A5075007882- Glycosylation and Glycoproteins Research
- Carbohydrate Chemistry and Synthesis
- Enzyme Production and Characterization
- Genomics and Phylogenetic Studies
Leiden University
2020
Abstract The assembly of complex bacterial glycans presenting rare structural motifs and cis ‐glycosidic linkages is significantly obstructed by the lack knowledge reactivity constituting building blocks stereoselectivity reactions in which they partake. We here report a strategy to map carbohydrate apply it understand sugar, caryophyllose, C12‐monosaccharide, containing characteristic tetrasubstituted stereocenter. mapped reactivity–stereoselectivity relationships for caryophyllose donor...
Abstract The assembly of complex bacterial glycans presenting rare structural motifs and cis ‐glycosidic linkages is significantly obstructed by the lack knowledge reactivity constituting building blocks stereoselectivity reactions in which they partake. We here report a strategy to map carbohydrate apply it understand sugar, caryophyllose, C12‐monosaccharide, containing characteristic tetrasubstituted stereocenter. mapped reactivity–stereoselectivity relationships for caryophyllose donor...