A5089518271- Advanced Polymer Synthesis and Characterization
- Photopolymerization techniques and applications
- Sulfur-Based Synthesis Techniques
- Radical Photochemical Reactions
- Photochromic and Fluorescence Chemistry
- Organoselenium and organotellurium chemistry
- biodegradable polymer synthesis and properties
- Luminescence and Fluorescent Materials
- Synthetic Organic Chemistry Methods
- Chemical Synthesis and Reactions
- Innovative Microfluidic and Catalytic Techniques Innovation
- Additive Manufacturing and 3D Printing Technologies
- Polymer composites and self-healing
- Covalent Organic Framework Applications
- Antimicrobial agents and applications
- Carbon dioxide utilization in catalysis
- Organophosphorus compounds synthesis
- Catalytic C–H Functionalization Methods
- Synthesis and properties of polymers
- Oxidative Organic Chemistry Reactions
- Chemical Synthesis and Analysis
- Supramolecular Self-Assembly in Materials
- Organometallic Complex Synthesis and Catalysis
- Electrospun Nanofibers in Biomedical Applications
- Polymer Surface Interaction Studies
Ingenierie des Materiaux polymeres
2025
Soochow University
2015-2024
Mudanjiang Medical University
2024
Soochow University
2024
Suzhou Research Institute
2014-2018
Chemical Synthesis Lab
2014-2017
Ghent University
2017
Sichuan University
2014-2015
Yangzhou University
2013
Laboratoire de Synthèse Organique
2013
Mn(III)-mediated phosphonations of carbon–carbon double and triple bonds to form alkenylphosphonates are introduced.
We explore the utilization of aromatic diselenides as new low temperature exchangeable monomers for their in thermosets.
Mn(OAc)3-mediated direct Csp2–H radical trifluoromethylation of coumarins with CF3SO2Na (Langlois reagent) to afford selective 3-trifluoromethyl in moderate good yields is described. This methodology can also be applied the quinolinones and pyrimidinones.
Abstract Orthogonal maleimide and thiol deprotections were combined with thiol–maleimide coupling to synthesize discrete oligomers/macromolecules on a gram scale molecular weights up 27.4 kDa (128mer, 7.9 g) using an iterative exponential growth strategy degree of polymerization (DP) 2 n −1. Using the same chemistry, “readable” sequence‐defined oligomer cyclic topology also created. Furthermore, uniform dendrons fabricated sequential (DP=2 −1) or double dendrimer approaches significantly...
Novel synthesis of selenium containing polymers with pre-determined structures and applications thereof.
Three-dimensional (3D) printing based on photoinduced reversible addition–fragmentation chain transfer (RAFT) polymerization is emerging as a versatile and powerful method to prepare "living" 3D objects, which can be postmodified with various functionalities. However, an additional photoinitiator or photocatalyst necessary in these systems, toxic will cause negative effects the properties of prepared materials. Here, we report oxygen-tolerant rapid living photoiniferter RAFT polymerization,...
Multifunctional hydrogels with controllable degradation and drug release have attracted extensive attention in diabetic wound healing. This study focused on the acceleration of healing selenide-linked polydopamine-reinforced hybrid on-demand light-triggered nanozyme release.Herein, selenium-containing hydrogels, defined as DSeP@PB, were fabricated via reinforcement selenol-end capping polyethylene glycol (PEG) by polydopamine nanoparticles (PDANPs) Prussian blue nanozymes a one-pot approach...
Vinyl acetate is polymerized in the living way under irradiation of blue light‐emitting diodes (LEDs) or sunlight without photocatalyst at ambient temperature. 2‐(Ethoxycarbonothioyl)sulfanyl propanoate exclusively added and acts as initiator chain transfer agent simultaneously current system. Poly(vinyl acetate) with well‐regulated molecular weight narrow distribution ( Đ < 1.30) synthesized. Near quantitative end group fidelity polymer demonstrated by nuclear magnetic resonance (NMR)...
Reactions of diphenylphosphinoyl radicals with 5-aryl-2-pentenoates or β-phenylethylene styrenes generate trans-substituted tetrahydronaphthalenes through a cascade reaction sequence.
