A5032357068- DNA and Nucleic Acid Chemistry
- Chemical Synthesis and Analysis
- Ionic liquids properties and applications
- Carbon Dioxide Capture Technologies
- Carbon dioxide utilization in catalysis
- Inorganic and Organometallic Chemistry
- Chemical synthesis and alkaloids
- Electrochemical Analysis and Applications
- Synthesis and Biological Evaluation
- Click Chemistry and Applications
- Synthesis and Catalytic Reactions
RISE Research Institutes of Sweden
2024
University of Southampton
2024
Universidade Nova de Lisboa
2019-2022
Rede de Química e Tecnologia
2020
University of Lisbon
2020
Two novel bicyclo[6.1.0]nonyne (BCN) linker derivatives, which can be directly incorporated into oligonucleotide sequences during standard automated solid-phase synthesis, are reported. Stabilities of BCN-carbinol and two BCN-oligonucleotides evaluated under acidic conditions. In addition, derivatized BCN linkers (non-acidic acid treated) for strain-promoted alkyne-azide cycloaddition (SPAAC).
Finding a cheap and easily recycling material that can capture CO2 under atmospheric pressure (1 atm) is of paramount importance. In this context, combining ionic liquids (ILs) with abundant natural materials, such as chitin-based biopolymers, appears an interesting alternative. work, four acetate-based ILs were selected to explore the solubility chitin, chitosan, carboxymethyl-chitosan. Using carboxymethyl-chitosan biopolymer monomer units models, different Nuclear Magnetic Resonance (NMR)...
The synthesis of an unreported 2-aminopyrrolidine-1-carboxamidine unit is here described for the first time. This unusual and promising structure was attained through oxidative decarboxylation amino acids using pair reagents, silver(I)/peroxydisulfate (Ag(I)/S2O82-) followed by intermolecular (in case l-proline derivative) intramolecular trapping acyl l-arginine) N-nucleophiles. approach has a broader scope derivatives, whereas cyclization afforded l-acylarginines, when applied, results in...