A5048124879- X-ray Diffraction in Crystallography
- Crystallization and Solubility Studies
- CO2 Reduction Techniques and Catalysts
- Radical Photochemical Reactions
- Photochemistry and Electron Transfer Studies
- Magnetism in coordination complexes
- Organometallic Complex Synthesis and Catalysis
- Metal complexes synthesis and properties
University of Basel
2023-2024
Abstract Classical photochemistry requires nanosecond excited-state lifetimes for diffusion-controlled reactions. Excited radicals with picosecond have been implied by numerous photoredox studies, and controversy has arisen as to whether they can actually be catalytically active. We provide direct evidence the elusive pre-association between radical ions substrate molecules, enabling photoinduced electron transfer beyond diffusion limit. A strategy based on two distinct light absorbers,...
The effects of introducing bpy ligands with CH 2 CCH substituents in the 6- and 6,6′-positions [Cu(N^N)(P^P)] + complexes are explored; structural data discussed terms CC⋯π arene interactions compounds Cambridge Structural Database.