A5010992519- X-ray Diffraction in Crystallography
- Crystallization and Solubility Studies
- Carbon dioxide utilization in catalysis
- Metal-Organic Frameworks: Synthesis and Applications
- Organometallic Complex Synthesis and Catalysis
- Covalent Organic Framework Applications
- Luminescence and Fluorescent Materials
- Advanced Photocatalysis Techniques
- biodegradable polymer synthesis and properties
- Radioactive element chemistry and processing
- Coordination Chemistry and Organometallics
- Advanced Nanomaterials in Catalysis
- Electrocatalysts for Energy Conversion
- CO2 Reduction Techniques and Catalysts
- Catalysis for Biomass Conversion
- Synthesis and characterization of novel inorganic/organometallic compounds
- Environmental Chemistry and Analysis
- Catalytic Cross-Coupling Reactions
- Fuel Cells and Related Materials
- Synthetic Organic Chemistry Methods
- Catalytic Processes in Materials Science
- Organoboron and organosilicon chemistry
- Magnetism in coordination complexes
- Molecular Sensors and Ion Detection
- Ionic liquids properties and applications
City University of Hong Kong
2022-2025
Sun Yat-sen University
2018-2023
National Institute of Clean and Low-Carbon Energy
2018
Based on the concept of function-oriented synthesis, we pertinently developed a series new functional ionic polymers, which exhibited good catalytic performance, robust constancy, and excellent substrate expansibility for sustainable catalysis CO<sub>2</sub>-involved reactions.
Abstract The development of efficient electrocatalysts for ethanol oxidation reaction (EOR) is crucial the potential commercialization direct fuel cells, yet it faces significant challenges between catalytic performance and cost‐effectiveness. 2D materials have recently emerged as a promising group due to their large surface area, charge transport, tunable band structures, excellent activity. In this study, novel layered noble‐metal dichalcogenide, PtSe 2 , explored electrocatalysis from...
A series of Ti(IV) and Zr(IV) bis(benzyl) post-metallocene precatalysts containing an unusual C(sp3)-chelating [O,N,CH(Ar)] ligand has been synthesized. The four-membered N,C-donor chelate is anticipated to engender more accessible active sites, while the aryl-substituted C(methine) moiety can introduce element flexibility therein. racemic complexes have fully characterized by multinuclear NMR spectroscopy. In particular, [1H,19F]-COSY -HOESY experiments were conducted elucidate environment...
As indicated by ROESY NMR experiments, the title catalyst (X 2 = –C 4 H –) favours conformations with proximal, syn -Ti sites, which engender cooperative reactivity.
Rapid and selective removal of micropollutants from water is important for the reuse resources. Despite hollow frameworks with specific functionalized porous walls adsorption based on a series interactions, tailoring stable shape nanometer- micrometer-sized architectures pollutants remains challenge. Here, exactly controlled sheets, tubes, spherical were presented crosslinking supramolecular colloids in polar solvents. The strongly depended architecture original colloids. As entropy...
Rigid binuclear assemblies with M⋯M distances and syn binding sites that are amenable for cooperative reactivity have been structurally characterised; the Ti 2 catalysts more active than anti mono-Ti controls produced higher- M w polymers.
Despite many cationic nanomaterials that have been developed for efficient adsorption of anionic pollutants, tailoring a stable shape with denser cations on the surface advanced removal capability remains challenging. Here, new strategy is presented fabricating two-dimensional (2D) laminas and their curvature based cross-linking 2D supramolecular networks from hydrogen-bonded trimesic amide derivatives. Owing to distribution most surface, two nanostructures show fast sorption kinetics...
A series of conformationally rigid (Zn-salphen)2 complexes with a planar bridging component (xanthene or dibenzofuran) are described. Conformational changes for these assemblies essentially limited to the axial rotation Zn-salphen moieties; however, such geometric constraints crucially permit subtle tuning intermetallic separation and geometry potentially enhance catalytic activity (and cooperative effects). The have been investigated as catalysts in conjunction nBu4NI coupling CO2 epoxides....
A series of shape-persistent bis-[C(sp3)-chelating] Ti2 (plus Zr2 and Hf2) complexes with a rigid linker component (xanthene or dibenzofuran) are presented. These structurally diverse assemblies display limited yet different conformational flexibility, crucially, such geometric constraints confer access to range intermetallic separations orientations potentially enhance catalytic activity cooperative effects. For ethylene polymerizations, the catalysts (in conjunction trityl borate) exhibit...
A tubular catalyst showed fast catalytic kinetics for CO 2 conversion with a TON of 2300 and TOF up to 173 h −1 .
Abstract Rapid and selective removal of micropollutants from water is important for the reuse resources. Despite hollow frameworks with specific functionalized porous walls adsorption based on a series interactions, tailoring stable shape nanometer‐ micrometer‐sized architectures pollutants remains challenge. Here, exactly controlled sheets, tubes, spherical were presented crosslinking supramolecular colloids in polar solvents. The strongly depended architecture original colloids. As entropy...