ADVERTISEMENT RETURN TO ISSUEPREVNoteNEXTAir Oxidative Radical Hydroxysulfurization of Styrenes Leading to β-HydroxysulfidesShao-Fang Zhou†, Xiangqiang Pan*†, Zhi-Hao Adedamola Shoberu†, and Jian-Ping Zou*†‡View Author Information† Key Laboratory Organic Synthesis Jiangsu Province, College Chemistry Chemical Engineering, Soochow University, 199 Renai Street, Suzhou, 215123, China‡ Synthetic Natural Substances, Shanghai Institute Chemistry, Chinese Academy Sciences, 200032, China*E-mail:...
A diphenylphosphinoyl radical-initiated sequential reaction of 1,4-diaryl-1-butynes and analogues is developed for the synthesis 2-phosphinoylated 3,4-dihydronaphathalenes related compounds.
Three-dimensional (3D) printing utilizing controlled polymerization systems is emerging as a powerful approach to fabricate "living" objects, which can be further modified with various functionalities. Here, we report photoinduced free radical-promoted cationic reversible addition–fragmentation chain transfer (RAFT) under broad wavelengths from ultraviolet (UV) near-infrared (NIR) light. A commercially available iron catalyst, cyclopentadienyl dicarbonyl dimer (Fe2(Cp)2(CO)4), was used the...
The application of reversible deactivation radical polymerization techniques in 3D printing is emerging as a powerful method to build "living" polymer networks, which can be easily postmodified with various functionalities. However, the building speed these systems still limited compared commercial systems. Herein, digital light processing (DLP)-based system via photoinduced free radical-promoted cationic addition-fragmentation chain transfer vinyl ethers, objects by DLP printer at...
A versatile protocol for the synthesis of a variety multiresponsive diselenide-containing polymeric architectures was investigated. It consists one-pot, two-step process with generation selenol by in situ nucleophilic ring opening selenolactone broad range amine-containing structures, followed transformation obtained compounds to corresponding diselenide through spontaneous oxidation coupling reaction. After elaboration this one-pot reaction, number routes based on selenolactones have been...
This work provides an unprecedented example for the exploration of cyclic topology effects on shape memory performance bulk polyurethane materials, providing a novel angle to elucidate structure–property relationship polymeric materials.
Butyl acrylate is polymerized in the living way under irradiation of purple light‐emitting diode (LED) or sunlight without photocatalyst at ambient temperature. 2‐((Phenoxycarbonothioyl)thio) ethyl propanoate) exclusively added and acted as an initiator a chain transfer agent simultaneously current system. Poly(butyl acrylate) with well‐regulated molecular weight relatively narrow distribution ( Ð < 1.30) synthesized. High conversion (>95%) can be achieved within several minutes....
The use of a 980 nm light providing deep penetration power and high compatibility for weak bonds shows potential bio-related applications.
The unstable PbSe quantum dot (QD) surface requires tedious and complicated synthetic protocols renders them substantially underdeveloped compared to PbS QDs. Here, we describe a direct synthesis of QD inks at room temperature. In comparison the conventional three-step synthesis, our strategy simplifies fabrication process one step reduces preparation cost by factor eight. A photovoltaic device based on these has achieved conversion efficiency (PCE) 10.38% with high stability, which is...
Photopolymerization-based three-dimensional (3D) printing techniques have been widely utilized to fabricate polymeric materials with complex architectures. The application of reversible deactivation radical polymerization (RDRP) in 3D is emerging as a powerful tool introduce various postprinting abilities but still at an early stage. Here, photoinduced free radical-promoted cationic addition–fragmentation chain transfer (RAFT) method was developed, utilizing the direct photolysis RAFT agent...
Photoinduced 3D printing based on the reversible addition-fragmentation chain transfer (RAFT) process has emerged as a robust method for creating diverse functional materials. However, achieving precise control over mechanical properties of these printed objects remains critical challenge practical application. Here, we demonstrated RAFT step-growth polymerization bifunctional xanthate and vinyl acetate. Additionally, photoinduced through with tetrafunctional By adjusting molar ratio...