Yaocai Bai

ORCID: 0000-0003-3700-2520
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About
Contact & Profiles
Research Areas
  • Advancements in Battery Materials
  • Extraction and Separation Processes
  • Recycling and Waste Management Techniques
  • Advanced Battery Materials and Technologies
  • Gold and Silver Nanoparticles Synthesis and Applications
  • Electrocatalysts for Energy Conversion
  • Advanced battery technologies research
  • Advanced Battery Technologies Research
  • Supercapacitor Materials and Fabrication
  • Plasmonic and Surface Plasmon Research
  • Nanocluster Synthesis and Applications
  • Copper-based nanomaterials and applications
  • Fuel Cells and Related Materials
  • Quantum Dots Synthesis And Properties
  • Nanomaterials for catalytic reactions
  • Advanced Photocatalysis Techniques
  • Ionic liquids properties and applications
  • Electrochemical Analysis and Applications
  • CO2 Reduction Techniques and Catalysts
  • Concrete and Cement Materials Research
  • Catalytic Processes in Materials Science
  • Pickering emulsions and particle stabilization
  • Transition Metal Oxide Nanomaterials
  • Optical Coatings and Gratings
  • Metamaterials and Metasurfaces Applications

Shihezi University
2025

Xinjiang Production and Construction Corps
2025

Oak Ridge National Laboratory
2020-2024

National Transportation Research Center
2020-2024

University of California, Riverside
2015-2023

Guilin University of Electronic Technology
2023

University of California System
2015-2020

Riverside
2017-2020

Materials Science & Engineering
2015-2017

Institute of Catalysis and Petrochemistry
2017

Colloidal plasmonic metal nanoparticles have enabled surface-enhanced Raman scattering (SERS) for a variety of analytical applications. While great efforts been made to create hotspots amplifying signals, it remains challenge ensure their high density and accessibility improved sensitivity the analysis. Here we report dealloying process fabrication porous Au-Ag alloy containing abundant inherent hotspots, which were encased in ultrathin hollow silica shells so that need conventional organic...

10.1021/acs.nanolett.6b00868 article EN Nano Letters 2016-05-18

Oxygen evolution reaction (OER) plays a key role in energy conversion and storage processes such as water splitting carbon dioxide reduction. However, the sluggish kinetics caused by insufficient active surface limited charge transfer hinder OER's wide applications. In this work, novel self‐templating strategy for fabrication of composite CoO–MoO 2 nanocages with enhanced OER performance is proposed. By designing nanocage structure incorporating conductive MoO to promote both mass transfer,...

10.1002/adfm.201702324 article EN Advanced Functional Materials 2017-07-20

Abstract Ionic liquids (ILs) are a family of nonconventional molten salts that offer many advantages, such as negligible vapor pressures, flammability, wide liquidus ranges, good thermal stability, and much synthesis flexibility. The unique solvation environment these ILs provides new reaction or flux media for controlling formation solid‐state materials with minimum perturbation morphologies. A successful lithiation via ionothermal using cost‐effective Li halide source recyclable solvents...

10.1002/aenm.202001204 article EN Advanced Energy Materials 2020-06-24

Manipulating the selectivity-determining step in post-C–C coupling is crucial for enhancing C2 product specificity during electrocatalytic CO2 reduction, complementing efforts to boost rate-determining kinetics. Here we highlight role of single-site noble metal dopants on Cu surfaces influencing C–O bond dissociation an oxygen-bound intermediate, steering toward ethylene versus ethanol. Integrating theoretical and experimental analyses, demonstrate that oxygen binding strength surface...

10.1038/s44286-023-00018-w article EN other-oa Nature Chemical Engineering 2024-02-08

Abstract Separation of electrode materials from their current collectors is an enabling step toward recovering critical spent lithium‐ion batteries. In the presented research, a highly efficient, cost‐effective, and environmentally sustainable separation process was developed for that purpose. Ethylene glycol, vital commodity chemical as antifreeze polymer precursor, used to delaminate at low temperatures in seconds without altering crystalline structure morphology active materials. The...

