dy filled CoSb<sub>3</sub>skutterudites (Dy<sub>0.4</sub>Co<sub>4−x</sub>Ni<sub>x</sub>Sb<sub>12</sub>(<italic>x</italic>= 0, 0.4, and 0.8)) have been reported.

10.1039/c8se00395e article EN Sustainable Energy & Fuels 2018-01-01

Mg<sub>3</sub>Sb<sub>2</sub> based Zintl compounds are promising thermoelectric materials due to the abundance of magnesium and antimony in nature.

10.1039/d1se00656h article EN Sustainable Energy & Fuels 2021-01-01
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