A detailed structural disorder investigation of Prussian blue analogues M1.5[Cr(CN)6]·zH2O (M = Fe and Co) has been done by carrying out a reverse Monte Carlo (RMC) simulation on the powder neutron diffraction data. X-ray diffraction, infrared spectroscopy, Mössbauer dc magnetization measurements have also employed to investigate magnetic properties compounds. The Rietveld refinement patterns reveals that both compounds are in single phase with face-centered cubic crystal structure (space...

Dynamics of crystal water in Prussian blue (PB), Fe(III)4[Fe(II)(CN)6]3.14H2O and its analogue green (PG), ferriferricynaide, Fe(III)4[Fe(III)(CN)6]4.16H2O have been investigated using Quasielastic Neutron Scattering (QENS) technique. PB compounds are important materials for their various interesting multifunctional properties. It is known that plays a crucial role towards the properties compounds. Three structurally distinguishable molecules: (i) coordinated molecules at empty nitrogen...

Oxalate (ox) and phenanthroline (phen) ligands based one dimensional spin chain molecular magnets, [{Fe(Δ)Fe(Λ)}1−x{Cr(Δ)Cr(Λ)}x(ox)2(phen)2]n (x = 0, 0.1, 0.5) have been designed, synthesized using a hydrothermal synthesis method. The Rietveld refinement of the powder X-ray neutron diffraction patterns at room temperature confirms single-phase formation compounds in monoclinic structure with space group P21. consist two ligands, oxalate (C2O42−) as coordination acceptor building block...

We have controlled the nature of magnetic ordering in RbxBayMn[3-(x + 2y)]/2[Fe(CN)6]·zH2O prussian blue analogues by alkaline earth metal cation (Ba2+) substitution and application an external field. Structural analysis, employing Rietveld refinement X-ray neutron diffraction patterns, reveals a tetragonal crystal structure for all these compounds. The presence Fe3+-C ≡ N-Mn2+ chains structure, absence both cyanide flipping (Mn2+-C N-Fe3+) charge transfer from Mn2+ to Fe3+ (Fe2+-C N-Mn3+)...

We report the effect of a 4d ion (Ru3+) substitution on structural disorder and magnetic ordering in cyanide-bridged molecular magnets, RuxNi3-3x/2[Cr(CN)6]2⋅zH2O (0≤x≤0.5). Structural analysis, by employing Rietveld refinement x-ray diffraction patterns, reveals face centered cubic structure for all these compounds. In present study, we have controlled [Cr(CN)6] vacancies substituting Ru at Ni site then role varying correlations consequently properties has been investigated. succeeded...

We report a detailed structural disorder study of the BaxMn[Fe(CN)6]2(x+1)/3·zH2O (x = 0 and 0.3) molecular magnets by carrying out Reverse Monte Carlo (RMC) simulations neutron diffraction data. Both samples have also been investigated using X-ray diffraction, infrared spectroscopy dc magnetization techniques. Rietveld refinement patterns confirmed single phase formation for both compounds in face-centered cubic structure. IR spectral establishes presence cyanide flipping compounds, thereby...

A one-dimensional single-chain molecular magnet [{CoII(Δ)CoII(Λ)}(ox)2(phen)2]n with a cross-linked π–π coordination network has been synthesized hydrothermally and investigated for its structural magnetic properties. Oxalate (ox) ligands bridge the paramagnetic CoII metal ions, whereas phenanthroline (phen) exhibit networks. The compound thoroughly using room-temperature X-ray neutron diffraction, infrared spectroscopy, dc magnetization, reverse Monte Carlo (RMC) simulation methods....

We report a magnetic field dependent (H) antiferromagnetic (AFM) to ferrimagnetic (FIM) transition in Rb0.19Ba0.3Mn1.1[Fe(CN)6]·0.48H2O Prussian blue analogue. A microscopic understanding of the nature this induced AFM FIM is achieved by carrying out low temperature neutron diffraction study under an external field. decrease Néel and evolution phase with increase dc are evident ac susceptibility measurements. With H, grows at expense phase, for H > 4 T, system fully transforms phase....

