- X-ray Diffraction in Crystallography
- Crystallization and Solubility Studies
- Organometallic Complex Synthesis and Catalysis
- Conducting polymers and applications
- Organic Electronics and Photovoltaics
- Metal complexes synthesis and properties
- Organic Light-Emitting Diodes Research
- Magnetism in coordination complexes
- Synthesis and properties of polymers
- Advanced Memory and Neural Computing
- Luminescence and Fluorescent Materials
- biodegradable polymer synthesis and properties
- Carbon dioxide utilization in catalysis
- Lanthanide and Transition Metal Complexes
- Supramolecular Chemistry and Complexes
- Synthesis and Biological Evaluation
- Crystal structures of chemical compounds
- Semiconductor materials and devices
- Molecular Junctions and Nanostructures
- Metal-Organic Frameworks: Synthesis and Applications
- Crystallography and molecular interactions
- Fluorine in Organic Chemistry
- Copper Interconnects and Reliability
- Catalytic Cross-Coupling Reactions
- Supramolecular Self-Assembly in Materials
San’an Optoelectronics (China)
2024
Nanjing University of Aeronautics and Astronautics
2014-2023
Shanghai Public Health Clinical Center
2020
Material (Belgium)
2019
Nanjing University
1998-2012
Fudan University
2010-2011
State Key Laboratory of ASIC and System
2010-2011
Chemnitz University of Technology
2003-2010
Shanghai Fudan Microelectronics (China)
2010
Supramolecular binary vesicles based on the host–guest complexation of water-soluble pillar[6]arene (WP6) and SAINT molecule have been successfully constructed, which showed pH-, Ca2+-, thermal-responsiveness. These supramolecular can efficiently encapsulate model substrate calcein, then be released either by adjusting solution pH to acidic condition due complete disruption vesicular structure, or particularly, adding a certain amount Ca2+ Ca2+-induced vesicle fusion accompanied structure...
Abstract Functional materials play a vital role in the fabrication of smart windows, which can provide more comfortable indoor environment for humans to enjoy better lifestyle. Traditional windows tend possess only single functionality with purpose regulating input solar energy. However, different color tones also have great influences on human emotions. Herein, strategy orthogonal integration properties is proposed, namely thermo-responsiveness ethylene glycol-modified pillar[6]arene ( EGP6...
Abstract Background We aimed to evaluate the antiviral activity and safety of darunavir/cobicistat (DRV/c) in treating COVID-19 patients. Methods In this single-center, randomized, open-label trial, mild patients with polymerase chain reaction (PCR)–confirmed were enrolled Shanghai, China. Participants randomized receive DRV/c for 5 days on top interferon alpha 2b inhaling or alone. The primary end point was virological clearance rate oropharyngeal swabs at day 7 after randomization...
Smart windows are a promising solution to improve energy-saving efficiency and indoor comfort due their potential functionalities including solar modulation, coloration, self-cleaning, self-power, moisture scavenging. Recently, smart constructed by supramolecular strategy have attracted increasing attention the inherent dynamic, reversible adaptive properties of noncovalent interactions, which can endow fabricated with desired fascinating functionalities. In this review, emerging...
Thermo- and oxidation-responsive pillar[6]arene-ferrocene based supramolecular vesicles were constructed for controlled drug release.
Two novel 3′,4′,5′-trifluorobiphenyl-based aromatic polyimide monomers, 2,2′-bis[4′-(3′′,4′′,5′′-trifluorophenyl)phenyl]-4,4′-biphenyl diamine (BTFBPD) and 2,2′-bis[4′-(3′′,4′′,5′′-trifluorophenyl)phenyl]-4,4′,5,5′-biphenyltetracarboxylic dianhydride (BTFBPDA) were synthesized. fluorinated polyimides (PIs), PI(BTFBPD-DPBPDA) PI(BTFBPD-BTFBPDA) prepared via a two-step procedure using BTFBPD reacting with 2,2′-diphenyl-4,4′,5,5′-biphenyltetracarboxylic (DPBPDA) BTFBPDA, respectively. was...
Two novel polyimides, PI(CzBD-BTFBPDA) and PI(TPABD-BTFBPDA), consisting of alternating electron-donating 2,2′-bis[4-(9H-carbazol-9-yl)phenyl]- or 2,2′-bis[4-(diphenylamino)phenyl]-substituted biphenyl moieties electron-accepting phthalimide were synthesized characterized. These polyimides are thermally stable with 5% weight loss over 500 °C the glass transition temperatures found to be 293 °C. The optical band gaps PI(TPABD-BTFBPDA) 3.42 3.30 eV, respectively, indicating significance...
An effective, regioselective C-2 arylation of imidazo[2,1-b]thiazoles catalyzed by Cu(I) has been developed. This proceeded smoothly without promotion the ligands, and various functional (22 samples) groups were well tolerated. Preliminary mechanistic studies this are also reported.
The self-assembly of 3,5-pyrazoledicarboxylic acid (H3pdc) and metal salts under hydrothermal conditions leads to the formation a series novel NaI-CuII-LnIII heterometallic coordination polymers, [[Na(H2O)4]2[Cu(pdc)2Ln(H2O)5]2 x 3H2O]n [Ln = La (1); Sm (2); Pr (3); Nd (4) pdc3- 3,5-pyrazoledicarboxylate]. X-Ray structure analyses show that these complexes all exhibit pairs infinite, unexpected, cationic anionic chains. It is first successful attempt construct unprecedented polymers with...
Abstract As part of a strategy to explore highly functionalized macromolecular semiconductors, two novel polyimides consisting electron‐donating carbazole and triphenylamine side groups are synthesized characterized. Polyimide films sandwiched between an indium‐tin oxide (ITO) bottom electrode Al top exhibit accessible conductivity states can be switched from the low‐conductivity state high‐conductivity state. Memory devices with configuration Al/PI(CzBD‐DPBPDA)/ITO bipolar flash‐type memory...
Two novel soluble aromatic polyimides were prepared from BBCDA and TFDMC by polycondensation with PMDA BPDA <italic>via</italic> a two-step procedure. Memory devices fabricated the PIs. In devices, ITO was used as ground electrode (the cathode) Al set top anode).
Four single-chain bolaamphiphiles, in which the hydrophobic chain was made of flexible dodecamethylene unit and bissalicylideneimine unit, were designed synthesized. These bolaamphiphiles can form two types stable ordered monolayer membranes dilute aqueous solution, linear curved monolayers (vesicles), have been characterized by transmission electron microscopy X-ray diffraction. The aggregate structure thermal behavior from these investigated variable temperature 1H NMR, Fourier transform...
Abstract Copper(I) carboxylates of type [( n Bu 3 P) m CuO 2 CR] (m = 1: 3a , R Me; 3b CF ; 3c Ph; 3d CH=CHPh. 2: 4a 4b 4c 4d 3: 8a 8b 8c CH 8d (CH OCH ) H; 8e c C 4 H 7 O) are accessible by following synthesis methodologies: the reaction [CuO ( 1a 1b 1c 1d CH=CHPh) with equivalents P 1, 2, 3), or treatment CuCl] 5a 1; 5b 2) [KO CCF ] 6 ). A more straightforward method for – is electrolysis copper in presence HO CR 7a 7b 7c 7d 7e and respectively. This allows to prepare appropriate copper(I)...