10.1002/cssc.202001479 article EN publisher-specific-oa ChemSusChem 2020-07-31

Effective separation of cathode materials and current collectors is one the most enabling steps, yet a very challenging step, in recycling electrode scraps spent Li-ion cells. Here, green solvent, triethyl phosphate, was used to recover invaluable cobalt-containing cathodes, such as NMC622, by dissolving polymeric binder poly(vinylidene fluoride). Electrochemically active were separated from collected at manufacturing step electrodes through solvent-based method without jeopardizing their...

10.1021/acssuschemeng.1c01293 article EN ACS Sustainable Chemistry & Engineering 2021-04-20

The proper handling of end-of-life (EOL) lithium-ion batteries (LIBs) has become an urgent and challenging issue with the surging use LIBs, in which recovering high-value cathodes not only relieves pressure on raw material supply chain but also minimizes environmental pollution. Beyond direct recycling spent to their pristine states, upcycling next-generation is great significance maximize value materials sustain fast development LIBs. Herein, a "reciprocal ternary molten salts" (RTMS)...

10.1016/j.isci.2022.103801 article EN cc-by-nc-nd iScience 2022-01-22

Identification of active sites for oxygen evolution reaction (OER) plays a key role in the design and fabrication high-performance cobalt-based electrocatalysts. Herein, we report synthesis two types two-dimensional monometallic cobalt hydroxide nanoplates aqueous solution OER: α-Co(OH)2 with both Co2+Td Co2+Oh β-Co(OH)2 sites. Electrochemical characterization reveals that is more than towards OER. The better activity can be attributed to presence α-Co(OH)2, which are Our finding clarifies...

10.1039/c7dt01110e article EN Dalton Transactions 2017-01-01

Dynamic manipulation of optical properties through the reversible assembly plasmonic nanoparticles offers great opportunities for practical applications in many fields. The previous success, however, has been limited to Au nanoparticles. Reversible and tuning Ag (AgNPs) have remained a significant challenge due difficulty finding an appropriate surface agent that can effectively stabilize particle control their interactions. Here, we overcome by developing limited-ligand-protection (LLP)...

10.1021/acs.nanolett.8b02325 article EN Nano Letters 2018-07-13

A novel ratiometric surface-enhanced Raman scattering (SERS) nanosensor has been developed to probe the activity of endonuclease under in vitro and living cells conditions. The optimized alloyed Au/Ag nanoparticles (NPs) were synthesized as SERS substrate, which combined superior properties both pure Au Ag nanoparticles: they exhibit excellent plasmonic property with high chemical stability low cytotoxicity. They then employed for quantitative detection through functionalization...

10.1021/acs.analchem.7b04735 article EN Analytical Chemistry 2018-03-05

Fully alloyed Ag/Au nanorods were synthesized with highly tunable plasmonic properties and great chemical stability.

10.1039/c7nr06002e article EN Nanoscale 2017-01-01

Plasmonic noble metal nanocrystals with interior nanogaps have attracted great attention in surface-enhanced Raman scattering (SERS) applications due to the presence of built-in hotspots. Herein, we report a synthesis route holey Au–Ag alloy nanoplates by controlled galvanic replacement Ag as sacrificial template, sulfite-coordinated Au(I) salt Au source, and polyvinylpyrrolidone (PVP) capping agent. PVP helps regulate anisotropic growth nanopores on afford highly nanostructure, monovalent...

10.1039/c6nr04866h article EN Nanoscale 2016-01-01

Here, this study reports a novel confined‐space thermal dewetting strategy for the fabrication of Au nanocups with tunable diameter, height, and size cup opening. The nanocup morphology is defined by cup‐shaped void space created yolk–shell silica template that spontaneously takes an eccentric configuration during annealing. Thermal Au, which sandwiched between yolk shell, leads to desired morphology. With strong scattering in near infrared, exhibit superior efficiency as contrast agents...

10.1002/adma.201701070 article EN Advanced Materials 2017-05-03
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