A5088477251- X-ray Diffraction in Crystallography
- Crystallization and Solubility Studies
- Metal-Organic Frameworks: Synthesis and Applications
- Magnetism in coordination complexes
- Lanthanide and Transition Metal Complexes
- Advanced oxidation water treatment
- Advanced Photocatalysis Techniques
- Nanocluster Synthesis and Applications
- Covalent Organic Framework Applications
- Perovskite Materials and Applications
- Luminescence and Fluorescent Materials
- Catalytic Processes in Materials Science
- Analytical chemistry methods development
- Electrochemical Analysis and Applications
- Surface Modification and Superhydrophobicity
- Polyoxometalates: Synthesis and Applications
Jilin University of Chemical Technology
2018-2019
Jilin University
2011-2018
State Key Laboratory of Inorganic Synthesis and Preparative Chemistry
2011-2018
Institute of Chemical Technology
2018
The reversible sorption–desorption of terminal coordinated water molecules and the guest can switch slow magnetic relaxation in a classic lanthanide metal–organic framework system, Dy(BTC)(H2O)·DMF Dy(BTC).
A copper(I) halide-based compound with a formula of [Cu4I3(DABCO)2]I3 (DABCO = N,N'-dimethyl-1,4-diazabicyclo[2.2.2]octane) has been prepared by solvothermal reactions. This characterized single-crystal X-ray diffraction, elemental analysis, IR, TG, XPS and powder diffractions. Structure analyses reveal that this is constructed unprecedented cationic cluster [Cu8I6](2+) organic ligand DABCO the channels are occupied I2 I(-). The guest I(-) can move freely in out host-framework. UV/vis...
Abstract A series of 3D interpenetrating metal‐organic frameworks, namely, [Zn 3 (BPDC) (4‐BPT) 1.5 ] · 1.5DMF [ 1 , BPDC = biphenyl‐4,4′‐dicarboxylic acid, 4‐BPT 4‐amino‐3,5‐bis(4‐pyridyl)‐1,2,4‐triazole, DMF dimethylformamide], (4‐PYTZ) 2 4‐PYTZ 3,6‐bis(pyridin‐4‐yl)‐1,2,4,5‐tetrazine], (OBA) (4‐PYTZ)] 2DMF OBA 4,4′‐oxybis(benzoate)], (3‐PYTZ) Zn (DMF) 7DMF 4 3‐PYTZ 3,6‐bis(pyridin‐3‐yl)‐1,2,4,5‐tetrazine] and (3‐BPT)] 2.5DMF 5 3‐BPT 4‐amino‐3,5‐bis(3‐pyridyl)‐1,2,4‐triazole] were...
Manganese modified silicate ore (MnSO) prepared using an impregnation method was used as a heterogeneous ozonation catalyst, and the catalytic activity evaluated by degradation of ciprofloxacin (CIP). The results showed that manganese oxide successfully loaded onto natural (SO). mineralization efficiencies CIP were considerably improved in presence MnSO. Under optimal conditions, removal process followed pseudo-first-order reaction model well. rate constant MnSO/O3 1.7 times 3.3 higher than...
The coordinated CH<sub>3</sub>CN play the role of an unusual reversible photoluminescence switch to perfectly modulate luminescence in a copper(<sc>i</sc>) halide cluster coordination polymer.
We report a new copper halide-based compound [Cu6I6Br2C16H32N4] (1) with 3D 2-fold interpenetrated framework structure. Upon excitation at 290 nm and 350 nm, 1 shows dual emission ca. 500 530 nm. As the temperature decreased from 300 K down to 6 K, luminescent properties of show large red shifts 120 72 respectively.
Antibiotic tetracycline hydrochloride was efficiently degraded by CoSO-catalytic ozonation and the catalytic oxidation mechanism elucidated.
Abstract Three new organically templated copper(I) halides formulated (C 10 H 22 N 2 ) [Cu 4 I 8 ] ( 1 ), Br and C 20 44 3 {C = , ′‐diethyl‐1, 4‐diazabicyclo‐[2.2.2]octane T1 4, 4′‐(butane‐1, 4‐diyl)bis(1‐ethyl‐1, 4‐diazonia‐bicyclo[2.2.2]octane) T2 )} were synthesized under solvothermal conditions by an in situ copper reduction route. The structures of these compounds are constructed similar inorganic anion cluster skeleton, Cu X ′ I, Br), organic templates. templates the originated from...