A5033292558- Catalytic Alkyne Reactions
- Chemical Synthesis and Reactions
- Cyclopropane Reaction Mechanisms
- Synthetic Organic Chemistry Methods
- Cancer Treatment and Pharmacology
- Asymmetric Hydrogenation and Catalysis
- Catalytic C–H Functionalization Methods
- Nanomaterials for catalytic reactions
- Inorganic and Organometallic Chemistry
- Metal-Organic Frameworks: Synthesis and Applications
- Advanced Polymer Synthesis and Characterization
- biodegradable polymer synthesis and properties
- Oxidative Organic Chemistry Reactions
- Microbial Natural Products and Biosynthesis
- Synthesis of β-Lactam Compounds
- Catalytic Processes in Materials Science
- Analytical Chemistry and Chromatography
- Polyoxometalates: Synthesis and Applications
- Fluorine in Organic Chemistry
- Organic and Inorganic Chemical Reactions
- Biological Activity of Diterpenoids and Biflavonoids
- Advanced Chemical Sensor Technologies
- Catalytic Cross-Coupling Reactions
- Click Chemistry and Applications
- Organoselenium and organotellurium chemistry
Henan Academy of Sciences
2020-2024
Institute of Chemistry
2020-2024
Xiamen University
2014-2016
Collaborative Innovation Center of Chemistry for Energy Materials
2016
Green Chemistry
2016
Qiannan Normal College For Nationalities
2014
Nanjing Tech University
2014
Nanjing Library
2014
Sun Yat-sen University
2014
Lanzhou University
2008-2011
A novel method for the selective synthesis of (Z)-1,5-dien-2-yl esters has been developed though Pt(II)-catalyzed tandem 1,2-acyl and 1,2-hydride migration, along with an allyl migration reaction propargylic carboxylates electronically unbiased internal alkynes. The unusual selectivity 1,2-acyloxy was realized.
A simple and convenient synthetic approach to furan derivatives 4 has been developed via gold-catalyzed tandem cyclization/Friedel-Crafts type reactions.
High-quality spherical V-MCM-48 catalysts were successfully synthesized and showed higher catalytic activity for the selective oxidation of styrene to benzaldehyde.
A mild and direct pathway for the formation of five-membered heterocyclic compounds from hydroxylated enynes has been developed. In this reaction, were selectively transformed into 2, with an allene moiety at 3-position, in presence F(3) CSO(3) H (0.1 mol %). When R(1) , R(2) =Ph, diphenylvinyl-2,3-dihydro-1H-pyrrole (2 y) was obtained. With HSbF(6) (5 %) as catalyst, polycyclic skeletons 3 4 adjacent stereocenters =H =styrene, 1,3-dienyl-2,5-dihydro-1H-pyrrole (6 as) formed. This Brønsted...
New ruthenium complexes with rigid ligand <italic>o</italic>-(diphenylphosphino)aniline exhibit excellent performance in chemoselective hydrogenation of dimethyl oxalate to methyl glycolate.
Abstract A mixture of taxols was prepared from 10‐deacetyl‐7‐xylosyltaxanes by three‐step reactions: redox, acetylation, and deacetylation. The separated column chromatography on silica gel to afford Taxol, Taxol B (Cephalomannine) C. C converted Docetaxel Schwartz's reagent. structures were characterized HPLC, 1 H‐NMR, 13 C‐NMR MS. This synthetic process has expanded the source biomass for chemical semi‐synthesis Docetaxel, reduced production costs, increased resource taxanes.
The efficiency of photocatalysts depends largely on the accessibility reaction species to active centre, electron transfer and geometric matching between surface catalyst species. In this work, we successfully synthesized designed one two-dimensional Mn(II) MOF with [Mn
ABSTRACT High‐nickel LiNi 0.8 Co 0.1 Mn O 2 (NCM811) cathode paired with silicon‐based graphite (SiO/Gr) is pivotal for enhancing the energy density of lithium‐ion batteries (LIBs). However, high reactivity NCM811 electrolyte and volumetric expansion issues associated SiO/Gr pose significant challenges to their practical application. To settle these issues, we explore impact additives phenyl acid anhydride moieties on performance NCM811‖SiO/Gr pouch cells across a wide temperature range...
Epitaxial layers of GaAsN were grown on GaAs by metalorganic molecular beam epitaxy using dimethylhydrazine, triethylgallium, and conventional arsenic sources. The nitrogen incorporation in was studied varying the gallium fluxes, at growth temperatures between 430 500 °C. kinetics mechanism have been modeled assuming formation an adduct trimethylgallium dimethylhydrazine. model accounts for experimentally observed relationships rates N into GaAsN, fluxes Ga, As, N, temperature.
Palladium nanoparticles with unique catalytic activity and high stability are synthesized. These exhibit excellent reduction for nitroaromatics in green solvents the presence of H 2 at ambient pressure temperature. The prominent advantages this nanotechnology include low consumption catalyst, chemoselectivity, reusability environmentally solvents.
Abstract A mild and direct route to five‐membered heterocyclic compounds from hydroxylated enynes is reported.