The electronic structures of Prussian blue analog $({\mathrm{Rb}}_{x}{\mathrm{Ba}}_{y}){\mathrm{Mn}}_{[3\ensuremath{-}(x+2y)]/2}[\mathrm{Fe}{(\mathrm{CN})}_{6}]$ cyanides have been investigated by employing soft x-ray absorption spectroscopy (XAS) and magnetic circular dichroism (XMCD) at the Fe Mn $L$ $(2p)$ edges. measured XAS spectra analyzed with configuration-interaction (CI) cluster model calculations. valence states ions are found to be...

Crystal water plays a crucial role towards the multifunctional properties of Prussian blue and its analogue (PBA) compounds. We have investigated dynamics crystal in (PB), Fe(III)4[Fe(II)(CN)6]3. 14 H2 O using Quasielastic Neutron Scattering (QENS). In PB, molecules exist spherical cavity, created due to vacant sites Fe(CN)6 units, also at interstitial sites. QENS data showed that evolves with increase temperature. The observed has been correlated quantitatively different lattice. It is...

Benign prostatic hyperplasia (BPH) is a commonly occurring disease in aging men. It involves cellular proliferation of stromal and glandular tissues leading to prostate enlargement. Current drug therapies show several adverse effects such as sexual dysfunctions cardiovascular side effects. Therefore, there need develop more effective medical treatment for BPH. In this regard, we aimed identify genes which play critical role We have obtained the dataset differentially expressed (DEGs) BPH...

Background: Anatomical variations of the mandibular canal play a vital role while performing surgical procedures affecting an area with course in mandible. The neurovascular bundle may be severed during carried out Aims and Objectives: present retrospective study was aimed to assess evaluate its on panoramic radiography. Materials Methods: included 88 randomly selected radiographs complete mandible associated bone. On radiograph, following parameters were assessed including bifid location...

In this article, we study how technological components affect the price of hearing aids. The main goals are to determine which functional and features have greatest influence on manufacturer-based prices in aid industry, analyse price-cost margins at dispenser level using a unique data set that is compiled from clinic West Texas. result shows style signal processing scheme two most important determinants price. Other characteristics such as directional microphone, noise cancellation, certain...

The idea that 'organisations which do not learn will cease to exist' has led scholars investigate the presence of learning dimensions in various industries. This paper attempts provide an empirical study on public and private banks India. respondents for comprise different managerial levels age groups with tenures service. highlights India differ significantly from each other basis present them. level respondent does affect perception employees regarding bank as a organisation. analysis...

The idea that 'organisations which do not learn will cease to exist' has led scholars investigate the presence of learning dimensions in various industries. This paper attempts provide an empirical study on public and private banks India. respondents for comprise different managerial levels age groups with tenures service. highlights India differ significantly from each other basis present them. level respondent does affect perception employees regarding bank as a organisation. analysis...

Objectives: This study aimed to compare WHO modified partogram and paperless in the effective management of labor.Methods: hospital-based prospective observational included 200 pregnant women.They were randomized into Group A (n=100) who monitored with during active labor B partogram.Resident doctors compared partographs on basis user friendliness (1-10), teachability overall usefulness (1-10).Statistical Package for Social Sciences (SPSS) version 21.0 was used statistical analysis.P-value...

Background: Oral cancer is a preventable disease that can be controlled by tobacco cessation and health education. For development of healthy nation, society desirable dependent on physically mentally strong adolescents adults. Objectives: The present study was conducted to assess the effectiveness utilization structured instructional module knowledge, attitude, practice regarding prevention oral among adolescents. Materials Methods: 500 preuniversity urban college students, divided into two...

Views Icon Article contents Figures & tables Video Audio Supplementary Data Peer Review Share Twitter Facebook Reddit LinkedIn Tools Reprints and Permissions Cite Search Site Citation Nidhi Thakur, S. M. Yusuf, J. V. Yakhmi; Nature of Magnetic Ordering in Molecular Magnet Mn[Fe(CN)6]2/3⋅zH2O. AIP Conf. Proc. 30 June 2011; 1347 (1): 145–148. https://doi.org/10.1063/1.3601805 Download citation file: Ris (Zotero) Reference Manager EasyBib Bookends Mendeley Papers EndNote RefWorks BibTex toolbar...

This research aimed to better understand how Indian customers felt about fibers made from eco-friendly fibers. A systematic questionnaire was used gather data 500 respondents, and many statistical tests, such as regression chi-square were performed evaluate the hypotheses. The findings indicated that awareness attitudes toward fiber goods are strongly correlated, education level is favorably correlated with awareness. Additionally, it shown female respondents more likely than male have...