A5100336238- Metal-Organic Frameworks: Synthesis and Applications
- Fuel Cells and Related Materials
- Magnetism in coordination complexes
- X-ray Diffraction in Crystallography
- Crystallization and Solubility Studies
- Lanthanide and Transition Metal Complexes
- Electrocatalysts for Energy Conversion
- Molecular Sensors and Ion Detection
- Crystal structures of chemical compounds
- Covalent Organic Framework Applications
- Chemical Synthesis and Characterization
- Membrane-based Ion Separation Techniques
- Polyoxometalates: Synthesis and Applications
- Zeolite Catalysis and Synthesis
- Advanced battery technologies research
- Geological and Geochemical Analysis
- Crystallography and molecular interactions
- Surface Modification and Superhydrophobicity
- Chemical Synthesis and Reactions
- Crystal Structures and Properties
- Metal complexes synthesis and properties
- earthquake and tectonic studies
- Organometallic Compounds Synthesis and Characterization
- Inorganic Fluorides and Related Compounds
- Advanced Nanomaterials in Catalysis
Jilin University
2016-2025
Gansu Agricultural University
2025
Jilin Medical University
2011-2025
East China University of Technology
2021-2024
Guiyang Medical University
2024
Jiangxi University of Science and Technology
2023
Zhejiang University
1999-2023
State Key Laboratory of Chemical Engineering
2022-2023
Southwest Petroleum University
2023
Tsinghua University
2023
We clarified the chemical structure of typical “bottom-up” CDs and proved that IPCA is molecular state photoluminescence center.
Defect engineering is a versatile approach to modulate band and electronic structures as well materials performance. Herein, metal-organic frameworks (MOFs) featuring controlled structural defects, namely UiO-66-NH2 -X (X represents the molar equivalents of modulator, acetic acid, with respect linker in synthesis), were synthesized systematically investigate effect defects on photocatalytic properties. Remarkably, MOFs are able switch photocatalysis. The H2 production rate presents...
SnS nanocrystals have been synthesized in a simple and facile way. Sn6O4(OH)4 is introduced to synthesize tin sulfide, which used as precursor. By changing the reaction conditions (reaction temperature Sn/S molar ratio), with different shape size can be produced. nanoparticles nanoflowers orthorhombic crystal structure uniform distribution. The firstly transform polycrystalline nanoflowers, then become amorphous nanosheets. drive force of amorphization reduces high free-energy nanocrystals....
Phosphoric acid (PA)-doped polybenzimidazoles generally require high PA doping levels to achieve conductivity as high-temperature proton exchange membranes. However, result in a significant decrease the mechanical properties of and leaching from Herein, Zr-based metal-organic framework material (UIO-66) was introduced into poly[2,2'-(p-oxydiphenylene)-5,5'-benzimidazole] (OPBI) The composite membranes exhibited long-range continuous transport channels when mass ratio UIO-66 OPBI ≥30 wt %....
Bacterial invasion and proliferation on various surfaces pose a serious threat to public health worldwide. Conventional antibacterial strategies that mainly rely bactericides exhibit high bacteria-killing efficiency but might trigger the well-known risk of antibiotic resistance. Here, we report superhydrophobic mechano-bactericidal surface with photodynamically enhanced capability. First, bioinspired nanopillars polycarbonate as bulk material were replicated from anodized alumina oxide...
Abstract Information security occupies an important position in the era of big data. Attempts to improve performance tend impart them with more additional encryption strategies. Herein, inspired by wettability feature Stenocara beetle elytra and signal model traffic light, a novel array perovskite nanocrystals (PNs)‐integrated PhC microsphere for information is presented. The photoluminescent PNs are encapsulated angle‐independent microspheres binary optical signals as coding information....
