A5002364379- Covalent Organic Framework Applications
- Metal-Organic Frameworks: Synthesis and Applications
- Crystallization and Solubility Studies
- X-ray Diffraction in Crystallography
- Carbon dioxide utilization in catalysis
- Chemical Synthesis and Reactions
- Membrane Separation and Gas Transport
- Advanced Photocatalysis Techniques
- Molecular Sensors and Ion Detection
- Asymmetric Hydrogenation and Catalysis
Instituto de Ciencia de Materiales de Madrid
2022-2024
Consejo Superior de Investigaciones Científicas
2024
Institut Parisien de Chimie Moléculaire
2022
Sorbonne Université
2022
Centre National de la Recherche Scientifique
2022
The development of efficient catalysts that include the advantages homogeneous and heterogeneous is a challenge can be achieved with metal-organic frameworks (MOFs) since they incorporate different functionalities in their structure make them promising for processes. Herein, two new isoreticular nitrogen-rich naphthalene cobalt-MOFs, Co-NDTz Co-NDPhTz, were successfully prepared under solvothermal conditions from corresponding linkers (H2NDTz=2,6-naphthaleneditetrazole...
A novel covalent triazine framework (DPhBTBT-CTF) prepared by microwave cyclotrimerization of BTBT units was proved as very versatile photocatalyst for different reactions: oxidations, bromination, Diels–Alder cycloaddition and hydroxylations.
A tetrazole-naphthalene linker was used to prepare a nickel MOF (metal–organic framework) (NiNDTz) with interesting properties: specific surface area SBET of 320 m2g–1 (SLangmuir 436 m2g–1), high thermal stability (Tdonset = 300 °C), and CO2 uptake 1.85 mmolg–1, attributed the tetrazole groups be as fillers in gas separation membranes. The role these crucial mechanical properties mixed membranes prepared using polycarbonate polymer matrix, providing very homogeneous filler distribution also...
The enantioselective discrimination of racemic compounds can be achieved through the design and preparation a new family chiral conjugated BINOL–porous polymers (CBPPs) from enantiopure (R)- or (S)-BINOL derivatives 1,3,5-tris(4-phenylboronic acid)benzene 1,3,5-tris(4-ethynylphenyl)benzene, 1,3,5-triethynyl-2,4,6-trifluorobenzene, tetra(4-ethynylphenyl)methane as comonomers following Suzuki–Miyaura Sonogashira–Hagihara carbon–carbon coupling approaches. obtained CBPPs show high thermal...
Noble metal elements are ubiquitous in our everyday life, from medical applications to electronic devices and synthetic chemistry. Iridium is one of the least abundant elements, despite its scarcity, it remains essential for efficient active catalytic processes. Consequently, development heterogeneous catalysts with presence iridium sites enormous interest as leads improvement their recyclability reusability. Here, we demonstrate a strategy incorporate atoms into metal-organic frameworks...
Noble metals (Ag, Au, Pt, Rh, Ir, Pd, Ru and Os) are ubiquitous in our everyday life, from medical applications to electronic devices synthetic chemistry. Iridium is one of the least abundant elements, despite its scarcity, it remains essential for efficient active catalytic processes. Consequently, development heterogeneous catalysts with presence iridium sites enormous interest as leads improvement their recyclability reusability. Here, we demonstrate a strategy incorporate atoms into...