Two novel lanthanide metal–organic frameworks (MOFs) with the formulas [Tb(bidc)(Hbidc)(H2O)]n (JXUST-20) and {[Tb3(bidc)4(HCOO)(DMF)]·solvents}n (JXUST-21) were synthesized based on 2,1,3-benzothiadiazole-4,7-dicarboxylic acid (H2BTDC) under solvothermal conditions. Interestingly, benzimidazole-4,7-dicarboxylic (H2bidc) was formed in situ using H2BTDC as starting material. The self-assembly process of targeted MOFs different topological structures can be controlled by solvents concentration...
Mycoplasma bovis (M. bovis) has caused huge economic losses to the cattle industry. The interaction between M. and host cells is elucidated by screening identifying target protein of adhesin on surface cell membrane. However, response mechanism embryonic bovine lung (EBL) infection not yet fully understood. Additionally, it necessary further explore whether with induces oxidative stress mitochondrial damage in EBL cells. In this study, oxidation reaction, membrane potential, structure,...
Imidazolinium-derived carbenes catalyze the ring-expansion lactonization of oxacycloalkane-2-carboxaldehydes. A variety functionalized five-, six-, and seven-membered lactones can be formed efficiently under mild reaction conditions. The success this new method for construction is highly influenced by electronic nature carbene catalyst.
Abstract Defect engineering is a versatile approach to modulate band and electronic structures as well materials performance. Herein, metal–organic frameworks (MOFs) featuring controlled structural defects, namely UiO‐66‐NH 2 ‐X (X represents the molar equivalents of modulator, acetic acid, with respect linker in synthesis), were synthesized systematically investigate effect defects on photocatalytic properties. Remarkably, MOFs are able switch photocatalysis. The H production rate presents...
The integration of 1 and polymer matrices leads to the fabrication 1@polymer MMMs, which can be used in detection pH folic acid. Powder samples also show potential for application fingerprint identification.
Recent progress on branched polymer membranes as electrolyte materials for proton exchange membrane fuel cell (PEMFC) applications has attracted interest due to the limitations of commercially available Nafion® membranes. Branched have shown improved chemical stability, conductivity, and good solubility. The branching degree structure agent an essential correlation with characteristics This review presents most recent promising design strategies polymers both low- high-temperature cells....
High-purity heavy water (D2O) is a strategic material owing to its important application in the fields of nuclear energy and scientific research. D2O always tends get contaminated by H2O strong hygroscopicity. Herein, bimetallic hexanuclear Ln(III) cluster-based metal–organic framework (Eu0.5Tb0.5-TZB-MOF) has been synthesized for fluorescence sensing D2O–H2O binary mixtures. Eu0.5Tb0.5-TZB-MOF can be used immediately differentiate or via fluorescent color responses that are obvious naked...
A novel 3,8-diimidazol-1,10-phen (phen = phenanthroline) compound has been prepared from the carbon−nitrogen bond cross-coupling reaction. X-ray structural studies for this and its dihydrate reveal they have different molecular conformations (Lb in 1 Lc·2H2O 2). Two cadmium(II) one zinc(II) complexes of 3,8-diimidazol-1,10-phen, formulated as [Cd2(d-cam)2(La)2]·(H2O)6 (3), [Cd2(d-cam)2(La)(H2O)] (4), [Zn2(d-cam)2(Lb)2]·(H2O)5 (5), obtained involving an auxiliary chiral ligand d-cam (a...
Colloidal IV–VI SnSe nanocrystals with small and uniform size distribution were synthesized by a facile phosphine-free method. Simple Sn6O4(OH)4 was introduced as tin precursor to synthesize the nanocrystals. By changing reaction temperature Sn/Se molar ratio, different shapes sizes achieved. The influence of ratio shape has been discussed detail. Similar other chalcogenides, shows potential energy storage material. performance an anode material for lithium ion batteries investigated. A...
Metal–organic frameworks (MOFs)-based fluorescent sensors have attracted much attention due to their high selectivity, sensitivity, and operability. However, the poor stability of MOFs seriously limits applications in detecting toxic species water system. Herein, taking advantage chemical metal phosphonate bond, easy crystallinity carboxylate, π-conjugated benzene, a new luminescent MOF with three-dimensional network has been successfully synthesized using predesigned...